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undergraduate thesis
Solvatokromna bojila u kemijskim optičkim senzorima: mehanizam detekcije
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2019. urn:nbn:hr:149:656933
Gudan Pavlović, Iva
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Gudan Pavlović, I. (2019). Solvatokromna bojila u kemijskim optičkim senzorima: mehanizam detekcije (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:656933

Gudan Pavlović, Iva. "Solvatokromna bojila u kemijskim optičkim senzorima: mehanizam detekcije." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2019. https://urn.nsk.hr/urn:nbn:hr:149:656933

Gudan Pavlović, Iva. "Solvatokromna bojila u kemijskim optičkim senzorima: mehanizam detekcije." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2019. https://urn.nsk.hr/urn:nbn:hr:149:656933

Gudan Pavlović, I. (2019). 'Solvatokromna bojila u kemijskim optičkim senzorima: mehanizam detekcije', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 20 December 2024, https://urn.nsk.hr/urn:nbn:hr:149:656933

Gudan Pavlović I. Solvatokromna bojila u kemijskim optičkim senzorima: mehanizam detekcije [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2019 [cited 2024 December 20] Available at: https://urn.nsk.hr/urn:nbn:hr:149:656933

I. Gudan Pavlović, "Solvatokromna bojila u kemijskim optičkim senzorima: mehanizam detekcije", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:149:656933

Metadata
TitleSolvatokromna bojila u kemijskim optičkim senzorima: mehanizam detekcije
Title (english)Solvatochromic dyes in optical chemical sensors: mechanism of detection
AuthorIva Gudan Pavlović
MentorIvana Steinberg (mentor)
Committee memberIvana Steinberg (predsjednik povjerenstva)
Committee memberPetar Kassal (član povjerenstva)
Committee memberLjerka Kratofil Krehula (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2019-09-11, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Tema rada je primjena solvatokromnih bojila u kemijskim optičkim senzorima s naglaskom na mehanizme detekcije. Ion-selektivni optički senzori sa solvatokromnim bojilima kao pretvorničkim elementima predstavljaju unapređenje klasičnih ion-selektivnih optoda s H+ kromoionoforima. Primjena solvatokromnih bojila omogućuje izradu pH neosjetljivih ion-selektivnih optičkih senzora. U radu su opisani mehanizmi detekcije ion-selektivnih optičkih senzora sa solvatokromnim bojilima. Izložen je pregled literature vezan uz trendove razvoja senzora. Eksperimentalno je izrađen i ispitan senzor sa solvatokromnim bojilom 3,3'-diheksadeciloksakarbocijanin perklorat (DiOC16(3)) na papiru kao supstratu osjetljiv na ione kalija. Potvrđena je neosjetljivost na promjenu pH u rasponu 1-10, određena je kalibracijska krivulja, područje osjetljivosti i vrijeme odziva optode. Senzor omogućava određivanje koncentracije kalija u intervalu od 3,16∙10^-2 M do 1 M u nepuferiranim otopinama te pokazuje dobru reverzibilnost. Vrijeme odziva optode kraće je od 3 minute.
Abstract (english)
The topic of the thesis is application of solvatochromic dyes in chemical optical sensors, with emphasis on detection mechanisms. Ion-selective optical sensors based on solvatochromic dyes can be viewed as upgrades of conventional ion-selective optical sensors that are based on H+ chromoionophores. The application of solvatochromic dyes leads to sensor pH insensitivity. Detection mechanisms of ion-selective optical sensors with solvatochromic dyes are described in work. A literature review related to sensor development trends is presented in the thesis. A potassium sensitive sensor with solvatochromic dye 3,3'-dihexadecyloxacarbocyanine perchlorate (DiOC16(3)) was fabricated on a paper substrate and experimentally tested. Insensitivity to pH in the interval 1-10 was confirmed. Calibration curve, sensitivity range and sensor response time were determined. The sensor allows the determination of potassium concentrations in the range from 3.16∙10^-2 M to 1 M in non-buffered solutions and shows good reversibility. The sensor response time is less than 3 minutes.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:656933
Study programmeTitle: Materials Science and Engineering - Undergraduate study
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
Access conditionsAccess restricted to students and staff of home institution
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Created on2023-05-10 09:02:49