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undergraduate thesis
Priprava novih indenskih heteropolicikličkih sustava
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2021. urn:nbn:hr:149:269419
Znika, Monika
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Znika, M. (2021). Priprava novih indenskih heteropolicikličkih sustava (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:269419

Znika, Monika. "Priprava novih indenskih heteropolicikličkih sustava." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2021. https://urn.nsk.hr/urn:nbn:hr:149:269419

Znika, Monika. "Priprava novih indenskih heteropolicikličkih sustava." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2021. https://urn.nsk.hr/urn:nbn:hr:149:269419

Znika, M. (2021). 'Priprava novih indenskih heteropolicikličkih sustava', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 04 November 2024, https://urn.nsk.hr/urn:nbn:hr:149:269419

Znika M. Priprava novih indenskih heteropolicikličkih sustava [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2021 [cited 2024 November 04] Available at: https://urn.nsk.hr/urn:nbn:hr:149:269419

M. Znika, "Priprava novih indenskih heteropolicikličkih sustava", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2021. Available at: https://urn.nsk.hr/urn:nbn:hr:149:269419

Metadata
TitlePriprava novih indenskih heteropolicikličkih sustava
Title (english)Preparation of new indene heteropolycyclic systems
AuthorMonika Znika
MentorDragana Vuk (mentor)
Committee memberDragana Vuk (predsjednik povjerenstva)
Committee memberIrena Škorić (član povjerenstva)
Committee memberInes Despotović (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2021-09-20, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Cilj ovoga rada je prirediti furanske indanske i indenske derivate u jednom koraku termičkom reakcijom kako bi se izbjegli kompleksni reakcijski postupci pri čemu će se poseban naglasak dati na ispitivanje mehanizama reakcije računskim pristupom. Kao početni prekursor koristio se 5-metil-2-furilni derivat o-divinilbenzena koji je pripravljen Wittigovom reakcijom iz difosfonijeve soli α,α'-o-ksilendibromida i 5-metilfurfurala. Početni spoj podvrgnut je termičkoj reakciji u kiselom mediju pri čemu su nastala 4 nova produkta, ciklizacijski derivati I2 i J te indanski i indenski derivati G2 i H2. Svi spojevi su okarakterizirani i identificirani, te su na Institutu Ruđer Bošković provedeni kvantno-kemijski izračuni za svaki pojedini produkt u cilju istraživanja reakcijskih putova.
Abstract (english)
The aim of this research is to prepare furan indane and indene derivatives in one step by thermal reaction to avoid complex reaction procedures, with special emphasis on the analysis of reaction mechanisms given by quantum chemical calculations. 5-methyl-2-furyl derivative of o-divinylbenzene prepared by the Wittig reaction from the diphosphonium salt of α,α'-o-xylenedibromide and 5-methylfurfural was used as a starting precursor. The starting compound was subjected to a thermal reaction in an acidic medium to give 4 new products, cyclization derivatives I2 and J, and indan and indene derivatives G2 and H2. All compounds were characterized and identified, and quantum chemical calculations were performed at the Ruđer Bošković Institute for each individual product in order to research the reaction pathways.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:269419
Study programmeTitle: Materials Science and Engineering - Undergraduate study
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
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Created on2023-04-27 09:17:18