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undergraduate thesis
Referentna elektroda srebro/srebrov klorid bez unutarnjeg elektrolita temeljena na poli(vinil-butiralu)
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2023. urn:nbn:hr:149:246214
Vojvodić, Hrvoje
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

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Vojvodić, H. (2023). Referentna elektroda srebro/srebrov klorid bez unutarnjeg elektrolita temeljena na poli(vinil-butiralu) (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:246214

Vojvodić, Hrvoje. "Referentna elektroda srebro/srebrov klorid bez unutarnjeg elektrolita temeljena na poli(vinil-butiralu)." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2023. https://urn.nsk.hr/urn:nbn:hr:149:246214

Vojvodić, Hrvoje. "Referentna elektroda srebro/srebrov klorid bez unutarnjeg elektrolita temeljena na poli(vinil-butiralu)." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2023. https://urn.nsk.hr/urn:nbn:hr:149:246214

Vojvodić, H. (2023). 'Referentna elektroda srebro/srebrov klorid bez unutarnjeg elektrolita temeljena na poli(vinil-butiralu)', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 22 November 2024, https://urn.nsk.hr/urn:nbn:hr:149:246214

Vojvodić H. Referentna elektroda srebro/srebrov klorid bez unutarnjeg elektrolita temeljena na poli(vinil-butiralu) [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2023 [cited 2024 November 22] Available at: https://urn.nsk.hr/urn:nbn:hr:149:246214

H. Vojvodić, "Referentna elektroda srebro/srebrov klorid bez unutarnjeg elektrolita temeljena na poli(vinil-butiralu)", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2023. Available at: https://urn.nsk.hr/urn:nbn:hr:149:246214

Metadata
TitleReferentna elektroda srebro/srebrov klorid bez unutarnjeg elektrolita temeljena na poli(vinil-butiralu)
Title (english)Silver/silver chloride reference electrode without internal electrolyte based on polyvinyl butyral
AuthorHrvoje Vojvodić
MentorPetar Kassal (mentor)
Committee memberPetar Kassal (predsjednik povjerenstva)
Committee memberIrena Ivanišević (član povjerenstva)
Committee memberIgor Dejanović (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2023-07-07, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U ovom radu formirane su dvije izvedbe čvrstofaznih referentnih elektroda (SSRE, solid-state reference electrode). Prva izvedba (RM1) temelji se na nanošenju zaštitne membrane od poli(vinil butirala) (PVB) na kemijski kloriranu srebrnu elektrodu. Za drugu izvedbu (RM2) formulirana je PVB-membrana zasićena srebrom, srebrovim kloridom te natrijevim kloridom. Membrane su prvo nanesene na disk elektrode: RM1 na srebrnu elektrodu te RM2 na elektrodu od staklastog ugljika (GC-elektroda). Po sušenju i kondicioniranju, provedeno je potenciometrijsko testiranje elektroda u nizu standardnih otopina širokog raspona koncentracija, uključujući: KCl, NaCl, CaCl2 te NaNO3. Ispitan je utjecaj pH na elektrodni odziv, za što je korišten citratni pufer širokog raspona pH vrijednosti od 2 do 12. Primjenjivost ovako pripremljenih elektroda ispitana je u postupku baždarenja komercijalne natrijeve ionsko-selektivne elektrode. Nakon što je potvrđena zahtijevana naponska stabilnost pripremljenih SSRE, proveden je transfer na inkjet ispisane Ag-elektrode na PET podlozi. RM1 i RM2 su nakapane na ispisane elektrode te su elektrokemijski ispitane jednako kao disk elektrode. Cilj je ispisivanje plošnih all-solid-state elektroda koje bi doprinijele optimizaciji i minijaturizaciji elektrokemijskih senzornih sustava.
Abstract (english)
In this work, two versions of solid-state reference electrodes (SSRE) were formed. For the first one, a protective poly(vinyl butyral) membrane (RM1) was drop-cast on a chemically chlorinated disc Ag-electrode. The second realization was made by drop-casting a PVB membrane saturated with silver, silver chloride and sodium chloride (RM2) on a disc glassy carbon electrode (GC-electrode). After drying and conditioning, potentiometric testing of the electrodes was performed in a number of standard solutions having a wide range of concentrations, including: KCl, NaCl, CaCl2 and NaNO3. The influence of pH on the electrode response was investigated, for which a citrate buffer with a wide pH range from 2 to 12 was used. After the required voltage stability of the prepared SSREs was confirmed, a transfer to inkjet printed Ag-electrodes on a PET substrate was performed. RM1 and RM2 were drop-cast on the printed electrodes. These were electrochemically tested in the same way as the disk electrodes. This work aimed to make sustainable all-solid-state horizontal electrodes that would optimize and miniaturize electronics and sensor units.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:246214
ProjectNumber: UIP-2020-02-9139
Title: Fotonsko sinteriranje inkjet ispisanih elektrokemijskih senzora i biosenzora na plastičnim podlogama
Title: Photonic sintering for inkjet printed electrochemical sensors and biosensors on plastic substrates
Acronym: PrintEChemSens
Leader: Petar Kassal
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: UIP
Study programmeTitle: Applied Chemistry - Undergraduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry
Course: Advanced materials and technologies
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2023-07-25 14:29:45