prikaz prve stranice dokumenta Priprava poroznih nosača za uklanjanje industrijskih bojila iz vodene otopine
  Download
PDF 2.12 MB
master's thesis
Priprava poroznih nosača za uklanjanje industrijskih bojila iz vodene otopine
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. urn:nbn:hr:149:501961
Perčić, Maja
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Perčić, M. (2017). Priprava poroznih nosača za uklanjanje industrijskih bojila iz vodene otopine (Master's thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:501961

Perčić, Maja. "Priprava poroznih nosača za uklanjanje industrijskih bojila iz vodene otopine." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:501961

Perčić, Maja. "Priprava poroznih nosača za uklanjanje industrijskih bojila iz vodene otopine." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:501961

Perčić, M. (2017). 'Priprava poroznih nosača za uklanjanje industrijskih bojila iz vodene otopine', Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 23 June 2024, https://urn.nsk.hr/urn:nbn:hr:149:501961

Perčić M. Priprava poroznih nosača za uklanjanje industrijskih bojila iz vodene otopine [Master's thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2017 [cited 2024 June 23] Available at: https://urn.nsk.hr/urn:nbn:hr:149:501961

M. Perčić, "Priprava poroznih nosača za uklanjanje industrijskih bojila iz vodene otopine", Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:149:501961

Metadata
TitlePriprava poroznih nosača za uklanjanje industrijskih bojila iz vodene otopine
Title (english)Preparation of porous scaffolds for industrial dyes removal from aqueous solution
AuthorMaja Perčić
MentorMarica Ivanković (mentor)
Committee memberMarica Ivanković (predsjednik povjerenstva)
Committee memberAnamarija Rogina (član povjerenstva)
Committee memberHrvoje Ivanković (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2017-09-28, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Chemical Engineering in Material Development
Abstract
Sintetička bojila u velikoj su mjeri prisutna u otpadnim vodama industrije papira, tekstila i plastike. Mnoga bojila u svojoj strukturi sadrže aromatske prstene, što ih čini otrovnim i kancerogenim. S ciljem smanjenja rizika od onečišćenja okoliša, potrebno je tretiranje otpadnih voda prije ispusta u okoliš. Postoji nekoliko metoda koje se primjenjuju za uklanjanje bojila iz obojenih otpadnih voda poput koagulacije, oksidacije, adsorpcije, membranske filtracije i biološke obrade. Između tih tehnika, adsorpcija je okarakterizirana kao jedna od najučinkovitijih metoda zbog svoje jednostavnosti, isplativosti i energetske učinkovitosti. Iako postoje brojni nekonvencionalni jeftini adsorbensi koji se primjenjuju za uklanjanje bojila, velika je pozornost usmjerena prema polisaharidima poput kitozana. Ovaj biokompatibilni polimer posjeduje nekoliko karakteristika koje ga čine učinkovitim adsorbensom za uklanjanje bojila. U ovom radu pripravljeni su materijali na temelju kitozana kao polimerne biokompatibilne i biorazgradljive matrice i hidroksiapatita kao anorganske faze. Porozna struktura kitozana te kompozita postignuta je metodom toplinski inducirane fazne separacije uz geliranje i ekstrakciju. Sastav pripravljenih nosača utvrđen je rendgenskom difrakcijskom analizom i infracrvenom spektroskopijom s Fourierovim transformacijama. Morfologija materijala istražena je pomoću pretražnog elektronskog mikroskopa. Materijalima je određena poroznost, stupanj bubrenja te Youngov modul elastičnosti. Kitozan i njegov kompozit te aktivni ugljen kao kontrolni adsorbens korišteni su za uklanjanje bojila Congo Red iz vodene otopine. Provela se kinetička analiza adsorpcije i usporedila s kinetičkim modelima koji uobičajno opisuju proces adsorpcije. Regeneracija korištenih nosača se provela s ciljem ponovne upotrebe materijala nakon adsorpcije bojila.
Abstract (english)
Synthetic dyes widely exist in the wastewaters of industries such as textiles, paper and plastics. Many dyes contain aromatic rings in their structures, which make them toxic and carcinogenic. In order to reduce risk of environmental pollution, it is necessary to treat the wastewaters before releasing them into the environment. There are several methods for dyes removal from colored wastewaters such as coagulation, oxidation, adsorption, membrane filtration and biological treatment. Among these techniques, adsorption is characterized as one of the most effective methods due to it's simplicity, cost and energy efficiency. There are numerous non-conventional low-cost adsorbent materials that are used for dye removal, however, special attention has been given to polysaccharides such as chitosan. This biocompatible polymer possesses several characteristics that make it an effective biosorbent for dye removal. Materials based on chitosan as biocompatible and biodegradable matrix and hydroxyapatite as inorganic phase were prepared in this study. Porous structures of chitosan and its composite has been obtained by freeze-gelation method. The composition of prepared scaffolds was carried out by X-ray diffraction analysis and Fourier-transform infrared spectroscopy. The morfology of materials was imaged by scanning electron microscopy. Chitosan and its composite and activated carbon as control adsorbent have been used as the adsorbents for removal of Congo Red dye from aqueous solution. The analysis of adsorption kinetics was carried out while behaviour of dye removal was evaluated by kinetic models that usually describe adsorption process. In order to reuse the materials after adsorption of Congo Red, regeneration of pre-adsorbed scaffolds was done.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:501961
Study programmeTitle: Chemical Engineering - Graduate study
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra inženjer/inženjerka kemijskog inženjerstva (magistar/magistra inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2020-05-26 04:59:59