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undergraduate thesis
Matematičko modeliranje kaskadne reakcije
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2018. urn:nbn:hr:149:848016
Grošić, Karla
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Grošić, K. (2018). Matematičko modeliranje kaskadne reakcije (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:848016

Grošić, Karla. "Matematičko modeliranje kaskadne reakcije." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2018. https://urn.nsk.hr/urn:nbn:hr:149:848016

Grošić, Karla. "Matematičko modeliranje kaskadne reakcije." Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2018. https://urn.nsk.hr/urn:nbn:hr:149:848016

Grošić, K. (2018). 'Matematičko modeliranje kaskadne reakcije', Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 23 November 2024, https://urn.nsk.hr/urn:nbn:hr:149:848016

Grošić K. Matematičko modeliranje kaskadne reakcije [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2018 [cited 2024 November 23] Available at: https://urn.nsk.hr/urn:nbn:hr:149:848016

K. Grošić, "Matematičko modeliranje kaskadne reakcije", Undergraduate thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:149:848016

Metadata
TitleMatematičko modeliranje kaskadne reakcije
Title (english)Mathematical modeling of a cascade reaction
AuthorKarla Grošić
MentorZvjezdana Findrik Blažević (mentor)
Committee memberZvjezdana Findrik Blažević (predsjednik povjerenstva)
Committee memberMartina Sudar (član povjerenstva)
Committee memberMarija Vuković Domanovac (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2018-09-10, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Reaction Engineering
Abstract
U ovom radu određena je kinetika oksidacije etanola u acetaldehid koja je katalizirana enzimom alkohol dehidrogenazom (ADH). Kinetički parametri procijenjeni su iz eksperimentalnih podataka ovisnosti početne brzine reakcije oksidacije etanola o koncentraciji etanola i NAD+. Ispitivana reakcija je sporedna reakcija u kaskadnoj reakciji koja se sastoji od oksidacije alkohola u aldehid te aldolne adicije acetaldehida na aldehid pri čemu nastaje konačni produkt laktol. Ova kaskadna reakcija također uključuje i regeneraciju koenzima NAD+ kataliziranu enzimom NADH oksidazom (NOX). Razvijen je matematički model kaskadne reakcije, te su provedene simulacije u programskom paketu SCIENTIST kako bi se ispitao utjecaj pojedine komponente u reakciji na konačnu koncentraciju aldolnog produkta.
Abstract (english)
In this work the kinetics of ethanol oxidation into acetaldehyde catalyzed by alcohol dehydrogenase (ADH) was determined. Kinetic parameters were estimated from the experimental data of dependence of the initial reaction rate on the concentration of ethanol and NAD+. This reaction is a side reaction in a cascade reaction of an alcohol oxidation to aldehyde and aldol addition of acetaldehyde to aldehyde in which the final product lactol is formed. This cascade reaction also includes a coenzyme regeneration of NAD+ catalyzed by NADH oxidase (NOX). Mathematical model for the cascade reaction was developed and used for simulations in the software package SCIENTIST. The influence of concentrations of different components of the reaction system on the final aldol product concentration was investigated.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:848016
ProjectNumber: 635595
Title: Sustainable industrial processes based on a C-C bond-forming enzyme platform
Acronym: CARBAZYMES
Leader: Zvjezdana Findrik Blažević
Jurisdiction: eu
Funder: EC
Funding stream: H2020
Study programmeTitle: Applied Chemistry - Undergraduate study; specializations in: Environmental chemistry and green technologies, Advanced materials and technologies, Applied organic chemistry
Course: Applied organic chemistry
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) primijenjene kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2021-06-24 13:01:48