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master's thesis
Sinteza novih aminonaftalenskih fotouklonjivih zaštitnih skupina
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. urn:nbn:hr:149:040734
Marić, Mia
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Marić, M. (2020). Sinteza novih aminonaftalenskih fotouklonjivih zaštitnih skupina (Master's thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:040734

Marić, Mia. "Sinteza novih aminonaftalenskih fotouklonjivih zaštitnih skupina." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:040734

Marić, Mia. "Sinteza novih aminonaftalenskih fotouklonjivih zaštitnih skupina." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:040734

Marić, M. (2020). 'Sinteza novih aminonaftalenskih fotouklonjivih zaštitnih skupina', Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 25 August 2024, https://urn.nsk.hr/urn:nbn:hr:149:040734

Marić M. Sinteza novih aminonaftalenskih fotouklonjivih zaštitnih skupina [Master's thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2020 [cited 2024 August 25] Available at: https://urn.nsk.hr/urn:nbn:hr:149:040734

M. Marić, "Sinteza novih aminonaftalenskih fotouklonjivih zaštitnih skupina", Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2020. Available at: https://urn.nsk.hr/urn:nbn:hr:149:040734

Metadata
TitleSinteza novih aminonaftalenskih fotouklonjivih zaštitnih skupina
Title (english)Synthesis of new aminonaphtalene photocages
AuthorMia Marić
MentorDragana Vuk (mentor)
MentorNikola Basarić (komentor)
Committee memberDragana Vuk (predsjednik povjerenstva)
Committee memberIrena Škorić (član povjerenstva)
Committee memberNikola Basarić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2020-02-28, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U sklopu rada sintetizirani su novi derivati aminonaftalena 2-5, koji će se koristiti kao supstrati tijekom priprave fotoklonjivih zaštitnih skupina. Početni korak sinteze odnosi se na reakciju metiliranja aminonaftalena, kojom je dobiven N,N-dimetilaminonaftalen (1) u iskorištenju od 93 %. Nadalje, Vilsmeier-Haackovom reakcijom formiliranja spoja 1 dobivena je smjesa dva aldehida 3 i 4. Za daljnu sintezu odabran je dialdehid 4, koji redukcijom s natrijevim borhidridom daje dialkohol 5, koji se pokazao kao pogodan prekursor za pripravu odgovarajućih etera i estera.
Abstract (english)
This thesis describes the synthesis of aminonaphthalene derivatives 2-5, which are suitable precursors for the transformation to photocages. The first step includes the methylation of aminonaphthalene 1, whereby N,N-dimethylaminonaphthalene 2 has been obtained in 93 % yield. Vilsmeier-Haack reaction of N,N-dimethylaminonaphthalene 2 gave a mixture of two aldehydes 3 and 4. The dialdehyde 4 was chosen for further investigation and its reduction with sodium borohydride gave dialcohol 5, which is a suitable precursors in future synthesis of ethers and esters.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:040734
Study programmeTitle: Applied Chemistry - Graduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry
Course: Applied organic chemistry
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra primijenjene kemije (magistar/magistra primijenjene kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
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Created on2022-03-06 14:13:10