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undergraduate thesis
Fotokemijske transformacije 2-[2-(2-etenilfenil)etenil]-5-metiltiofena
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2018. urn:nbn:hr:149:990113
Lužaić, Ana
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

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Lužaić, A. (2018). Fotokemijske transformacije 2-[2-(2-etenilfenil)etenil]-5-metiltiofena (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:990113

Lužaić, Ana. "Fotokemijske transformacije 2-[2-(2-etenilfenil)etenil]-5-metiltiofena." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2018. https://urn.nsk.hr/urn:nbn:hr:149:990113

Lužaić, Ana. "Fotokemijske transformacije 2-[2-(2-etenilfenil)etenil]-5-metiltiofena." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2018. https://urn.nsk.hr/urn:nbn:hr:149:990113

Lužaić, A. (2018). 'Fotokemijske transformacije 2-[2-(2-etenilfenil)etenil]-5-metiltiofena', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 22 November 2024, https://urn.nsk.hr/urn:nbn:hr:149:990113

Lužaić A. Fotokemijske transformacije 2-[2-(2-etenilfenil)etenil]-5-metiltiofena [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2018 [cited 2024 November 22] Available at: https://urn.nsk.hr/urn:nbn:hr:149:990113

A. Lužaić, "Fotokemijske transformacije 2-[2-(2-etenilfenil)etenil]-5-metiltiofena", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:149:990113

Metadata
TitleFotokemijske transformacije 2-[2-(2-etenilfenil)etenil]-5-metiltiofena
Title (english)Photochemical transformation of 2-[2-(2-ethenylphenyl)ethenyl]-5-methylthiophene
AuthorAna Lužaić
MentorDragana Vuk (mentor)
Committee memberDragana Vuk (predsjednik povjerenstva)
Committee memberIvana Šagud (član povjerenstva)
Committee memberMarijana Kraljić Roković (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2018-07-12, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Organic Chemistry
Abstract
Cilj ovog rada je sintetizirati tiofenski derivat o-divinilbenzena kao prekursor za daljnju sintezu potencijalno aktivnih bioloških spojeva. β-supstituirani 5-tiofenski derivat o-divinilbenzena 1 sintetiziran je Wittigovom reakcijom u dva stupnja. Spoj 1 dobiven je u obliku smjese cis- i trans- izomera. Dobiveni spoj 1 okarakteriziran je 1H NMR spektroskopijom, UV spektroskopijom i masenom spektrometrijom nakon čega su napravljena preliminarna fotokemijska ispitivanja. Novosintetizirani derivat 1 podvrgnut je fotokemijskim reakcijama u smislu priprave novih policikličkih struktura fotokemijskom metodologijom. Očekivano je dobivanje novih složenih policikličkih struktura ovisno o elektronskom i steričkom utjecaju metilne skupine kao supstituenta u molekuli 1.
Abstract (english)
The aim of this work is to synthesize novel thiophene derivative of o-divinylbenzene as precursor for further synthesis of potencial biologicaly active agents. β-substituted thiophene derivative of o-divinylbenzene 1 was synthesized by two-step Wittig reaction. Compound 1 was obtained as cis- and trans- isomer. Compound 1 was isolated and characterized by 1H NMR spectroscopy, UV spectroscopy and mass spectrometry. Preliminary photochemical screening were also conducted on puriffied isomers and their photochemical reactivity were compared. New synthesized derivative 1 undergo photochemical reactions in terms of obtaining new polycyclic structures by photochemical methodology. Getting the new complex polycyclic structures which depends on the electronic and steric effects of methyl group was expected.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:990113
Study programmeTitle: Applied Chemistry - Undergraduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry
Course: Applied organic chemistry
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2021-06-23 11:48:03