prikaz prve stranice dokumenta Termodinamika ciklopaladiranja 4-dimetilaminoazobenzena
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master's thesis
Termodinamika ciklopaladiranja 4-dimetilaminoazobenzena
Zagreb: University of Zagreb, Faculty of Pharmacy and Biochemistry, 2015. urn:nbn:hr:163:246888
Prohaska, Boris
University of Zagreb
Faculty of Pharmacy and Biochemistry
Department of general and inorganic chemistry

Institutional repository: Repository of Faculty of Pharmacy and Biochemistry University of Zagreb

Cite this document

Prohaska, B. (2015). Termodinamika ciklopaladiranja 4-dimetilaminoazobenzena (Master's thesis). Zagreb: University of Zagreb, Faculty of Pharmacy and Biochemistry. Retrieved from https://urn.nsk.hr/urn:nbn:hr:163:246888

Prohaska, Boris. "Termodinamika ciklopaladiranja 4-dimetilaminoazobenzena." Master's thesis, University of Zagreb, Faculty of Pharmacy and Biochemistry, 2015. https://urn.nsk.hr/urn:nbn:hr:163:246888

Prohaska, Boris. "Termodinamika ciklopaladiranja 4-dimetilaminoazobenzena." Master's thesis, University of Zagreb, Faculty of Pharmacy and Biochemistry, 2015. https://urn.nsk.hr/urn:nbn:hr:163:246888

Prohaska, B. (2015). 'Termodinamika ciklopaladiranja 4-dimetilaminoazobenzena', Master's thesis, University of Zagreb, Faculty of Pharmacy and Biochemistry, accessed 29 November 2024, https://urn.nsk.hr/urn:nbn:hr:163:246888

Prohaska B. Termodinamika ciklopaladiranja 4-dimetilaminoazobenzena [Master's thesis]. Zagreb: University of Zagreb, Faculty of Pharmacy and Biochemistry; 2015 [cited 2024 November 29] Available at: https://urn.nsk.hr/urn:nbn:hr:163:246888

B. Prohaska, "Termodinamika ciklopaladiranja 4-dimetilaminoazobenzena", Master's thesis, University of Zagreb, Faculty of Pharmacy and Biochemistry, Zagreb, 2015. Available at: https://urn.nsk.hr/urn:nbn:hr:163:246888

Metadata
TitleTermodinamika ciklopaladiranja 4-dimetilaminoazobenzena
Title (english)Thermodynamics of cyclopalladation of 4-dimethylaminoazobenzene
AuthorBoris Prohaska
MentorAna Budimir (mentor)
Committee memberAna Budimir
Committee memberTin Weitner
Committee memberViktor Pilepić
GranterUniversity of Zagreb
Faculty of Pharmacy and Biochemistry
(Department of general and inorganic chemistry)
Zagreb
Defense date and country2015-09-30, Croatia
Scientific / art field,
discipline and subdiscipline		BIOMEDICINE AND HEALTHCARE
Pharmacy
Pharmacy
Abstract
U ovom radu ispitana je kinetika i mehanizam reakcije PdCl2(DMF)2 s 4-dimetilaminoazobenzenom u N,N-dimetilformamidu. Mjerenja su izvršena pod uvjetima pseudo-prvog reda tj. u velikom molarnom suvišku PdCl2(DMF)2 u odnosu na 4-dimetilaminoazobenzen te pri različitim temperaturama. Rezultati kinetičkih istraživanja pokazali su da se u ovim eksperimentalnim uvjetima reakcije monopaladiranja, odnosno dipaladiranja, odvijaju u dva uzastopna koraka. U prvom brzom koraku dolazi do nastajanja mononuklearnog, LPdCl2(DMF), odnosno monociklopaladiranog adukta L[PdCl2(DMF)]2 nakon čega slijedi spori korak u kojem dolazi do pucanja orto C-H veze i nastajanja nove Pd-C veze. Aktivacijski parametri, ΔH, ΔS te ΔEa za oba reakcijska koraka su određeni i diskutirani.
Abstract (english)
In this work the kinetics and mechanism of reactions of PdCl2(DMF)2 with azobenzene and 4-dimethylaminoazobenzene in N,N-dimethylformamide were examined. The measurements were conducted under pseudo first order which means that one of the reactant was in molar excess, PdCl2(DMF)2. It was found that the mono- and dicyclopalladation reactions of azobenzenes proceed in two consecutive processes, adduct formation and palladation steps. The rate-determining step in both palladations is the breaking of the ortho C-H bond. From specific rate constants can be seen that the substitution of azobenzene significantly affect on the rate of complexation. From the resaults we see that by increasing the temperature we came to increase the constance rate.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:163:246888
Study programmeTitle: Pharmacy
Study programme type: university
Study level: integrated undergraduate and graduate
Academic / professional title: magistar/magistra farmacije (magistar/magistra farmacije)
Type of resourceText
File originBorn digital
Access conditionsAccess restricted to students and staff of home institution
Terms of useLicence In copyright icon
Created on2016-02-23 12:08:21