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undergraduate thesis
Utjecaj D-leucina na konformaciju izvedenog ferocenskog dipeptida
Zagreb: University of Zagreb, Faculty of Food Technology and Biotechnology, 2023. urn:nbn:hr:159:672408
Vidan, Emili
University of Zagreb
Faculty of Food Technology and Biotechnology
Department of Chemistry and Biochemistry
Laboratory for Organic Chemistry

Institutional repository: Repository of the Faculty of Food Technology and Biotechnology

Cite this document

Vidan, E. (2023). Utjecaj D-leucina na konformaciju izvedenog ferocenskog dipeptida (Undergraduate thesis). Zagreb: University of Zagreb, Faculty of Food Technology and Biotechnology. Retrieved from https://urn.nsk.hr/urn:nbn:hr:159:672408

Vidan, Emili. "Utjecaj D-leucina na konformaciju izvedenog ferocenskog dipeptida." Undergraduate thesis, University of Zagreb, Faculty of Food Technology and Biotechnology, 2023. https://urn.nsk.hr/urn:nbn:hr:159:672408

Vidan, Emili. "Utjecaj D-leucina na konformaciju izvedenog ferocenskog dipeptida." Undergraduate thesis, University of Zagreb, Faculty of Food Technology and Biotechnology, 2023. https://urn.nsk.hr/urn:nbn:hr:159:672408

Vidan, E. (2023). 'Utjecaj D-leucina na konformaciju izvedenog ferocenskog dipeptida', Undergraduate thesis, University of Zagreb, Faculty of Food Technology and Biotechnology, accessed 21 December 2024, https://urn.nsk.hr/urn:nbn:hr:159:672408

Vidan E. Utjecaj D-leucina na konformaciju izvedenog ferocenskog dipeptida [Undergraduate thesis]. Zagreb: University of Zagreb, Faculty of Food Technology and Biotechnology; 2023 [cited 2024 December 21] Available at: https://urn.nsk.hr/urn:nbn:hr:159:672408

E. Vidan, "Utjecaj D-leucina na konformaciju izvedenog ferocenskog dipeptida", Undergraduate thesis, University of Zagreb, Faculty of Food Technology and Biotechnology, Zagreb, 2023. Available at: https://urn.nsk.hr/urn:nbn:hr:159:672408

Metadata
TitleUtjecaj D-leucina na konformaciju izvedenog ferocenskog dipeptida
Title (english)Influence of D-leucine on the conformation of derived ferrocene dipeptide
AuthorEmili Vidan
MentorMonika Kovačević (mentor)
GranterUniversity of Zagreb
Faculty of Food Technology and Biotechnology
(Department of Chemistry and Biochemistry)
(Laboratory for Organic Chemistry)
Zagreb
Defense date and country2023-09-22, Croatia
Scientific / art field,
discipline and subdiscipline		BIOTECHNICAL SCIENCES
Biotechnology
Abstract
Ferocen je bioorganometalni spoj koji se sastoji od željezova kationa smještenog između dvije ciklopentadienilne jedinice. Zahvaljujući razmaku između ciklopentadienilnih prstenova od 3,3 Å, što odgovara prosječnoj duljini vodikove veze, nadogradnjom ferocenskog kalupa aminokiselinama inducira se tvorba različitih strukturnih elemenata. U ovom završnom radu opisana je priprava ferocenskog dipeptida 6 (Ac-D-Leu-NH-Fn-NH-DLeu-Boc) kopulacijom 1ʼ-aminoferocen-1-karboksilne kiseline (Fca) s aminokiselinom D-leucinom. Cilj ovog rada bio je utvrditi utjecaj ferocenskog kalupa, sterički zahtjevnog bočnog ogranka i kiralnosti leucina na obrazac nastajanja intramolekulskih vodikovih veza (IHB) provedbom konformacijske analize korištenjem IR-, NMR- i CD- spektroskopije.
Abstract (english)
Ferrocene is a bioorganometallic compound consisting of an iron cation located between two cyclopentadienyl units. Owing to the distance between the cyclopentadienyl rings of 3.3 Å, which corresponds to the average length of the hydrogen bond, the formation of various structural elements is induced upon attachment of ferrocene template to amino acids. This work describes the preparation of ferrocene 6 (Ac-D-Leu-NH-Fn-NH-D-Leu-Boc) by coupling 1ʼ-aminoferrocene-1-carboxylic acid (Fca) with the amino acid D-leucine. The aim of this work was to determine the influence of the ferrocene template, the branched side chain, and the chirality of leucine on the intramolecular hydrogen bond (IHB) pattern. The conformational analysis of the goal compounds was conducted by using standard spectroscopic methods (IR-, NMR-, and CDspectroscopy).
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:159:672408
Study programmeTitle: Biotechnology
Study programme type: university
Study level: undergraduate
Academic / professional title: sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka biotehnologije (sveučilišni/a prvostupnik/prvostupnica (baccalaureus/baccalaurea) inženjer/inženjerka biotehnologije)
Type of resourceText
File originBorn digital
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Created on2024-11-15 11:26:06