Objectives The aim of this search was to present and analyse medication error reports with salbutamol nebuliser solution in pediatric population and to measure the effectiveness of risk minimisation measures which Agency for Medicinal Products and Medical Devices of Croatia (HALMED) had already performed in order to prevent them. Material and Methods A search of national adverse drug reaction (ADR) database was conducted for the period from January 1st 2016 to December 31st 2022. Medication error reports were analysed according to the patient's age, patient's gender, reactions reported, persons who made medication errors and according to the year of the receipt. Analysis of medication errors according to ADRs was performed and ADRs were analysed according to the seriousness, listedness, outcome and type of reactions. A survey was conducted among pharmacists employed in community pharmacies regarding risk minimisation measures which HALMED had already performed. An on-line survey was conducted between regulatory agencies of the European Union and European Economic Area member states in order to compare the data with Croatian data. Results A total of 108 medication error reports with salbutamol nebuliser solution in pediatric population were received in the stated period. All of the reports were received from the Institute for Medical Research and Occupational Health. The most of the reports were observed in the children aged from 1 to 7 years. The most commonly reported medication errors were accidental overdose, accidental exposure to product by child, wrong drug administered and drug administered via inappropriate route. In 55.4% of the accidental overdose cases, dose administered was ten times higher than dose prescribed. ADRs occurred in 41.7% of the reports, and the most commonly reported was tachycardia, followed by tremor and vomiting. In 86.7% of the reports ADRs were assessed as non-serious, while in 13.3% of the reports were assessed as serious. Conclusion The results of this search indicate that medication errors with the use of salbutamol nebuliser solution in the pediatric population continue to occur. Incorrect understanding of prescribed dose due to very small amount i.e. volume of the medicinal product, switch of medicinal products due to similarity in inner packaging and availability of medicinal product to children were identified as causes of medication errors. Further risk minimisation measures are warranted in order to minimise the risk or to completely prevent the occurrence of medication errors. By preventing medication errors, the occurrence of ADRs in pediatric population would be prevented as well, including those severe and serious, thus contributing to preservation of health in pediatric patients.