prikaz prve stranice dokumenta Razvoj sinteze novih heteroaromatskih derivata skvareinske kiseline
  Download
PDF 3.96 MB
undergraduate thesis
Razvoj sinteze novih heteroaromatskih derivata skvareinske kiseline
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2021. urn:nbn:hr:149:413374
Gašparić, Davor
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Gašparić, D. (2021). Razvoj sinteze novih heteroaromatskih derivata skvareinske kiseline (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:413374

Gašparić, Davor. "Razvoj sinteze novih heteroaromatskih derivata skvareinske kiseline." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2021. https://urn.nsk.hr/urn:nbn:hr:149:413374

Gašparić, Davor. "Razvoj sinteze novih heteroaromatskih derivata skvareinske kiseline." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2021. https://urn.nsk.hr/urn:nbn:hr:149:413374

Gašparić, D. (2021). 'Razvoj sinteze novih heteroaromatskih derivata skvareinske kiseline', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 20 December 2024, https://urn.nsk.hr/urn:nbn:hr:149:413374

Gašparić D. Razvoj sinteze novih heteroaromatskih derivata skvareinske kiseline [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2021 [cited 2024 December 20] Available at: https://urn.nsk.hr/urn:nbn:hr:149:413374

D. Gašparić, "Razvoj sinteze novih heteroaromatskih derivata skvareinske kiseline", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2021. Available at: https://urn.nsk.hr/urn:nbn:hr:149:413374

Metadata
TitleRazvoj sinteze novih heteroaromatskih derivata skvareinske kiseline
Title (english)Development of synthesis of novel heteroaromatic squaric acid derivatives
AuthorDavor Gašparić
MentorDragana Vuk (mentor)
Committee memberDragana Vuk (predsjednik povjerenstva)
Committee memberVilko Mandić (član povjerenstva)
Committee memberIrena Škorić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2021-09-20, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U sklopu ovog rada provedena je sinteza dva derivata skvareinske kiseline, kroz nekoliko koraka. U prvom stupnju provedena je reakcija aminacije uz 4-benzilpiperidin kao sekundarni amin i 1-brom-3,5-dimetoksibenzen. Sljedeći korak odnosio se na demetiliranje tercijarnog amina u svrhu dobivanja alkohola 2 i 3, koji je reakcijom kondenzacije uz prisutnost skvareinske kiseline preveden u željeni heteroaromatski derivat skvareinske kiseline 4 i 5. Osim sinteze ciljanih produkata, provedeno je niz reakcija alkiliranja furfurilamina u cilju dobivanja pogodnog sekundarnog amina za moguću buduću sintezu skvareina. Reakcije su provedene pri različitim eksperimentalnim uvjetima, ovisno o otapalu i vrsti alkil-halogenida.
Abstract (english)
As part of this work, the synthesis of two squaric acid derivatives was performed, through several steps. In the first step, an amination reaction was performed with 4-benzylpyridine as the secondary amine and 1-bromo-3,5-dimethoxybenzene. The next step was to demethylate the tertiary amine to obtain alcohols 2 and 3, which were converted to the desired heteroaromatic derivatives of squaric acid 4 and 5 by the condensation reaction in the presence of squaric acid. In addition to the synthesis of target products a chain of alkylation furfurylamine reactions has been conducted. Purpose of that reaction is to get an adequate secondary amine for the possible future synthesis of squarein. The reactions were carried out under different experimental conditions, depending on the solvent and the type of alkyl halide.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:413374
ProjectNumber: PZS-2019-02-1555
Title: Fotonaponska-geopolimerna fasada: uloga vode-kisika u naprednom sklapanju filmova kompozitnih materijala
Title: Photovoltaic-geopolymer facade: the water-oxygen role in the advanced assembly of layered composite materials
Acronym: PV-WALL
Leader: Vilko Mandić
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: PZS
ProjectNumber: UIP-2019-04-2367
Title: Fenomeni na površini tijekom priprave naprednih nanokompozita infiltracijom i funkcionalizacijom poroznih materijala
Title: Surface limitations in preparing and infiltration of hard porous nanomaterial by soft or liquid precursors for performance enhancing
Acronym: SLIPPERYSLOPE
Leader: Vilko Mandić
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: UIP
Study programmeTitle: Materials Science and Engineering - Undergraduate study
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2023-03-29 09:28:19