Ferrocene belongs to the group of metallocenes and represents a significant pharmacophore in medicinal chemistry along with its derivatives being important ligands in coordination chemistry. In this work, novel mono- and bis-ferrocenyl derivatives connected to aromatic amine through 1,2,3-triazolyl linker and their metal complexes were prepared. Mono- and bis-propargylated terminal alkynes (1–3) were obtained by reaction of 2,2'-dipyridylamine, aniline and 2-aminobenzothiazole with propargyl bromide in a basic media while azide precursors for the „click“ reaction of 1-azidomethylferocene (4), 1-azidoferocene (5) and 1-azidoethylferocene (6) were prepared from corresponding ferrocene derivatives and sodum azide. Conjugates of ferrocene and heterocycles (7–9) were prepared by the Huisgen 1,3-dipolar cycloaddition of propargylated aromatic amines (1–3) and ferrocene azides (4–6). The reactions were performed using copper(II) acetate in methanol as a source of Cu(I) ionsConjugates of ferrocene and heterocycles were used as ligands in the synthesis of Zn(II) and Cu(II) metal complexes. The structures of the newly synthesized derivatives were confirmed by 1H and 13C NMR spectroscopy. The spectroscopic properties of the obtained complexes were investigated by NMR, UV-Vis and IR spectroscopy. The crystal structure of the Cu(II) complex of ferrocene and 2,2'-dipyridylamine conjugates linked by a 1,2,3-triazole was determined by single-crystal X-ray diffraction.