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undergraduate thesis
Primjena poliuretana kao materijala za sportsku obuću
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2021. urn:nbn:hr:149:677115
Ružić, Mark
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Ružić, M. (2021). Primjena poliuretana kao materijala za sportsku obuću (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:677115

Ružić, Mark. "Primjena poliuretana kao materijala za sportsku obuću." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2021. https://urn.nsk.hr/urn:nbn:hr:149:677115

Ružić, Mark. "Primjena poliuretana kao materijala za sportsku obuću." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2021. https://urn.nsk.hr/urn:nbn:hr:149:677115

Ružić, M. (2021). 'Primjena poliuretana kao materijala za sportsku obuću', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 04 November 2024, https://urn.nsk.hr/urn:nbn:hr:149:677115

Ružić M. Primjena poliuretana kao materijala za sportsku obuću [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2021 [cited 2024 November 04] Available at: https://urn.nsk.hr/urn:nbn:hr:149:677115

M. Ružić, "Primjena poliuretana kao materijala za sportsku obuću", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2021. Available at: https://urn.nsk.hr/urn:nbn:hr:149:677115

Metadata
TitlePrimjena poliuretana kao materijala za sportsku obuću
Title (english)Materials for sports footwear applications based on polyurethane
AuthorMark Ružić
MentorEmi Govorčin Bajsić (mentor)
Committee memberEmi Govorčin Bajsić (predsjednik povjerenstva)
Committee memberLjerka Kratofil Krehula (član povjerenstva)
Committee memberIgor Sutlović (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2021-07-16, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Abstract
U proizvodnji sportske obuće koriste se različiti materijali, od tkanine do kože. Poliuretan je materijal koji je razvijen 30-ih godina 20. st. i u industriji sportske obuće koristi se za izradu uložaka i đonova. Postoje dva tipa PU đonova ovisno o tipu poliola ( polieter i poliester poliol) i diizocijanata (aromatski i cikloalifatski diizocijanat). U ovom radu su pretpolimernim postupkom sintetizirani PU elastomeri na osnovi aromatskog diizocijanata, (MDI) i cikloalifatskog diizocijanata (H12MDI) uz i 1,4-butandiol kao produživač lanca, kao meki segment korišten je polikaprolakton (PCL). Istražena su toplinska svojstva PU elastomera primjenom tehnike diferencijalne pretražne kalorimetrije (DSC) te mehanička svojstva. Rezultati pokazuju da se vrijednosti staklišta (Tg) pomiču se prema višim temperaturama s povećanjem udjela tvrdog segmenta. Veću kristalnost imaju PU elastomeri s aromatskim tipom diizocijanata. Kod PU elastomera s većim udjelom tvrdog segmenta dobivene su veće vrijednosti prekidne čvrstoće.
Abstract (english)
Different materials, from fabric to leather, were used insports footwear production. Polyurethane is material which was developed in 1930s and in the sports footwear industry PU is used to make insoles and shoe soles. There are two types of PU soles based on polyol (polyether and polyester polyol) and type of diisocyanate (aromatic and cycloaliphatic diisocyanate). In this work PU elastomers based on aromatic (MDI) and cycloaliphatic (H12MDI) diisocyanate with 1,4-butanediol (BDO) as chain extender and polycaprolactone (PCL) as soft segment were synthesized by a prepolymer method. The thermal and mechanical properties of PU elastomers were investigated using differential scanning calorimetry (DSC) and tensile strength test. The Tg increased as the hard segment content increased. PU elastomers based on aromatic diisocyanate show the higher degree of crystalization. The PU elastomers with the higher hard segment content show better mechanical properties .
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:677115
Study programmeTitle: Materials Science and Engineering - Undergraduate study
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
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Created on2023-04-17 11:41:15