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doctoral thesis
Mechanochemical strategies for synthesis and modification of functional metal-organic frameworks
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2024. urn:nbn:hr:149:573978
Martinez, Valentina
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Martinez, V. (2024). Mechanochemical strategies for synthesis and modification of functional metal-organic frameworks (Doctoral thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:573978

Martinez, Valentina. "Mechanochemical strategies for synthesis and modification of functional metal-organic frameworks." Doctoral thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2024. https://urn.nsk.hr/urn:nbn:hr:149:573978

Martinez, Valentina. "Mechanochemical strategies for synthesis and modification of functional metal-organic frameworks." Doctoral thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2024. https://urn.nsk.hr/urn:nbn:hr:149:573978

Martinez, V. (2024). 'Mechanochemical strategies for synthesis and modification of functional metal-organic frameworks', Doctoral thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 29 November 2024, https://urn.nsk.hr/urn:nbn:hr:149:573978

Martinez V. Mechanochemical strategies for synthesis and modification of functional metal-organic frameworks [Doctoral thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2024 [cited 2024 November 29] Available at: https://urn.nsk.hr/urn:nbn:hr:149:573978

V. Martinez, "Mechanochemical strategies for synthesis and modification of functional metal-organic frameworks", Doctoral thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2024. Available at: https://urn.nsk.hr/urn:nbn:hr:149:573978

Metadata
TitleMechanochemical strategies for synthesis and modification of functional metal-organic frameworks
Title (croatian)Mehanokemijske strategije za sintezu i modifikaciju funkcionalnih metalo-organskih mreža
AuthorValentina Martinez
MentorKrunoslav Užarević (mentor)
MentorIgor Dejanović (mentor)
Committee memberErnest Meštrović (predsjednik povjerenstva)
Committee memberPetar Kassal (član povjerenstva)
Committee memberMirta Rubčić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2024-07-12, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Inorganic Chemistry
Universal decimal classification
(UDC)		54 - Chemistry. Crystallography. Mineralogy
Abstract
Metal-organic frameworks (MOF) are among the most researched porous materials due to the tunability of their physico-chemical properties through structural changes and broad application potential. Mechanochemical MOF synthesis is a sustainable and often superior alternative to solution MOF synthesis. Therefore, this work aimed to advance mechanochemical strategies for the synthesis and modification of MOFs and their unconventional derivatives by using two well-investigated MOF classes, ZIF-8 and MOF-74. It involved the development of the controllable mechanochemical synthetic strategy for the encapsulation of functional guests into MOFs, using the encapsulation of Buckminsterfullerene into ZIF-8 as a model system. Moreover, it explored the preparation of both crystalline and amorphous phases of multivariate MOFs, bimetallic zinc-copper MOF-74 materials through diverse synthetic pathways, including mechanochemical amorphisation. The results have demonstrated that the selection of an appropriate synthetic strategy significantly affects the physical and chemical characteristics and the possible applications of explored MOFs.
Abstract (croatian)
Metalo-organske mreže (MOF) među najistraživanim su poroznim materijalima zbog prilagodljivosti njihovih fizikalno-kemijskih svojstava kroz modifikacije u strukturi i širokog potencijala primjene. Mehanokemijska sinteza MOF-ova održiva je i često nadmoćnija alternativa otopinskoj sintezi MOF-ova. Stoga je cilj ovog rada bio unaprijediti mehanokemijske strategije sinteze i modifikacije MOF-ova kao i njihovih nekonvencionalnih derivata, korištenjem dvije dobro istražene grupe MOF-ova, ZIF-8 i MOF-74. To je uključivalo razvoj kontrolirane mehanokemijske sintetske strategije za enkapsulaciju funkcionalnih gostiju u MOF-ove, koristeći enkapsulaciju Buckminsterfullerena u ZIF-8 kao modelni sustav. Nadalje, istraživana je priprema kristalnih i amorfnih faza multivarijantnih MOF-ova, bimetalnih cink-bakarnih MOF-74 materijala različitim sintetskim putevima, uključujući mehanokemijsku amorfizaciju. Rezultati su pokazali da odabir odgovarajuće sintetske strategije značajno utječe na fizikalna i kemijska svojstva te na moguću primjenu istraženih MOF-ova.
Keywords
Keywords (croatian)
Languageenglish
URN:NBNurn:nbn:hr:149:573978
Promotion2024
ProjectNumber: PZS-2019-02-4129
Title: Mehanokemijske i bezotopinske strategije za sintezu funkcionalnih poroznih materijala s naprednim fizičko-kemijskim i katalitičkim svojstvima
Title: Mechanochemical and solvent-free strategies towards functional porous materials with advanced physico-chemical and catalytic properties
Acronym: MECHADVANCE
Leader: Krunoslav Užarević
Jurisdiction: Croatia
Funder: Hrvatska zaklada za znanost
Funding stream: Programme Research Cooperability
Study programmeTitle: Chemical Engineering and Applied Chemistry - Doctoral course
Study programme type: university
Study level: postgraduate
Academic / professional title: doktor/doktorica znanosti u području prirodnih znanosti (doktor/doktorica znanosti u području prirodnih znanosti)
Type of resourceText
Extent141 str. ; 30 cm
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2024-09-01
Terms of useLicence In copyright icon
Public noteSkandinavski model
Created on2024-07-22 10:10:00