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undergraduate thesis
Oksidacija čađe katalizirana nanočesticama cerijeva (IV) oksida dopiranog manganom
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. urn:nbn:hr:149:019863
Terzin, Andrej
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

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Terzin, A. (2020). Oksidacija čađe katalizirana nanočesticama cerijeva (IV) oksida dopiranog manganom (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:019863

Terzin, Andrej. "Oksidacija čađe katalizirana nanočesticama cerijeva (IV) oksida dopiranog manganom." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:019863

Terzin, Andrej. "Oksidacija čađe katalizirana nanočesticama cerijeva (IV) oksida dopiranog manganom." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2020. https://urn.nsk.hr/urn:nbn:hr:149:019863

Terzin, A. (2020). 'Oksidacija čađe katalizirana nanočesticama cerijeva (IV) oksida dopiranog manganom', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 27 December 2024, https://urn.nsk.hr/urn:nbn:hr:149:019863

Terzin A. Oksidacija čađe katalizirana nanočesticama cerijeva (IV) oksida dopiranog manganom [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2020 [cited 2024 December 27] Available at: https://urn.nsk.hr/urn:nbn:hr:149:019863

A. Terzin, "Oksidacija čađe katalizirana nanočesticama cerijeva (IV) oksida dopiranog manganom", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2020. Available at: https://urn.nsk.hr/urn:nbn:hr:149:019863

Metadata
TitleOksidacija čađe katalizirana nanočesticama cerijeva (IV) oksida dopiranog manganom
Title (english)Soot oxidation catalyzed with manganese-doped ceria nanoparticles
AuthorAndrej Terzin
MentorStanislav Kurajica (mentor)
Committee memberStanislav Kurajica (predsjednik povjerenstva)
Committee memberJuraj Šipušić (član povjerenstva)
Committee memberDavor Dolar (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2020-09-22, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Basic Technical Sciences
Abstract
Cerijev(IV) oksid, CeO2 koristi se kao katalizator raznih reakcija oksidacije i redukcije u brojnim industrijskim granama. U novije vrijeme, intenzivno se istražuje za primjenu u automobilima sa dizelskim motorima u svrhu razgradnje štetnih plinova te katalitičke oksidacije čađe. Visoka katalitička učinkovitost CeO2 rezultat je visoke mobilnosti kisika i kapacitetu skladištenja kisika unutar rešetke te mogućnosti stvaranja vakancija kisika. Dopiranjem cerijava(IV) oksida manganom dolazi do ulaska manganovih atoma u kristalnu rešetku CeO2 i poboljšanja njegovih katalitičkih svojstava. Hidrotermalnom sintezom su pripremljeni uzorci nanokristala čistog CeO2 i CeO2 dopiranog sa 10, 20 i 30 % mangana. Uzorci su termički obrađeni te analizirani raznim metodama kako bi se ispitala morfologija te utjecaj mangana na termičku stabilnost cerijeva(IV) oksida. Osim toga ispitan je utjecaj čistog i dopiranog CeO2 na proces katalitičke oksidacije čađe. Dobiveni rezultati upućuju na povećanje termičke stabilnosti i katalitičke aktivnosti cerija(IV) oksida, kada je u njegovoj kristalnoj strukturi prisutan mangan.
Abstract (english)
Ceria, CeO2 is used as a catalyst for different oxidation and reduction reactions throughout the industries. In recent times, it is extensively studied for the catalytic soot oxidation and degradation of harmful gasses in vehicles with diesel engines. High catalytic activity of CeO2 can be attributed to high oxygen mobility and oxygen storage capacity, together with its ability to form oxygen vacancies. When doping ceria with manganese, manganese atoms enter the crystal lattice of CeO2 and improve its catalytic properties. Nanocrystals of pure and ceria doped with 10, 20 and 30 % of manganese were prepared via hydrothermal synthesis. The samples were annealed and analysed by various methods to study morphology and the impact of manganese on thermal stability of ceria. Also, the influence of pure and doped ceria as catalyst for soot oxidation was studied. Obtained results indicate that doping of ceria increased thermal stability and catalytic activity.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:019863
ProjectNumber: IP-2018-01-2963
Title: Hidrotermalna sinteza dopiranog cerij oksidnog nanokatalizatora
Acronym: HOuDiNI
Leader: Stanislav Kurajica
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: Applied Chemistry - Undergraduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry
Course: Advanced materials and technologies
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
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Created on2023-05-09 09:22:10