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master's thesis
Novel heterogeneous photoredox transformations using organic materials
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. urn:nbn:hr:149:847191
Cazin, Ines
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

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Cazin, I. (2017). Novel heterogeneous photoredox transformations using organic materials (Master's thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:847191

Cazin, Ines. "Novel heterogeneous photoredox transformations using organic materials." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:847191

Cazin, Ines. "Novel heterogeneous photoredox transformations using organic materials." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:847191

Cazin, I. (2017). 'Novel heterogeneous photoredox transformations using organic materials', Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 27 December 2024, https://urn.nsk.hr/urn:nbn:hr:149:847191

Cazin I. Novel heterogeneous photoredox transformations using organic materials [Master's thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2017 [cited 2024 December 27] Available at: https://urn.nsk.hr/urn:nbn:hr:149:847191

I. Cazin, "Novel heterogeneous photoredox transformations using organic materials", Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:149:847191

Metadata
TitleNovel heterogeneous photoredox transformations using organic materials
Title (croatian)Nove heterogene fotoreduktivne transformacije organskih materijala
AuthorInes Cazin
MentorSilvana Raić-Malić (mentor)
Committee memberSilvana Raić-Malić (predsjednik povjerenstva)
Committee memberIrena Škorić (član povjerenstva)
Committee memberPetar Kassal (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2017-09-28, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Organic Chemistry
Abstract
Recently, photoredox catalysis has become a popular tool in organic synthesis with a plethora of interesting applications. In 2014, Sammis and co-workers reported decarboxylative fluorination using Ru(bpy)3Cl2 as a visible-light photoredox catalyst (PRC) in the presence of Selectfluor. More recently (2015), MacMillan and co-workers reported the decarboxylative fluorination with Ir[dF(CF3)ppy]2(dtbbpy)PF6. Despite the excellent properties of ruthenium and iridium polypyridyl complexes in PRC, these catalyses are expensive, potentially toxic, and usually not recycled. Compared to these transition metal based homogeneous catalysts, graphitic carbon nitrides (g-C3N4) are a class of pure organic, heterogeneous, and therefore, recyclable semiconducting materials with great potential for photoredox catalysis. The aim of this research is to replace the Ir[dF(CF3)ppy]2(dtbbpy)PF6 and Ru(bpy)3Cl2 catalysts with a modified CMB-C3N4 heterogeneous catalyst for the decarboxylative fluorination of carboxylic acids under visible irradiation at room temperature.
Abstract (croatian)
U posljednje vrijeme je fotoredutkivna kataliza postala popularno sredstvo u organskoj sintezi s nizom zanimljivih primjena. 2014. godine Sammis i suradnici su izveli dekarboksilativno fluoriranje pomoću Ru(bpy)3Cl2 kao fotoreduktivnim katalizatorom u području vidljive svjetlosti (PRC) u prisutnosti Selectfluora. U novije vrijeme (2015.), MacMillan i suradnici izveli su dekarboksilativno fluoriranje s Ir[dF(CF3)ppy]2(dtbbpy)PF6. Unatoč izvrsnim svojstvima rutenskih i iridijskih polipiridilnih kompleksa u području vidljive svjetlosti, ti su katalizatori skupi, potencijalno toksični i obično se ne recikliraju. U usporedbi s homogenim katalizatorima na bazi prijelaznih metala, grafitni ugljični nitridi (g-C3N4) klasa su čistih organskih, heterogenih i stoga reciklabilnih poluvodičkih materijala s velikim potencijalom za fotoredutkivno kataliziranje. Cilj ovog istraživanja je zamijeniti Ir[dF(CF3)ppy]2(dtbbpy)PF66 i Ru(bpy)3Cl2 katalizatore modificiranim CMB-C3N4 heterogenim katalizatorom za dekarboksilativnu fluorizaciju karboksilnih kiselina uz vidljivo zračenje pri sobnoj temperaturi.
Keywords
Keywords (croatian)
Languageenglish
URN:NBNurn:nbn:hr:149:847191
Study programmeTitle: Applied Chemistry - Graduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry
Course: Applied organic chemistry
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra primijenjene kemije (magistar/magistra primijenjene kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2020-05-25 15:26:48