This paper proposes an improvement of the conventional Lightweight Steel Frame (LSF) wall structure suitable for the design of high- performance modular buildings. A mobile module, named MUZA, is used as a case study building to analyse the performance of such LSF structures in terms of their thermal bridging effect on the U- value of the opaque envelope elements, linear heat losses at junctions, and moisture condensation risk, as well as thermal bridging effect on the overall energy performance of the building. The study included an additional climate- and orientationdependent analysis that examined the performance of MUZA under various conditions. The main conclusion is that the steel studs increase the U-value from 28.4% to 41.6% compared to cases without the studs, which consequently increases transmission losses through opaque elements. Thanks to the continuous covering of the metal studs with thermal insulation, the thermal bridges at the element junctions are minimized, and in almost all cases, the Ψ-values are well below 0.1 W/(m·K) and are free from moisture condensation. The overall impact of thermal bridges on heating energy demand is significant, while the impact on cooling energy is less pronounced. The designed module with the proposed LSF wall structure can meet the Croatian requirements for Nearly Zero- Energy Buildings (NZEB), but the shading devices and photovoltaics orientation must be optimized depending on the climatic conditions and the orientation of the large transparent openings. MUZA can be a promising solution for post-disaster housing, providing better indoor environmental quality, healthy living conditions, and low energy bills for the affected people. In addition, it can also be used for permanent housing when a fast and robust modular construction is required which is also energy efficient and sustainable.