prikaz prve stranice dokumenta Priprava novih funkcionaliziranih furanskih policikla reakcijom fotokatalitičke oksigenacije uz Mn(III) porfirin u neutralnom i lužnatom mediju
Access restricted to students and staff of home institution
master's thesis
Priprava novih funkcionaliziranih furanskih policikla reakcijom fotokatalitičke oksigenacije uz Mn(III) porfirin u neutralnom i lužnatom mediju
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. urn:nbn:hr:149:942688
Markotić, Mateja
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Markotić, M. (2020). Priprava novih funkcionaliziranih furanskih policikla reakcijom fotokatalitičke oksigenacije uz Mn(III) porfirin u neutralnom i lužnatom mediju (Master's thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:942688

Markotić, Mateja. "Priprava novih funkcionaliziranih furanskih policikla reakcijom fotokatalitičke oksigenacije uz Mn(III) porfirin u neutralnom i lužnatom mediju." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:942688

Markotić, Mateja. "Priprava novih funkcionaliziranih furanskih policikla reakcijom fotokatalitičke oksigenacije uz Mn(III) porfirin u neutralnom i lužnatom mediju." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:942688

Markotić, M. (2020). 'Priprava novih funkcionaliziranih furanskih policikla reakcijom fotokatalitičke oksigenacije uz Mn(III) porfirin u neutralnom i lužnatom mediju', Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 20 December 2024, https://urn.nsk.hr/urn:nbn:hr:149:942688

Markotić M. Priprava novih funkcionaliziranih furanskih policikla reakcijom fotokatalitičke oksigenacije uz Mn(III) porfirin u neutralnom i lužnatom mediju [Master's thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2020 [cited 2024 December 20] Available at: https://urn.nsk.hr/urn:nbn:hr:149:942688

M. Markotić, "Priprava novih funkcionaliziranih furanskih policikla reakcijom fotokatalitičke oksigenacije uz Mn(III) porfirin u neutralnom i lužnatom mediju", Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2020. Available at: https://urn.nsk.hr/urn:nbn:hr:149:942688

Metadata
TitlePriprava novih funkcionaliziranih furanskih policikla reakcijom fotokatalitičke oksigenacije uz Mn(III) porfirin u neutralnom i lužnatom mediju
Title (english)Preparation of new functionalized furan polycycles by photocatalytic oxygenation using Mn(III) porphyrins in neutral and basic media
AuthorMateja Markotić
MentorDragana Vuk (mentor)
Committee memberDragana Vuk (predsjednik povjerenstva)
Committee memberIrena Škorić (član povjerenstva)
Committee memberLidija Furač (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2020-01-30, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U svrhu istraživanja fotokatalitičkih reakcija provedene su reakcije fotokatalitičke oksigenacija na tri furanska derivata o-divnilbenzena 1 – 3, koji su sintetizirani Wittigovom reakcijom. Reakcije fotokatalitičke oksigenacije provedene su osvjetljavanjem volframovom lampom širokog spektra uz anionski i kationski Mn porfirin i propuhivanje kisikom u neutralnom mediju. Početni spojevi 1 i 3 reagirali su uz kationski manganov porfirin pri čemu su kao produkti dobiveni ciklizacijski spojevi 4 i 6 i dimerni derivati 5 i 7. Metilni spoj 2 pokazao se kao znatno nestabilnijim te je došlo do propadanja spoja. Anionski Mn porfirin pokazao se kao nereaktivan pri čemu nisu nastali novi produkti. Svi dobiveni spojevi okarakterizirani su spektroskopskim metodama.
Abstract (english)
In aim to investigate photocatalytic oxygenation reactions, the three starting furan derivatives of o-divinylbenzene 1 – 3 were synthesized by Wittig reaction. Photocatalytic oxygenation reactions were performed by irradiation with a wide-spectrum wolfram lamp with anionic and cationic Mn porphyrin and oxygen in a neutral medium. The initial compounds 1 and 3 reacted with the cationic manganese porphyrin, obtaining cyclization compounds 4 and 6 and dimers 5 and 7 as products. Methyl compound 2 proved to be significantly more unstable and the compound decayed. The anionic Mn porphyrin proved to be non-reactive with no new products being formed. All the compounds obtained were characterized by spectroscopic methods.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:942688
Study programmeTitle: Applied Chemistry - Graduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry
Course: Applied organic chemistry
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra primijenjene kemije (magistar/magistra primijenjene kemije)
Type of resourceText
File originBorn digital
Access conditionsAccess restricted to students and staff of home institution
Terms of useLicence In copyright icon
Created on2022-03-06 15:00:23