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master's thesis
Utjecaj molarne mase polielektrolita na formiranje i svojstva ultra-tankih filmova poli(alilamin-hidroklorida) i poli(akrilne kiseline)
Zagreb: University of Zagreb, Faculty of Science, 2022. urn:nbn:hr:217:529992
Masjar, Matej
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

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Masjar, M. (2022). Utjecaj molarne mase polielektrolita na formiranje i svojstva ultra-tankih filmova poli(alilamin-hidroklorida) i poli(akrilne kiseline) (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:529992

Masjar, Matej. "Utjecaj molarne mase polielektrolita na formiranje i svojstva ultra-tankih filmova poli(alilamin-hidroklorida) i poli(akrilne kiseline)." Master's thesis, University of Zagreb, Faculty of Science, 2022. https://urn.nsk.hr/urn:nbn:hr:217:529992

Masjar, Matej. "Utjecaj molarne mase polielektrolita na formiranje i svojstva ultra-tankih filmova poli(alilamin-hidroklorida) i poli(akrilne kiseline)." Master's thesis, University of Zagreb, Faculty of Science, 2022. https://urn.nsk.hr/urn:nbn:hr:217:529992

Masjar, M. (2022). 'Utjecaj molarne mase polielektrolita na formiranje i svojstva ultra-tankih filmova poli(alilamin-hidroklorida) i poli(akrilne kiseline)', Master's thesis, University of Zagreb, Faculty of Science, accessed 23 December 2024, https://urn.nsk.hr/urn:nbn:hr:217:529992

Masjar M. Utjecaj molarne mase polielektrolita na formiranje i svojstva ultra-tankih filmova poli(alilamin-hidroklorida) i poli(akrilne kiseline) [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2022 [cited 2024 December 23] Available at: https://urn.nsk.hr/urn:nbn:hr:217:529992

M. Masjar, "Utjecaj molarne mase polielektrolita na formiranje i svojstva ultra-tankih filmova poli(alilamin-hidroklorida) i poli(akrilne kiseline)", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2022. Available at: https://urn.nsk.hr/urn:nbn:hr:217:529992

Metadata
TitleUtjecaj molarne mase polielektrolita na formiranje i svojstva ultra-tankih filmova poli(alilamin-hidroklorida) i poli(akrilne kiseline)
Title (english)Influence of polyelectrolyte molar mass on formation and properties of poly(allylamine hydrochloride)7poly(acrylic acid) ultra-thin films
AuthorMatej Masjar
MentorDavor Kovačević (mentor)
Committee memberDavor Kovačević (predsjednik povjerenstva)
Committee memberŽeljka Soldin (član povjerenstva)
Committee memberAdriana Kenđel (član povjerenstva)
Committee memberTajana Begović (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2022-09-29, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U ovom radu je istražen utjecaj molarne mase polielektrolita na formiranje i svojstva polielektrolitnog višesloja poli(alilamin-hidroklorida) i poli(akrilne kiseline). U te svrhe filmovi su pripravljeni s različitim kombinacijama molarnih masa polielektrolita sloj po sloj metodom na površini silicijeva supstrata pri različitim eksperimentalnim uvjetima kako bi se utjecalo na konformaciju polimernih lanaca. Elipsometrom je praćena debljina filma tijekom njegove priprave, a mikroskopom atomskih sila je određena morfologija, hrapavost i poroznost površine filma. Iz dobivenih podataka utvrđeno je da se povećanjem molarne mase polielektrolita povećava debljina filma ako je barem jedan polielektrolit u globularnoj konformaciji. Pokazano je da molarna masa polielektrolita nema značajni utjecaj na debljinu i hrapavost filma ako su oba polielektrolita u izduženoj konformaciji. Otkrivena su i dva nova načina priprave ultra-tankih filmova (d ≈ 2 nm) s poli(akrilnom kiselinom) male molarne mase.
Abstract (english)
In this study the influence of the polyelectrolyte molar mass on the formation and properties of poly(allylamine hydrochloride)/poly(acrylic acid) polyelectrolyte multilayer was investigated. For these purposes, films were prepared on the silicon substrate using layer by layer method with different combinations of polyelectrolyte molar masses under different experimental conditions in order to influence the conformation of the polymer chains. The thickness of the film was monitored during its preparation with an ellipsometer and the morphology, roughness, and porosity of the film surface were determined with an atomic force microscope. From obtained data, it was established that by increasing the polyelectrolyte molar mass, the thickness of the film increases if at least one polyelectrolyte is in globular conformation. On the other hand, if both polyelectrolytes are in an elongated conformation, the polyelectrolyte molar mass has no significant influence on the thickness and roughness of the film. Also, two new ways of preparation of ultra-thin films (d ≈ 2 nm) were discovered by using poly(acrylic acid) of low molar mass.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:529992
ProjectNumber: IPS-2020-01-6126
Title: Modulacija polifenolnog profila voća uslijed fizikalnih tretmana nakon branja
Title: Modulation of fruit polyphenolic profile by sustainable postharvest physical treatments
Leader: Davor Kovačević
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IPS
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2024-09-29
Terms of useLicence In copyright icon
Created on2022-10-25 12:55:22