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master's thesis
Zaštita metala prevlakama umreženih primjenom ionizirajućeg zračenja
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. urn:nbn:hr:149:503598
Vesić, Kristijan
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Vesić, K. (2020). Zaštita metala prevlakama umreženih primjenom ionizirajućeg zračenja (Master's thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:503598

Vesić, Kristijan. "Zaštita metala prevlakama umreženih primjenom ionizirajućeg zračenja." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:503598

Vesić, Kristijan. "Zaštita metala prevlakama umreženih primjenom ionizirajućeg zračenja." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:503598

Vesić, K. (2020). 'Zaštita metala prevlakama umreženih primjenom ionizirajućeg zračenja', Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 19 May 2024, https://urn.nsk.hr/urn:nbn:hr:149:503598

Vesić K. Zaštita metala prevlakama umreženih primjenom ionizirajućeg zračenja [Master's thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2020 [cited 2024 May 19] Available at: https://urn.nsk.hr/urn:nbn:hr:149:503598

K. Vesić, "Zaštita metala prevlakama umreženih primjenom ionizirajućeg zračenja", Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2020. Available at: https://urn.nsk.hr/urn:nbn:hr:149:503598

Metadata
TitleZaštita metala prevlakama umreženih primjenom ionizirajućeg zračenja
Title (english)Metal protection by coatings crosslinked using ionising radiation
AuthorKristijan Vesić
MentorMarijana Kraljić Roković (mentor)
MentorKatarina Marušić (komentor)
Committee memberMarijana Kraljić Roković (predsjednik povjerenstva)
Committee memberHelena Otmačić Ćurković (član povjerenstva)
Committee memberKatarina Marušić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2020-09-29, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Abstract
Cilj ovog rada bio je sintetizirati zaštitnu polimernu prevlaku nano-debljine na bakrenu elektrodu primjenom gama-zračenja. Prevlaka je rađena umrežavanjem samoorganizirajućih monoslojeva linolelaitične kiseline. Samoorganizirani monoslojevi su nanošeni na površinu bakrene elektrode metodom uranjanja. Uspoređivala se učinkovitost različitih prevlaka na bakru: oksidni sloj, odnosno prirodna zaštita bakra, samoorganizirani monosloj i monoslojevi umreženi različitim apsorbiranim dozama zračenja. Ispitivane su doze zračenja od 100 kGy, 120 kGy, 130 kGy, 140 kGy, 160 kGy i 180 kGy. Uzorci su ispitivani metodama Tafelove ekstrapolacije i elektrokemijske impedancijske spektroskopije (EIS). Rezultati su pokazali da samoorganizirani sloj linolelaitične kiseline pruža relativno dobru zaštitu bakru s djelotvornosti od 66 %. Dobivene vrijednosti djelotvornosti zaštite kod umreženih prevlaka ukazuju na vrlo visoku efikasnost zaštine prevlake u odnosu na neozračene uzorke i uzorke od čistog bakra. Najefikasnija zaštita je postignuta kod doze od 130 kGy gdje je postignuta djelotvornost od skoro 99 %.
Abstract (english)
The objective of this work was to synthesize a protective polymer coating of nano-thickness on a copper electrode using gamma radiation. The coating was made by crosslinking self-organizing monolayers of linoleic acid. Self-assembled monolayers were applied to the copper electrode surface by immersion. The efficiency of different coatings on copper was compared: oxide layer, ie natural protection of copper, self-organized monolayer and monolayers crosslinked with different absorbed radiation doses. Radiation doses of 100 kGy, 120 kGy, 130 kGy, 140 kGy, 160 kGy and 180 kGy were tested. The samples were examined by Tafel extrapolation and electrochemical impedance spectroscopy (EIS) methods. The results showed that the self-organized layer of linoleic acid provides relatively good protection of copper with an efficiency of 66 %. The obtained values of protection efficiency in crosslinked coatings indicate a very high efficiency of coating protection in relation to non-irradiated samples and samples of pure copper. The most effective protection was achieved at a dose of 130 kGy where an efficiency of almost 99 % was achieved.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:503598
Study programmeTitle: Applied Chemistry - Graduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry
Course: Environmental chemistry and green technologies
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra primijenjene kemije (magistar/magistra primijenjene kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2022-04-21 12:02:12