prikaz prve stranice dokumenta Mehanizam ciklopaladiranja azobenzena sa paladijevim(II) acetatom
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master's thesis
Mehanizam ciklopaladiranja azobenzena sa paladijevim(II) acetatom
Zagreb: University of Zagreb, Faculty of Pharmacy and Biochemistry, 2016. urn:nbn:hr:163:590162
Šimičić, Dario
University of Zagreb
Faculty of Pharmacy and Biochemistry
Department of general and inorganic chemistry

Institutional repository: Repository of Faculty of Pharmacy and Biochemistry University of Zagreb

Cite this document

Šimičić, D. (2016). Mehanizam ciklopaladiranja azobenzena sa paladijevim(II) acetatom (Master's thesis). Zagreb: University of Zagreb, Faculty of Pharmacy and Biochemistry. Retrieved from https://urn.nsk.hr/urn:nbn:hr:163:590162

Šimičić, Dario. "Mehanizam ciklopaladiranja azobenzena sa paladijevim(II) acetatom." Master's thesis, University of Zagreb, Faculty of Pharmacy and Biochemistry, 2016. https://urn.nsk.hr/urn:nbn:hr:163:590162

Šimičić, Dario. "Mehanizam ciklopaladiranja azobenzena sa paladijevim(II) acetatom." Master's thesis, University of Zagreb, Faculty of Pharmacy and Biochemistry, 2016. https://urn.nsk.hr/urn:nbn:hr:163:590162

Šimičić, D. (2016). 'Mehanizam ciklopaladiranja azobenzena sa paladijevim(II) acetatom', Master's thesis, University of Zagreb, Faculty of Pharmacy and Biochemistry, accessed 10 October 2024, https://urn.nsk.hr/urn:nbn:hr:163:590162

Šimičić D. Mehanizam ciklopaladiranja azobenzena sa paladijevim(II) acetatom [Master's thesis]. Zagreb: University of Zagreb, Faculty of Pharmacy and Biochemistry; 2016 [cited 2024 October 10] Available at: https://urn.nsk.hr/urn:nbn:hr:163:590162

D. Šimičić, "Mehanizam ciklopaladiranja azobenzena sa paladijevim(II) acetatom", Master's thesis, University of Zagreb, Faculty of Pharmacy and Biochemistry, Zagreb, 2016. Available at: https://urn.nsk.hr/urn:nbn:hr:163:590162

Metadata
TitleMehanizam ciklopaladiranja azobenzena sa paladijevim(II) acetatom
Title (english)The mechanism of azobenzene cyclopalladation with palladium(II) acetate
AuthorDario Šimičić
MentorAna Budimir (mentor)
Committee memberAna Budimir (predsjednik povjerenstva)
Committee memberJadranka Vuković Rodriguez (član povjerenstva)
Committee memberMario Gabričević (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Pharmacy and Biochemistry
(Department of general and inorganic chemistry)
Zagreb
Defense date and country2016-07-22, Croatia
Scientific / art field,
discipline and subdiscipline		BIOMEDICINE AND HEALTHCARE
Pharmacy
Pharmacy
Abstract
1H-NMR spektroskopijom praćene su reakcije nastajanja ciklopaladiranih azobenzena u N,N-dimetilformamidu, a kao prekursor je korišten paladijev(II) acetat. Mjerenja su izvršena uz trostruki molarni suvišak Pd(OAc)2. Rezultati su pokazali da u reakciji 4-dimetilaminoazobenzena i Pd(OAc)2 nastaju i monopaladirani i dipaladirani kompleks dok u reakciji 4-dimetilamino-4'-nitroazobenzena i Pd(OAc)2 unutar 72 sata i pod ovim reakcijskim uvjetima nastaje samo monopaladirani kompleks. Iz ovisnosti promjene koncentracije monopaladiranih kompleksa o vremenu izračunane su konstante brzine reakcija.
Abstract (english)
In this work the formation of cyclopalladated azobenzenes were monitored by 1H-NMR spectroscopy. The solvent was N,N-dimethylformamide and as a Pd precursor palladium(II) acetate was used. The measurements were carried out with three-fold molar excess of Pd(OAc)2. The results have shown that in the reaction of 4-dimethylaminoazobenzene and Pd(OAc)2, dicyclopalladated and monocyclopalladated complex are formed. On the other hand, the reaction of 4-dimethylamino-4'-nitroazobenzene with Pd(OAc)2 during 72 hours leads only to monocyclopalladated complex.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:163:590162
Study programmeTitle: Pharmacy
Study programme type: university
Study level: integrated undergraduate and graduate
Academic / professional title: magistar/magistra farmacije (magistar/magistra farmacije)
Type of resourceText
File originBorn digital
Access conditionsAccess restricted to students and staff of home institution
Terms of useLicence In copyright icon
Created on2016-10-28 09:11:48