Title Polusuhi postupak priprave portland cementnog klinkera : završni rad
Title (english) Semy-dry portland cement clinker preparation procedure : bachelor thesis
Author Igor Plavčić
Mentor Dražan Jozić (mentor) MBZ: 231234
Committee member Damir Barbir (predsjednik povjerenstva)
Committee member Sanja Perinović Jozić (član povjerenstva)
Committee member Dražan Jozić (član povjerenstva)
Granter University of Split Faculty of Chemistry and Technology (Division of Engineering and Chemistry) Split
Defense date and country 2018-10-01, Croatia
Scientific / art field, discipline and subdiscipline TECHNICAL SCIENCES Chemical Engineering
Abstract Proizvodnja portland cementnog klinkera predstavlja složen tehnološki proces u kojem se sirovina, vapnenac i glina pomiješani u odgovarajućem omjeru prolaze cijeli niz vrlo složenih i zahtjevnih procesa koji obuhvaćaju sušenje, mljevenje, homogeniziranje u fazi priprave sirovine. U procesu priprave klinkera sirovina prolazi kroz izmjenjivač topline (grijana ispušnim plinovima iz rotacijske peći) pri čemu se odvija dodatno zagrijavanje sirovine na veće temperature koje omogućavaju odvijanje procesa dehidroksilacije i kalcinacije koja se odvije neposredno prije ulaska u rotacijsku peć. U rotacijskoj peći sirovina se grije na znatno više temperature koje osiguravaju odvijanje reakcija sinteriranja koje omogućavaju nastajanje glavnih minerala klinkera i to trikalcijeva silikata ( 𝐶 3 𝑆 ), dikalcijeva silikata ( 𝐶 2 𝑆 ), trikalcijeva aluminata ( 𝐶 3 𝐴 ) i tetrakalcijeva aluminat-ferita ( 𝐶 4 𝐴𝐹 ) koji čine četiri glavne mineralne faze. O masenom udjelu i obliku svake mineralne vrste te o njihovim fizikalni i kemijskim svojstvima uvelike ovisi i kvaliteta dobivenog klikera, odnosno u daljnoj fazi proizvodnje cementa ovise i konačna svojstva proizvedenog cementa koja se odražavaju na čvrstoću, topline hidratacije, kemijske otpornost i dr. U ovom radu pripravljen je klinker portland cementa na poluindustrijskoj peći uz korištenje standardnih materijala koji se koriste na industrijskim pećima s jednom razlikom da je punjenje peći izvršeno diskontinuirano sa sirovinom koja ne prolazi postupke predgrijavanja te je sirovina dodana u obliku granula (polusuhi postupak). Dobiveni kliker je karakteriziran primjenom mikroskopije i rendgenske difrakcije. Rezultati ukazuju na postizanje reakcijskih uvjeta koji osiguravaju proizvodnju klikera. Distribucija i veličina nastalih kristala minerala u klinkeru kao i sadržaj slobodnog vapna ukazuje da bi se postupak sinteze mogao odvijati i uz nešto duže zadržavanje sirovine u peći koji bi omogućilo manje slobodnog vapna i vjerojatno veći udio minerala.
Abstract (english) Portland cement clinker production is a complex technological process in which raw materials, limestone and clay mixed in the appropriate ratio pass through a variety of highly complex and demanding processes, including drying, grinding, homogenizing at the stage of raw material preparation. In the process of preparing the clinker raw material, it passes through a heat exchanger (heated by exhaust gas from the rotary kiln), whereby further heat of the raw material is carried out at higher temperatures which enable the dihydroxylation and calcination process to take place just before entering in the rotary kiln. In the rotary kiln the raw material is heated at the much higher temperature that ensures the sintering reaction and it allows the formation of the major minerals such as Tricalcium silicate ( 𝐶 3 𝑆 ), Dicalcium silicate ( 𝐶 2 𝑆 ), Tricalcium aluminate ( 𝐶 3 𝐴 ) and Tetracalcium Aluminoferrite ( 𝐶 4 𝐴𝐹 ) mineral phase. The weight and shape of each mineral type and their physical and chemical properties depend to a great extent on the quality of the cutters obtained, that is, in the further stage of cement production, and the final properties of the cement produced which reflect on strength, heat of hydration, chemical resistance, etc. In this paper, portland cement clinker was produced on a semi-industrial furnace using standard materials used on industrial furnaces with one difference that the furnace filling was discontinuously made with raw material that did not undergo preheating processes and the raw material was added as a granule (semi-dry process). The resulting clinker was characterized by microscopy and X-ray diffraction. The results indicate the achievement of reaction conditions that ensure the production of clinker. The distribution and size of the crystalline minerals formed in the clinker as well as the content of free lime indicates that the synthesis process could take place with a longer retention of the raw material in the furnace to allow less free lime and possibly higher mineral content.
Keywords
portland cement
portland cementni klinker
homogenizacija
TG/DTG-DTA analiza
XRD analiza
svjetlosna mikroskopija
Hrvatska.Solin
Cemex Hrvatska d.d.
Keywords (english)
portland cement
portland cenent clinker
homogenisation
XRD analysis
TG/DTG-DTA analysis
light microscopy
Croatia. Solin
Cemex Croatia
Language croatian
URN:NBN urn:nbn:hr:167:774280
Study programme Title: Chemical Technology; specializations in: Chemical Engineering, Environmental Protection Course: Chemical Engineering Study programme type: university Study level: undergraduate Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
Type of resource Text
File origin Born digital
Access conditions Open access
Terms of use
Public note Ključne riječi doradio knjižničar/ Key words are revised by the librarian
Created on 2019-06-10 08:49:08