prikaz prve stranice dokumenta Priprava i karakterizacija halogenokuprata(II) izvedenih iz alifatskih triamina i tetraamina
Embargo period 2025-02-21
master's thesis
Priprava i karakterizacija halogenokuprata(II) izvedenih iz alifatskih triamina i tetraamina
Zagreb: University of Zagreb, Faculty of Science, 2023. urn:nbn:hr:217:892411
Klarić, Petra
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Klarić, P. (2023). Priprava i karakterizacija halogenokuprata(II) izvedenih iz alifatskih triamina i tetraamina (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:892411

Klarić, Petra. "Priprava i karakterizacija halogenokuprata(II) izvedenih iz alifatskih triamina i tetraamina." Master's thesis, University of Zagreb, Faculty of Science, 2023. https://urn.nsk.hr/urn:nbn:hr:217:892411

Klarić, Petra. "Priprava i karakterizacija halogenokuprata(II) izvedenih iz alifatskih triamina i tetraamina." Master's thesis, University of Zagreb, Faculty of Science, 2023. https://urn.nsk.hr/urn:nbn:hr:217:892411

Klarić, P. (2023). 'Priprava i karakterizacija halogenokuprata(II) izvedenih iz alifatskih triamina i tetraamina', Master's thesis, University of Zagreb, Faculty of Science, accessed 22 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:892411

Klarić P. Priprava i karakterizacija halogenokuprata(II) izvedenih iz alifatskih triamina i tetraamina [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2023 [cited 2024 November 22] Available at: https://urn.nsk.hr/urn:nbn:hr:217:892411

P. Klarić, "Priprava i karakterizacija halogenokuprata(II) izvedenih iz alifatskih triamina i tetraamina", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2023. Available at: https://urn.nsk.hr/urn:nbn:hr:217:892411

Metadata
TitlePriprava i karakterizacija halogenokuprata(II) izvedenih iz alifatskih triamina i tetraamina
Title (english)Synthesis an characterization of of layered halocuprates(II) derived from aliphatic triamines and tetraamines
AuthorPetra Klarić
MentorMirta Rubčić (mentor)
Committee memberMirta Rubčić (predsjednik povjerenstva)
Committee memberIva Juranović Cindrić (član povjerenstva)
Committee memberĐani Škalamera (član povjerenstva)
Committee memberIvica Đilović (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2023-02-21, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U okviru ovog diplomskog rada pripravljene su halogenidne soli alifatskih triamina dietilentriamina ((H3DETA)Cl3), N-(2-aminoetil)-1,3-propandiamina ((H3N-1,3-PDA)Cl3 i (H3N-1,3-PDA)Br3) kao i kloridna sol trietilentetraaamina ((H4TETA)Cl4). Klasičnom otopinskom sintezom pripravljena je serija hibridno organsko-anorganskih halogenokuprata(II): (H3DETA)[CuCl5], (H3DETA)[CuBr5], (H3N-1,3-PDA)[CuCl5], (H3N1,3-PDA)[CuBr5], (H4TETA)[CuCl6] i (H4PEEA)[CuBr6]·H2O. Anorganske građevne jedinke kod svih priređenih halogenometalata su stehiometrije CuX4, te se većinom udružuju u slojevite okosnice. Kod hibridnih halogenometalata sa slojevitom strukturom dolazi do ugrađivanja organskih kationa između anorganskih slojeva. Organski kationi povezuju se putem protoniranih terminalnih amino skupina za halogenokupratne(II) jedinke, a međusobno se udružuju putem N‒H···X···H‒N vodikovih veza. Pripravljenim hibridnim halogenometalatima određene su kristalne strukture pomoću difrakcije rendgenskog zračenja na jediničnom kristalu, a spojevi su dodatno okarakterizirani pomoću infracrvene spektroskopije, difrakcije rendgenskog zračenja na polikristalnom uzorku te metodama termičke analize.
Abstract (english)
In this work, halide salts of aliphatic triamines diethylenetriamine, ((H3DETA)Cl3), N-(2- aminoethyl)-1,3-propanediamine, (H3N-1,3-PDA)Cl3 and (H3N-1,3 -PDA)Br3, and the chloride salt of triethylenetetraamine, (H4TETA)Cl4, were prepared. A series of hybrid organic-inorganic halocuprates(II) were prepared by solution crystallization: (H3DETA)[CuCl5], (H3DETA)[CuBr5], (H3N-1,3-PDA)[CuCl5], (H3N-1,3-PDA)[CuBr5], (H4TETA)[CuCl6] and (H4PEEA)[CuBr6]·H2O. The inorganic building blocks of all prepared halogenometalates have stoichiometry CuX4, and they are mostly combined into layered frameworks. In the case of hybrid halometallates with a layered structure, organic cations are incorporated between the inorganic layers. Organic cations are connected via protonated terminal amino groups to halocuprate(II) units, and interlinked to each other via N‒ H···X···H‒N hydrogen bonds. The crystal structures of the prepared hybrid halogenometalates were determined using single-crystal X-ray diffraction, and the compounds were additionally characterized using infrared spectroscopy, powder X-ray diffraction and thermal analyses.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:892411
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsEmbargoed access
Embargo expiration date: 2025-02-21
Terms of useLicence In copyright icon
Created on2023-03-30 13:31:06