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master's thesis
Optimiranje svojstava polimernih materijala za izradu mikroreaktora
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. urn:nbn:hr:149:103083
Lovrinov, Tea
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Lovrinov, T. (2017). Optimiranje svojstava polimernih materijala za izradu mikroreaktora (Master's thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:103083

Lovrinov, Tea. "Optimiranje svojstava polimernih materijala za izradu mikroreaktora." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:103083

Lovrinov, Tea. "Optimiranje svojstava polimernih materijala za izradu mikroreaktora." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:103083

Lovrinov, T. (2017). 'Optimiranje svojstava polimernih materijala za izradu mikroreaktora', Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 22 November 2024, https://urn.nsk.hr/urn:nbn:hr:149:103083

Lovrinov T. Optimiranje svojstava polimernih materijala za izradu mikroreaktora [Master's thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2017 [cited 2024 November 22] Available at: https://urn.nsk.hr/urn:nbn:hr:149:103083

T. Lovrinov, "Optimiranje svojstava polimernih materijala za izradu mikroreaktora", Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:149:103083

Metadata
TitleOptimiranje svojstava polimernih materijala za izradu mikroreaktora
Title (english)Optimization of polymeric materials properties for manufacturing of microreactors
AuthorTea Lovrinov
MentorDomagoj Vrsaljko (mentor)
Committee memberDomagoj Vrsaljko (predsjednik povjerenstva)
Committee memberZrinka Buhin Šturlić (član povjerenstva)
Committee memberZvonimir Katančić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2017-09-26, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Chemical Engineering in Material Development
Abstract
Akrilonitril/butadien/stiren (ABS) je jedan od najčešće korištenih polimera za 3D tisak proizvoda. Cilj ovog rada bio je optimirati svojstva polimernih materijala na osnovi ABS-a za proizvodnju mikroreaktora navedenom tehnologijom. U tu su svrhu pripremljene mješavine ABS-a s polietilenom visoke (PE-HD) i polietilenom niske gustoće (PE-LD) u različitim omjerima. Osim navedenih, ispitane su i mješavine sa silikom te titanijevim dioksidom kao punilom kako bi se dobio uvid u njihov utjecaj kao kompatibilizatora između nemješljivih polimera. Uzorci su pripremljeni umješavanjem u ekstruderu te su im određena mehanička svojstva rasteznim ispitivanjem. Mješavinama s najboljim mehaničkim svojstvima nadalje su ispitane toplinske karakteristike razlikovnom pretražnom kalorimetrijom te morfologija površine pomoću pretražnog elektronskog mikroskopa. Na temelju dobivenih rezultata zaključeno je kako dodatak polietilena ABS-u znatno mijenja njegova mehanička svojstva, prvenstveno smanjuje visoku vlačnu čvrstoću. Dodatak punila kod mješavina uglavnom djeluje povoljno na mehanička svojstva, a najbolje su rezultati pokazale mješavine s dodanih 5 % PE-LD-a, odnosno PE-HD-a. Ispitivanjem toplinskih svojstava i morfologije površine potvrđeno je kako korišteni polimeri stvaraju nemješljive sustave.
Abstract (english)
Acrylonitrile/butadiene/styrene (ABS) is one of the most commonly used polymers for 3D printing of products. The aim of this paper was to optimize the properties of ABS based polymeric materials for 3D printing of microreactors. For this purpose, high-density polyethylene (PE-HD) and low density polyethylene (PE-LD) mixtures with ABS were prepared in different ratios. In addition to these, silica and titanium dioxide as fillers were also tested to provide an insight into their influence as a compatibilizer in blending these immiscible polymers. The samples were prepared by melt mixing in Brabender plasticoder and their mechanical properties were determined by a tensile test. The selected mixtures were further tested for thermal properties by differential scanning calorimetry and surface morphology using a scanning electron microscope. Based on the obtained results, it was concluded that the addition of polyethylene to ABS significantly alters its mechanical properties, primarily reducing the high tensile strength. The addition of filler to the blend mostly works favorably on the mechanical properties, and the best results were achieved by the blends in which 5 % PE-LD or PE-HD were added. By examining the thermal properties and surface morphology, it was confirmed that the polymers create imiscible blends.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:103083
Study programmeTitle: Chemical Engineering - Graduate study
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra inženjer/inženjerka kemijskog inženjerstva (magistar/magistra inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2020-04-22 13:11:36