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undergraduate thesis
Sinteza i spektroskopska karakteristika novih derivata fenantrena i nafto[2,1-b]tiofena
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. urn:nbn:hr:149:342173
Kadić, Matej
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

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Kadić, M. (2017). Sinteza i spektroskopska karakteristika novih derivata fenantrena i nafto[2,1-b]tiofena (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:342173

Kadić, Matej. "Sinteza i spektroskopska karakteristika novih derivata fenantrena i nafto[2,1-b]tiofena." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:342173

Kadić, Matej. "Sinteza i spektroskopska karakteristika novih derivata fenantrena i nafto[2,1-b]tiofena." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:342173

Kadić, M. (2017). 'Sinteza i spektroskopska karakteristika novih derivata fenantrena i nafto[2,1-b]tiofena', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 04 November 2024, https://urn.nsk.hr/urn:nbn:hr:149:342173

Kadić M. Sinteza i spektroskopska karakteristika novih derivata fenantrena i nafto[2,1-b]tiofena [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2017 [cited 2024 November 04] Available at: https://urn.nsk.hr/urn:nbn:hr:149:342173

M. Kadić, "Sinteza i spektroskopska karakteristika novih derivata fenantrena i nafto[2,1-b]tiofena", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:149:342173

Metadata
TitleSinteza i spektroskopska karakteristika novih derivata fenantrena i nafto[2,1-b]tiofena
Title (english)Synthesis and spectroscopic characterization of novel phenantrene and naphtho[2,1-b]thiophene derivatives
AuthorMatej Kadić
MentorMarijana Hranjec (mentor)
Committee memberMarijana Hranjec (predsjednik povjerenstva)
Committee memberNataša Perin (član povjerenstva)
Committee memberLidija Furač (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2017-09-05, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Organic Chemistry
Abstract
Cilj ovog rada bio je sintetizirati nove amido supstituirane derivate nafto[2,1-b]tiofena 7-8 i amido supstituirane derivate fenantrena 14-15. Za pripravu ciljnih spojeva korištene su klasične metode organske i fotokemijske sinteze. Aciklički derivati akrilonitrila 3 i 10 priređeni su kondenzacijom aldehida i odgovarajućih acetonitrila. Bazičnom hidrolizom cikličkih cijano derivata 4 i 11 priređene su odgovarajuće karboksilne kiseline 5 i 12. Amido supstituirani derivati nafto[2,1-b]tiofena 7-8 priređeni su iz nafto[2,1-b]tiofen-9-karbonil-klorida 6 reakcijom s odgovarajućim aminima, dok je amido supstituirani derivat fenantrena 15 priređen iz fenantren-9-karbonil-klorida 13. Strukture svih novo priređenih spojeva potvrđene su 1H NMR i 13C NMR spektroskopijom. Sinteza amido supstituiranog derivata fenantrena 14 nije bila uspješna.
Abstract (english)
The intention of this study was to synthesize new amido substituted derivatives of naphto[2,1-b]thiophenes 7-8 and amido supstituted derivatives of phenanthrenes 14-15. For the synthesis of target compounds classical methods of organic synthesis and photochemical synthesis were used. Acyclic acrylonitriles 3 and 10 were obtained in the condensation of aldehydes and corresponding acetonitriles. Carboxylic acids 5 and 12 were prepared by basic hydrolysis of cyano substituted derivatives 4 and 11. Amido supstituted derivatives of naphto[2,1-b]thiophene 7-8 were prepared from naphto[2,1-b]thiophene-9-carbonyl-chloride 6 in the nucleophilyc substitution reaction with the appropriate amines, and amido substituted derivative of phenanthrene 15 was prepared from phenanthrene-9-carbonyl-chloride 13. Synthesis of amido derivativeof phenanthrene 14 was not successful. The structures of all newly synthesizes compounds were confirmed by means of 1H NMR and 13C NMR spectroscopy.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:342173
Study programmeTitle: Chemical Engineering - Undergraduate study
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
Access conditionsOpen access
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Created on2021-01-08 12:51:52