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master's thesis
Kokristali 2,4,6-kolidinijevih i 3,5-lutidinijevih halogenida s 1,4-dijodtetrafluorbenzenom
Zagreb: University of Zagreb, Faculty of Science, 2022. urn:nbn:hr:217:966322
Liović, Marin
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

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Liović, M. (2022). Kokristali 2,4,6-kolidinijevih i 3,5-lutidinijevih halogenida s 1,4-dijodtetrafluorbenzenom (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:966322

Liović, Marin. "Kokristali 2,4,6-kolidinijevih i 3,5-lutidinijevih halogenida s 1,4-dijodtetrafluorbenzenom." Master's thesis, University of Zagreb, Faculty of Science, 2022. https://urn.nsk.hr/urn:nbn:hr:217:966322

Liović, Marin. "Kokristali 2,4,6-kolidinijevih i 3,5-lutidinijevih halogenida s 1,4-dijodtetrafluorbenzenom." Master's thesis, University of Zagreb, Faculty of Science, 2022. https://urn.nsk.hr/urn:nbn:hr:217:966322

Liović, M. (2022). 'Kokristali 2,4,6-kolidinijevih i 3,5-lutidinijevih halogenida s 1,4-dijodtetrafluorbenzenom', Master's thesis, University of Zagreb, Faculty of Science, accessed 20 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:966322

Liović M. Kokristali 2,4,6-kolidinijevih i 3,5-lutidinijevih halogenida s 1,4-dijodtetrafluorbenzenom [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2022 [cited 2024 November 20] Available at: https://urn.nsk.hr/urn:nbn:hr:217:966322

M. Liović, "Kokristali 2,4,6-kolidinijevih i 3,5-lutidinijevih halogenida s 1,4-dijodtetrafluorbenzenom", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2022. Available at: https://urn.nsk.hr/urn:nbn:hr:217:966322

Metadata
TitleKokristali 2,4,6-kolidinijevih i 3,5-lutidinijevih halogenida s 1,4-dijodtetrafluorbenzenom
Title (english)Cocrystals of 2,4,6-collidinium and 3,5-lutidinium halogenides with 1,4-diiodotetrafluorobenzene
AuthorMarin Liović
MentorVladimir Stilinović (mentor)
Committee memberVladimir Stilinović (predsjednik povjerenstva)
Committee memberGordan Horvat (član povjerenstva)
Committee memberNikola Cindro (član povjerenstva)
Committee memberDominik Cinčić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2022-09-16, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
S ciljem izučavanja halogenida kao akceptora halogenske i vodikove veze istovremeno, u sklopu ovog diplomskog rada pripravljeni su halogenidi 2,4,6-kolidina (246kol) i 3,5-lutidina (35lut) koji su kokristalizirani s 1,4-dijodtetrafluorbenzenom (14tfib). Soli i kokristali su pripravljeni sintezom iz otopine. Metodom difrakcije na jediničnom kristalu, određene su molekulske i kristalne strukture 6 soli, 2 solvata soli i 7 kokristala soli. U svim pripravljenim kokristalima, uz vodikove veze N−H⋯X – s kationima 246kolH+ i 35lutH+, halogenidi ostvaruju halogenske veze C‒I⋯X‒ s molekulama 14tfib stvarajući motive cik-cak lanca. Uspoređujući duljine interakcija relativne sumama van der Waalsovih i ionskih radijusa atoma u interakciji unutar 246kol i 35lut serija, vodikove veze su relativno kraće za halogenide manjeg radijusa, dok su relativne duljine halogenskih veza međusobno bliskih vrijednosti i ne prate nikakav trend.
Abstract (english)
In order to study the halogenide anion as an acceptor of halogen and hydrogen bonds simultaneously, single crystals of 2,4,6-collidinium (246col) and 3,5-lutidinium halogenides (35lut), and their respective cocrystals with 1,4-diiodotetrafluorobenzene (14tfib), were prepared via solution synthesis within this master thesis. The molecular and crystal structures of 6 salts, 2 solvates of salts and 7 cocrystals of salts were determined by single crystal X-ray diffraction experiments. In all the prepared cocrystals, along with N−H⋯X– hydrogen bonds, every halogenide and 14tfib alternate forming zig-zag chains via C‒I⋯X‒ halogen bonds. Comparing interaction lengths relative to the sum of van der Waals and ionic radii of the donor and acceptor atoms within the 246col and 35lut series, hydrogen bonds are relatively shorter for smaller halogenides while halogen bonds vary slightly in relative length and do not follow any trend.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:966322
ProjectNumber: IP-2019-04-1868
Title: Nove građevne jedinke u supramolekulskom dizajnu složenih višekomponentnih molekulskih kristala temeljenih na halogenskim vezama
Title: New building blocks for the supramolecular design of complex multi-component molecular crystals based on halogen bonds
Acronym: HaloBond
Leader: Dominik Cinčić
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2024-09-16
Terms of useLicence In copyright icon
Created on2022-10-06 12:27:16