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master's thesis
Uklanjanje deksametazona iz vode naprednim oksidacijskim procesima
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2019. urn:nbn:hr:149:112823
Žitko, Ivana
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Žitko, I. (2019). Uklanjanje deksametazona iz vode naprednim oksidacijskim procesima (Master's thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:112823

Žitko, Ivana. "Uklanjanje deksametazona iz vode naprednim oksidacijskim procesima." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2019. https://urn.nsk.hr/urn:nbn:hr:149:112823

Žitko, Ivana. "Uklanjanje deksametazona iz vode naprednim oksidacijskim procesima." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2019. https://urn.nsk.hr/urn:nbn:hr:149:112823

Žitko, I. (2019). 'Uklanjanje deksametazona iz vode naprednim oksidacijskim procesima', Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 03 June 2024, https://urn.nsk.hr/urn:nbn:hr:149:112823

Žitko I. Uklanjanje deksametazona iz vode naprednim oksidacijskim procesima [Master's thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2019 [cited 2024 June 03] Available at: https://urn.nsk.hr/urn:nbn:hr:149:112823

I. Žitko, "Uklanjanje deksametazona iz vode naprednim oksidacijskim procesima", Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:149:112823

Metadata
TitleUklanjanje deksametazona iz vode naprednim oksidacijskim procesima
Title (english)Removal of dexamethasone from water by advanced oxidation processes
AuthorIvana Žitko
MentorLidija Furač (mentor)
Committee memberLidija Furač (predsjednik povjerenstva)
Committee memberMatija Cvetnić (član povjerenstva)
Committee memberDajana Kučić Grgić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2019-04-30, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Farmaceutska industrija, kao jedna od rastućih industrija danas, postala je jedna od većih zagađivača vodenog okoliša. Svakodnevno korištenje farmaceutika dovodi do onečišćenja površinskih i podzemnih voda te time i utjecaja na ljudsko zdravlje. Europska unija je donijela Okvirnu direktivu o vodama u kojoj je predložena strategija protiv onečišćenja voda. Direktiva sadrži listu prioritetnih onečišćivala među kojima su i mnogi farmaceutici. Osim njih, postoji još mnogo farmaceutika koji bi uskoro mogli naći svoje mjesto na tom popisu, budući da se sve više koriste. Mnogi konvencionalni procesi pročišćavanja otpadnih voda nisu dovoljno učinkoviti u uklanjanju farmaceutika, stoga se kao alternativni način uklanjanja nameću napredni oksidacijski procesi (engl. Advanced Oxidation Processes - AOP). Glavne prednosti naprednih oksidacijskih procesa su visoka učinkovitost, ekonomičnost te činjenica da su to razgradni procesi, čiji je cilj postići mineralizaciju organskih tvari do H2O i CO2 ili razgradnju do jednostavnijih i bezopasnijih anorganskih produkata. Svrha ovog rada je izrada poluempirijskog matematičko-mehanističkog modela za opisivanje kemizma razgradnje deksametazona (DXT) u vodi pomoću UV - C/H2O2 i UV - C/S2O82- fotooksidacijskih procesa, radi povećanja učinkovitosti pročišćavanja otpadnih voda. U eksperimentalnom radu praćena je koncentracija oksidansa, mineralizacija, pH vrijednost te konverzija. Utvrđeno je kako razvijeni mehanistički modeli relativno dobro opisuju potrošnju oksidansa, mineralizaciju otopine i konverziju deksametazona s RMSE (engl. Root Mean Square Deviation) vrijednošću ≤ 1,417 %, dok se razvijeni pojednostavljeni model nije pokazao dobrim u opisivanju promjene pH vrijednosti.
Abstract (english)
The pharmaceutical industry, as one of the growing industries today, has become one of the major environmental polluters. Daily use of pharmaceuticals leads to contamination of surface water and groundwaters and affects human health. The European Union has adopted the Water Framework Directive in which water pollution reduction strategy is proposed. The Directive contains a list of priority pollutants among which are many pharmaceuticals. Besides them, there are many pharmaceuticals that could soon find their place on that list, as they are increasingly used. Many conventional wastewater purification processes are not effective enough in removing pharmaceuticals, so advanced oxidation processes (AOP) are becoming one of the most effective alternative methods of removal. The main advantages of advanced oxidation processes are high efficiency, cost-effectiveness and the fact that these are degradation processes, which aim to achieve mineralization of organic substances up to H2O and CO2 or degradation to simpler and more harmless inorganic products. The purpose of this paper is to produce a semi-empiric mathematical-mechanical model for the chemistry of dexamethasone (DXT) decomposition in water using UV-C/H2O2 and UV-C/S2O82- photooxidation processes. The concentration of oxidants, mineralization, pH value and conversion were monitored. It was found that developed mechanistic models describe the consumption of oxidants, mineralization and dexamethasone conversion relatively well, with RMSE (Root Mean Square Deviation) value of ≤ 1,417 %, while it was not so effective in describing the changes in pH value.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:112823
ProjectNumber: IP-2014-09-7992
Title: Modeliranje okolišnih aspekata napredne obrade voda za razgradnju prioritetnih onečišćivala
Title: Modeling of environmental aspects of advanced water treatment for fegradation of priority pollutants
Acronym: MEAoWT
Leader: Tomislav Bolanča
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: Applied Chemistry - Graduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry
Course: Advanced materials and technologies
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra primijenjene kemije (magistar/magistra primijenjene kemije)
Type of resourceText
File originBorn digital
Access conditionsAccess restricted to students and staff of home institution
Terms of useLicence In copyright icon
Created on2022-02-27 22:25:59