Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation

Uršić, S.

prikaz prve stranice dokumenta Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation

Download
PDF 4.7 MB

Scientific paper - Original scientific paper

Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation

Croatica Chemica Acta, 54 (1981), 1; 69-74. urn:nbn:hr:163:183977

Uršić, S.

Institutional repository: Repository of Faculty of Pharmacy and Biochemistry University of Zagreb

Cite this document

APA 6th Edition

Uršić, S. (1981). Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation. Croatica Chemica Acta, 54. (1), 69-74. Retrieved from https://urn.nsk.hr/urn:nbn:hr:163:183977

MLA 8th Edition

Uršić, S.. "Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation." Croatica Chemica Acta, vol. 54, no. 1, 1981, pp. 69-74. https://urn.nsk.hr/urn:nbn:hr:163:183977

Chicago 17th Edition

Uršić, S.. "Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation." Croatica Chemica Acta 54, no. 1 (1981): 69-74. https://urn.nsk.hr/urn:nbn:hr:163:183977

Harvard

Uršić, S. (1981) 'Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation', Croatica Chemica Acta, 54(1), pp. 69-74. Available at: https://urn.nsk.hr/urn:nbn:hr:163:183977 (Accessed 11 January 2025)

Vancouver

Uršić S. Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation. Croatica Chemica Acta [Internet]. 1981 [cited 2025 January 11];54(1):69-74. Available at: https://urn.nsk.hr/urn:nbn:hr:163:183977

IEEE

S. Uršić, "Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation", Croatica Chemica Acta, vol. 54, no. 1, pp. 69-74, 1981. [Online]. Available at: https://urn.nsk.hr/urn:nbn:hr:163:183977. [Accessed: 11 January 2025]

Cite this item: https://urn.nsk.hr/urn:nbn:hr:163:183977

Metadata

Title (english)	Ferrocenylalkyl carbocations. Rates of formation and nucleophillic additions to ferrocenylmethyl carbocation
Author	S. Uršić
Author's institution	University of Zagreb Faculty of Pharmacy and Biochemistry (Department of physical chemistry)
Scientific / art field, discipline and subdiscipline	NATURAL SCIENCES Chemistry Physical Chemistry
Abstract (english)	Rate constants for FcC+H2 (Fe = Ierrocenyl) formation (3.42 s-1 M-1) and for nucleophillic additions of water (50.6 s· 1 M-1) and pyridine (3.77 X 106 s-1 M-1) to the same carbocation were determined. Corresponding secondary <1-hydrogen isotope effects on FcC+H2 formation (ca. L28) were found, and were calculated for additions of water (ca. 0.78) and pyridine (ca. 0.79) to FcC+H2. These results were discussed in terms of some possible structural models of Fcc+H2.
Language	english
Publication type	Scientific paper - Original scientific paper
Publication status	Published
Peer review	Peer review - international
Publication version	Published version
Journal title	Croatica Chemica Acta
Numbering	vol. 54, no. 1, pp. 69-74
p-ISSN	0011-1643
e-ISSN	1334-417X
URN:NBN	urn:nbn:hr:163:183977
Publication	1981
Document URL	https://hrcak.srce.hr/194415
Type of resource	Text
Access conditions	Open access
Terms of use
Created on	2020-05-05 14:13:02

Search form