prikaz prve stranice dokumenta Elektrokemijska karakterizacija tankih fotokatalitičkih filmova
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master's thesis
Elektrokemijska karakterizacija tankih fotokatalitičkih filmova
Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology, 2019. urn:nbn:hr:149:046850
Mesaroš, Nicole
University of Zagreb
Faculty of Chemical Engineering and Technology

Institutional repository: Repository of Faculty of Chemical Engineering and Technology University of Zagreb

Cite this document

Mesaroš, N. (2019). Elektrokemijska karakterizacija tankih fotokatalitičkih filmova (Master's thesis). Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:149:046850

Mesaroš, Nicole. "Elektrokemijska karakterizacija tankih fotokatalitičkih filmova." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2019. https://urn.nsk.hr/urn:nbn:hr:149:046850

Mesaroš, Nicole. "Elektrokemijska karakterizacija tankih fotokatalitičkih filmova." Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, 2019. https://urn.nsk.hr/urn:nbn:hr:149:046850

Mesaroš, N. (2019). 'Elektrokemijska karakterizacija tankih fotokatalitičkih filmova', Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, accessed 28 May 2024, https://urn.nsk.hr/urn:nbn:hr:149:046850

Mesaroš N. Elektrokemijska karakterizacija tankih fotokatalitičkih filmova [Master's thesis]. Zagreb: University of Zagreb, Faculty of Chemical Engineering and Technology; 2019 [cited 2024 May 28] Available at: https://urn.nsk.hr/urn:nbn:hr:149:046850

N. Mesaroš, "Elektrokemijska karakterizacija tankih fotokatalitičkih filmova", Master's thesis, University of Zagreb, Faculty of Chemical Engineering and Technology, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:149:046850

Metadata
TitleElektrokemijska karakterizacija tankih fotokatalitičkih filmova
Title (english)Electrochemical characterisation of photocatalytic thin films
AuthorNicole Mesaroš
MentorMarijana Kraljić Roković (mentor)
Committee memberMarijana Kraljić Roković (predsjednik povjerenstva)
Committee memberHelena Otmačić Ćurković (član povjerenstva)
Committee memberMarin Kovačić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Chemical Engineering and Technology
Zagreb
Defense date and country2019-07-08, Croatia
Scientific / art field,
discipline and subdiscipline		TECHNICAL SCIENCES
Chemical Engineering
Abstract
Cilj ovog rada bio je elektrokemijski okarakterizirati metalne okside koji se koriste u procesu fotokatalize. Provedeno je ispitivanje nanokompozita TiO2/SnS2 u otopini NaCl, s dodatkom i bez dodatka diklofenaka (DCF) te u otopini Na2SO4, s dodatkom i bez dodatka DCF. Osim toga, provedeno je ispitivanje elektrokemijski formiranog TiO2, koji je dobiven metodom kronoamperometrije na način da je titanska elektroda polarizirana tijekom 120 s na potencijalu od 1 V. Nanokompozitni fotokatalizator TiO2/SnS2 pripremljen je hidrotermalnom sintezom, a imobilizacija na titansku elektrodu je provedena metodom rotacijskog nanošenja. Elektrokemijske metode karakterizacije koje su korištene u ovom radu su ciklička voltametrija (CV), elektrokemijska impedancijska spektroskopija (EIS) i Mott-Schottky analiza. Pokazano je da je zaista došlo je do adsorpcije DCF-a na površinu fotokatalizatora, budući da se impedancijski spektar promijenio nakon njegova dodatka. Također, u ovom radu je dokazano da adsorpcija organskih tvari utječe na svojstva vanjskog, poroznog i unutarnjeg, kompaktnog sloja fotokatalizatora te na formiranje sloja prostornog naboja.
Abstract (english)
The objective of this research was electrochemical characterization of the metal oxide used in the photocatalytic processes. A study of the nanocomposite TiO2/SnS2 was performed in NaCl solution, with and without addition of diclofenac (DCF) and in Na2SO4 solution, also with and without DCF. In addition, an electrochemically-formed TiO2 was also tested. The electrochemically-formed TiO2 was obtained by using chronoamperometry method by polarization of titanium electrode for 120 s at potential of 1 V. The nanocomposite photocatalyst TiO2/SnS2 was prepared by hydrothermal method and immobilization on titanium electrode was carried out by spin-coating method. Methods of electrochemical characterization used in this work were cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and Mott-Schottky analysis. In the presence of DCF in the investigated solution the impedance spectrum was changed due to the DCF adsorption on the photocatalyst surface. It was also shown that adsorption of organic substances influence the properties of the outer, porous layer and inner, compact layer of the photocatalysts, as well as space charge layer.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:149:046850
ProjectNumber: IP-2018-01-1982
Title: Nano-katalizatori aktivirani Sunčevim zračenjem u tehnologijama zaštite okoliša
Title: Nano-sized solar-active catalysts for environmental technologies
Acronym: NaSCEnT
Leader: Hrvoje Kušić
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: Materials Science and Engineering - Graduate study
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra inženjer/inženjerka kemijskog inženjerstva (magistar/magistra inženjer/inženjerka kemijskog inženjerstva)
Type of resourceText
File originBorn digital
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Created on2022-02-26 09:47:15