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master's thesis
Fotokatalitička obrada farmaceutskih mikroonečišćivala pod simuliranim Sunčevim zračenjem
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. urn:nbn:hr:149:330189
Crmarić, Dora
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

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Crmarić, D. (2020). Fotokatalitička obrada farmaceutskih mikroonečišćivala pod simuliranim Sunčevim zračenjem (Master's thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:330189

Crmarić, Dora. "Fotokatalitička obrada farmaceutskih mikroonečišćivala pod simuliranim Sunčevim zračenjem." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:330189

Crmarić, Dora. "Fotokatalitička obrada farmaceutskih mikroonečišćivala pod simuliranim Sunčevim zračenjem." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:330189

Crmarić, D. (2020). 'Fotokatalitička obrada farmaceutskih mikroonečišćivala pod simuliranim Sunčevim zračenjem', Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 17 June 2024, https://urn.nsk.hr/urn:nbn:hr:149:330189

Crmarić D. Fotokatalitička obrada farmaceutskih mikroonečišćivala pod simuliranim Sunčevim zračenjem [Master's thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2020 [cited 2024 June 17] Available at: https://urn.nsk.hr/urn:nbn:hr:149:330189

D. Crmarić, "Fotokatalitička obrada farmaceutskih mikroonečišćivala pod simuliranim Sunčevim zračenjem", Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2020. Available at: https://urn.nsk.hr/urn:nbn:hr:149:330189

Metadata
TitleFotokatalitička obrada farmaceutskih mikroonečišćivala pod simuliranim Sunčevim zračenjem
Title (english)Photocatalytical treatment of pharmaceutical micropollutants under simulated solar irradiation
AuthorDora Crmarić
MentorMarin Kovačić (mentor)
Committee memberMarin Kovačić (predsjednik povjerenstva)
Committee memberAna Lončarić Božić (član povjerenstva)
Committee memberAna Vrsalović Presečki (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2020-09-25, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Abstract
Porast ljudske populacije i globalni razvoj rezultiraju rastućom potrošnjom vode, a time i povećanjem količine otpadnih voda. Neadekvatno obrađene otpadne vode, dospijećem u prirodne prijamnike, pridonose onečišćenju vode. Posebno su zabrinjavajuća farmaceutska mikroonečišćivala detektirana u vodama diljem svijeta, za čije uklanjanje nisu dostatni konvencionalni postupci obrade voda. Nesteroidni protupalni lijek diklofenak ubraja se u farmaceutska onečišćivala. Diklofenak iz ljudskog organizma izlazi dijelom nepromijenjem i dijelom u obliku raznih metabolita te dospijeva u otpadne vode. Konvencionalnim metodama obrade vode moguće je ukloniti samo dio prisutnog diklofenaka, stoga se okreće novim tehnologijama poput naprednih oksidacijskih procesa. U ovom radu ispitana je učinkovitost fotokataltičke razgradnje diklofenaka pod simuliranim Sunčevim zračenjem uz BiVO4 fotokatalizator. Ispitani su utjecaji metode sinteze fotokatalizatora, pH i dodatka modifikatora na fotokatalitičku razgradnju diklofenaka. Fotokatalizator sintetiziran metodom precipitacije pokazuje bolju fotokatalitičku aktivnost u odnosu na fotokatalizator sintetiziran hidrotermalnom metodom. Nadalje, dodatak modifikatora EDTA i povišenje pH pogoduju fotokatalitičkom uklanjanju diklofenaka. Najveća fotokatalitička aktivnost ostvarena je pri pH= 7,5 uz BiVO4 fotokatalizator sintetiziran precipitacijom s dodatkom EDTA. Ostvareno uklanjanje nakon 180 min provedbe procesa pod simuliranim Sunčevim zračenjem iznosi 34,5%, dok pod vidljivim zračenjem iznosi 56,1%.
Abstract (english)
The population growth and global development are resulting in an increase in water consumption, leading to an increase in amount of waste water. Inadequately treated waste water enters water sources and contributes to pollution of the water environment. Pharmaceutical micropollutants which are detected in water around the world present a great jeopardy, due to the insufficient removal by conventional water treatment. Among them is diclofenac, non-steroidal anti-inflammatory drug. Diclofenac is being released into the environment partially unchanged and as its metabolites. Since diclofenac can only be partially removed by conventional water treatments it is necessary to develop new methods such as advanced oxidation processes. This study questions the efficiency of photocatalytical processes in diclofenac removal under simulated solar irradiation using BiVO4 photocatalyst. The study investigated influences of BiVO4 preparation method, pH and different additives on photocatalytic removal of diclofenac. Photocatalysts synthesized by precipitation method shows higher photocatalytic activity than photocatalysts synthesized by hidrothermal method. Furthermore, addition of EDTA and increase in pH result in higher photocatalytical activity. The highest photocatalytical activity has been achieved with pH= 7,5 and BiVO4 photocatalyst synthesized by precipitation method with addition of EDTA. Achieved diclofenac removal after 180 min is 34,5 % under simulated solar irradiation and 56,1 under visible light irradiation.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:330189
ProjectNumber: IP-2018-01-1982
Title: Nano-katalizatori aktivirani Sunčevim zračenjem u tehnologijama zaštite okoliša
Title: Nano-sized solar-active catalysts for environmental technologies
Acronym: NaSCEnT
Leader: Hrvoje Kušić
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: Chemical Engineering - Graduate study
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra inženjer/inženjerka kemijskog inženjerstva (magistar/magistra inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2022-03-01 17:21:15