prikaz prve stranice dokumenta Sinteza i konformacijska analiza ferocenskog alkohola
  Download
PDF 547.58 KB
undergraduate thesis
Sinteza i konformacijska analiza ferocenskog alkohola
Zagreb: University of Zagreb, Faculty of Food Technology and Biotechnology, 2019. urn:nbn:hr:159:760746
Pavlić, Kristian
University of Zagreb
Faculty of Food Technology and Biotechnology
Department of Chemistry and Biochemistry
Laboratory for Organic Chemistry

Institutional repository: Repository of the Faculty of Food Technology and Biotechnology

Cite this document

Pavlić, K. (2019). Sinteza i konformacijska analiza ferocenskog alkohola (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Food Technology and Biotechnology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:159:760746

Pavlić, Kristian. "Sinteza i konformacijska analiza ferocenskog alkohola." Undergraduate thesis, University of Zagreb, Faculty of Food Technology and Biotechnology, 2019. https://urn.nsk.hr/urn:nbn:hr:159:760746

Pavlić, Kristian. "Sinteza i konformacijska analiza ferocenskog alkohola." Undergraduate thesis, University of Zagreb, Faculty of Food Technology and Biotechnology, 2019. https://urn.nsk.hr/urn:nbn:hr:159:760746

Pavlić, K. (2019). 'Sinteza i konformacijska analiza ferocenskog alkohola', Undergraduate thesis, University of Zagreb, Faculty of Food Technology and Biotechnology, accessed 09 September 2024, https://urn.nsk.hr/urn:nbn:hr:159:760746

Pavlić K. Sinteza i konformacijska analiza ferocenskog alkohola [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Food Technology and Biotechnology; 2019 [cited 2024 September 09] Available at: https://urn.nsk.hr/urn:nbn:hr:159:760746

K. Pavlić, "Sinteza i konformacijska analiza ferocenskog alkohola", Undergraduate thesis, University of Zagreb, Faculty of Food Technology and Biotechnology, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:159:760746

Metadata
TitleSinteza i konformacijska analiza ferocenskog alkohola
Title (english)Synthesis and conformational analysis of ferrocene alcohol
AuthorKristian Pavlić
MentorMonika Kovačević (mentor)
GranterUniversity of Zagreb
Faculty of Food Technology and Biotechnology
(Department of Chemistry and Biochemistry)
(Laboratory for Organic Chemistry)
Zagreb
Defense date and country2019-06-14, Croatia
Scientific / art field,
discipline and subdiscipline		BIOTECHNICAL SCIENCES
Food Technology
Abstract
U ovom radu opisani su sinteza i konformacijska svojstva ferocenskog alkohola 2 (HO2HC-Fn-NHBoc) koji se dobiva redukcijom esterske skupine ferocenske aminokiseline (Fca, 1) u prisustvu LiAlH4. Da bi se ispitao utjecaj dobivene hidroksilne skupine pri tvorbi intramolekulskih vodikovih veza (IHB) na konformacijski prostor koji ferocenski alkohol zauzima u otopini, provedena je spektroskopska analiza (IR- i NMR-spektroskopija). Kristalografskom analizom kao i DFT modeliranjem u čvrstom stanju, ispitana je mogućnost tvorbe IHB u čvrstom stanju. Pokazalo se da u čvrstom stanju dolazi do tvorbe IHB veze, dok u otopini nema indikacija za postojanjem takve veze.
Abstract (english)
This study has explored the synthesis and structural characteristics of ferrocene alcohol 2 (HO2HC-Fn-NHBoc), derived by reduction of ferrocene amino acid (Fca, 1) ester group in presence of LiAlH4. In order to explore influence of derived hydroxyl group on formation of intramolecular hydrogen bond (IHB), the detailed conformational analysis (IR and NMR spectroscopy) in solution was performed. Crystallographic structure and DFT modelling of alcohol 2 in solid state were determined to explore possibility of IHB formation. It was demonstrated that ferrocene alcohol 2 was stabilized through intramolecular hydrogen bonding in solid state. In solution state, there was no data indicating the same bonding pattern.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:159:760746
Study programmeTitle: Food Technology
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka prehrambene tehnologije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka prehrambene tehnologije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2019-07-12 08:33:27