prikaz prve stranice dokumenta Izocijanatni ligand kao akceptor halogenske veze u kokristalima koordinacijskog spoja nikla(II) s perhalogeniranim benzenima
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master's thesis
Izocijanatni ligand kao akceptor halogenske veze u kokristalima koordinacijskog spoja nikla(II) s perhalogeniranim benzenima
Zagreb: University of Zagreb, Faculty of Science, 2023. urn:nbn:hr:217:026412
Pehar, Leo
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

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Pehar, L. (2023). Izocijanatni ligand kao akceptor halogenske veze u kokristalima koordinacijskog spoja nikla(II) s perhalogeniranim benzenima (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:026412

Pehar, Leo. "Izocijanatni ligand kao akceptor halogenske veze u kokristalima koordinacijskog spoja nikla(II) s perhalogeniranim benzenima." Master's thesis, University of Zagreb, Faculty of Science, 2023. https://urn.nsk.hr/urn:nbn:hr:217:026412

Pehar, Leo. "Izocijanatni ligand kao akceptor halogenske veze u kokristalima koordinacijskog spoja nikla(II) s perhalogeniranim benzenima." Master's thesis, University of Zagreb, Faculty of Science, 2023. https://urn.nsk.hr/urn:nbn:hr:217:026412

Pehar, L. (2023). 'Izocijanatni ligand kao akceptor halogenske veze u kokristalima koordinacijskog spoja nikla(II) s perhalogeniranim benzenima', Master's thesis, University of Zagreb, Faculty of Science, accessed 20 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:026412

Pehar L. Izocijanatni ligand kao akceptor halogenske veze u kokristalima koordinacijskog spoja nikla(II) s perhalogeniranim benzenima [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2023 [cited 2024 November 20] Available at: https://urn.nsk.hr/urn:nbn:hr:217:026412

L. Pehar, "Izocijanatni ligand kao akceptor halogenske veze u kokristalima koordinacijskog spoja nikla(II) s perhalogeniranim benzenima", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2023. Available at: https://urn.nsk.hr/urn:nbn:hr:217:026412

Metadata
TitleIzocijanatni ligand kao akceptor halogenske veze u kokristalima koordinacijskog spoja nikla(II) s perhalogeniranim benzenima
Title (english)Isocyanate ligand as halogen bond acceptor in cocrystals of Ni(II) complex and perhalogenated benzens
AuthorLeo Pehar
MentorDominik Cinčić (mentor)
Committee memberDominik Cinčić (predsjednik povjerenstva)
Committee memberIva Juranović Cindrić (član povjerenstva)
Committee memberIvan Kodrin (član povjerenstva)
Committee memberVladimir Stilinović (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2023-02-20, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U ovom diplomskom radu sintetiziran je koordinacijski spoj tetrakis(piridin)bis(cianatoN)nikal(II) s ciljem da se pri kokristalizaciji s odabranim perhalogeniranim donorima halogenske veze istraži potencijal izocijanatnog liganda kao akceptora halogenske veze. Mehanokemijskom sintezom i sintezom u otopini pripravljeno je pet kokristala. Dobiveni produkti okarakterizirani su difrakcijom rendgenskog zračenja na polikristalnom uzoraku, termogravimetrijskom analizom te metodom difrakcije rendgenskog zračenja u jediničnom kristalu. Strukturnom analizom priređenih spojeva utvrđeno je da je u svim kokristalima dominantna supramolekulska interakcija halogenska veza NCO···I koja se ostvaruje između atoma joda perhalogeniranog benzena kao donora halogenske veze i atoma kisika izocijanatnog liganda koordinacijskog spoja nikla(II) kao akceptora halogenske veze.
Abstract (english)
In this thesis, the coordination compound tetrakis(pyridine)bis(cyanato-N)nickel(II) was synthesized to investigate the potential of the isocyanate ligand as a halogen bond acceptor during cocrystallization with selected perhalogenated halogen bond donors. Five cocrystals were prepared by mechanochemical synthesis and solution synthesis. The obtained products were characterized by X-ray diffraction on a polycrystalline sample, thermogravimetric analysis and single crystal X-ray diffraction. The structural analysis of the prepared compounds revealed that in all co-crystals the dominant supramolecular interaction is the halogen bond NCO···I , which occurs between the iodine atom of perhalogenated benzene as a halogen bond donor and the oxygen atom of the isocyanate ligand of the nickel(II) coordination compound as a halogen bond acceptor.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:026412
ProjectNumber: IP-2019-04-1868
Title: Nove građevne jedinke u supramolekulskom dizajnu složenih višekomponentnih molekulskih kristala temeljenih na halogenskim vezama
Title: New building blocks for the supramolecular design of complex multi-component molecular crystals based on halogen bonds
Acronym: HaloBond
Leader: Dominik Cinčić
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2024-02-20
Terms of useLicence In copyright icon
Created on2023-02-23 17:44:29