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undergraduate thesis
Odabir pseudoreferentne elektrode za sustav unutarnje katodne zaštite
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. urn:nbn:hr:149:773032
Šimanović, Barbara
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

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Šimanović, B. (2017). Odabir pseudoreferentne elektrode za sustav unutarnje katodne zaštite (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:773032

Šimanović, Barbara. "Odabir pseudoreferentne elektrode za sustav unutarnje katodne zaštite." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:773032

Šimanović, Barbara. "Odabir pseudoreferentne elektrode za sustav unutarnje katodne zaštite." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2017. https://urn.nsk.hr/urn:nbn:hr:149:773032

Šimanović, B. (2017). 'Odabir pseudoreferentne elektrode za sustav unutarnje katodne zaštite', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 04 November 2024, https://urn.nsk.hr/urn:nbn:hr:149:773032

Šimanović B. Odabir pseudoreferentne elektrode za sustav unutarnje katodne zaštite [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2017 [cited 2024 November 04] Available at: https://urn.nsk.hr/urn:nbn:hr:149:773032

B. Šimanović, "Odabir pseudoreferentne elektrode za sustav unutarnje katodne zaštite", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:149:773032

Metadata
TitleOdabir pseudoreferentne elektrode za sustav unutarnje katodne zaštite
Title (english)Selection of pseudo-reference electrode for internal cathodic protection system
AuthorBarbara Šimanović
MentorHelena Otmačić Ćurković (mentor)
Committee memberHelena Otmačić Ćurković (predsjednik povjerenstva)
Committee memberIgor Sutlović (član povjerenstva)
Committee memberSuzana Sopčić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2017-09-14, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Analysis, Synthesis and Management of Chemical Processes
Abstract
Ovaj rad baziran je na problemu iz prakse gdje je došlo do korozije unutarnje stjenke čeličnih bojlera te je bilo potrebno odabrati adekvatnu katodnu zaštitu. Cilj rada bio je ispitati mogućnost primjene različitih metalnih materijala kao pseudoreferentnih elektroda u sustavima unutarnje katodne zaštite. Metali na kojima se vršilo ispitivanje su titan, nikal-krom i bakar-nikal legura. Navedenim metalima određivao se korozijski potencijal pri različitim temperaturama u trajanju od 14 dana. Na početku te na kraju mjerenja za svaki metal provedena su ispitivanja metodom elektrokemijske impedancijske spektroskopije. Odabir pseudoreferentnih elektroda temelji se na stabilnosti njihovih potencijala i pouzdanosti. Najmanje oscilacije potencijala u vremenu, kao i najmanje razlike među pojedinim uzorcima primijećene su kod Cu-Ni legure dok su razlike najveće kod titana. Analizom standardne devijacije, odnosno usporedbom rasipanja vrijednosti potencijala utvrđeno je kako je uporaba legure Cu-Ni kao pseudoreferentne elektrode najpouzdanija, dok je najmanje pouzdana uporaba titana. Elektrokemijskom impedancijskom spektroskopijom dobiven je uvid u svojstva otpornosti ispitivanih metala. Za razliku od titana i legure Cr-Ni, kod legure Cu-Ni ne dolazi do nastanka pasivnog sloja pa ova legura pokazuje najmanju korozijsku otpornost.
Abstract (english)
This work is based on the problem from practice, where the corrosion of inner walls of steel boilers occurred and it was required to choose the adequate cathodic protection. The aim of the work was to examine the possibility of applying different metal materials as pseudo-reference electrodes in internal cathodic protection systems. The tested metals were titanium, nickel-chromium and copper-nickel alloy. The corrosion potential of these metals were examined at different temperatures during the period of 14 days. At the beginning and at the end of study, the electrochemical impedance spectroscopy was conducted. The selection of pseudo-reference electrodes is based on the stability of their potentials and obtained reliability. The slightest potential oscillations, as well as the lowest differences between the individual samples, were observed in Cu-Ni alloys, while the differences were highest in titanium. Based on the analysis of dispersion of measured potential values, it was established that the use of Cu-Ni alloys as a pseudo-reference electrode is the most reliable, while the use of titanium is the least reliable. The electrochemical impedance spectroscopy provided insight into the resistance properties of the tested metals. Unlike titanium and Cr-Ni alloy, Cu-Ni alloy does not exhibit any passivity properties and has proved to be the most prone to corrosion.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:773032
Study programmeTitle: Materials Science and Engineering - Undergraduate study
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva (sveučilišni/a prvostupnik/ prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
Access conditionsOpen access
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Created on2021-03-11 13:08:56