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master's thesis
Solvatomorfija ternarnih koordinacijskih spojeva bakra(II) s L-treoninom i 1,10-fenantrolinom
Zagreb: University of Zagreb, Faculty of Science, 2023. urn:nbn:hr:217:487286
Ležaić, Katarina
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

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Ležaić, K. (2023). Solvatomorfija ternarnih koordinacijskih spojeva bakra(II) s L-treoninom i 1,10-fenantrolinom (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:487286

Ležaić, Katarina. "Solvatomorfija ternarnih koordinacijskih spojeva bakra(II) s L-treoninom i 1,10-fenantrolinom." Master's thesis, University of Zagreb, Faculty of Science, 2023. https://urn.nsk.hr/urn:nbn:hr:217:487286

Ležaić, Katarina. "Solvatomorfija ternarnih koordinacijskih spojeva bakra(II) s L-treoninom i 1,10-fenantrolinom." Master's thesis, University of Zagreb, Faculty of Science, 2023. https://urn.nsk.hr/urn:nbn:hr:217:487286

Ležaić, K. (2023). 'Solvatomorfija ternarnih koordinacijskih spojeva bakra(II) s L-treoninom i 1,10-fenantrolinom', Master's thesis, University of Zagreb, Faculty of Science, accessed 14 May 2024, https://urn.nsk.hr/urn:nbn:hr:217:487286

Ležaić K. Solvatomorfija ternarnih koordinacijskih spojeva bakra(II) s L-treoninom i 1,10-fenantrolinom [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2023 [cited 2024 May 14] Available at: https://urn.nsk.hr/urn:nbn:hr:217:487286

K. Ležaić, "Solvatomorfija ternarnih koordinacijskih spojeva bakra(II) s L-treoninom i 1,10-fenantrolinom", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2023. Available at: https://urn.nsk.hr/urn:nbn:hr:217:487286

Metadata
TitleSolvatomorfija ternarnih koordinacijskih spojeva bakra(II) s L-treoninom i 1,10-fenantrolinom
Title (english)Solvatomorphism in ternary copper(II) coordination compounds with L-threonine and 1,10-phenanthroline
AuthorKatarina Ležaić
MentorBiserka Prugovečki (mentor)
MentorDarko Vušak (komentor)
Committee memberBiserka Prugovečki (predsjednik povjerenstva)
Committee memberDavor Kovačević (član povjerenstva)
Committee memberĐani Škalamera (član povjerenstva)
Committee memberDubravka Matković-Čalogović (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2023-09-28, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Otopinskim i/ili mehanokemijskim metodama priređeno je osam novih ternarnih koordinacijskih spojeva bakra(II) s L-treoninom i 1,10-fenantrolinom. Svi spojevi dobiveni otopinskom sintezom analizirani su metodom difrakcije rendgenskog zračenja na jediničnom kristalu dok su spojevi dobiveni mehanokemijskom metodom analizirani difrakcijom rendgenskog zračenja na polikristalnom uzorku. Neki od spojeva analizirani su dodatno infracrvenom spektroskopijom. Uspješno su određene i analizirane kristalne strukture svih osam spojeva. Bakrov(II) ion u spojevima je pentakoordiniran. U ekvatorijalnom položaju didentatno su vezani 1,10-fenantrolin te L-treoninat. Na peto koordinacijsko mjesto u apikalnom položaju vezana je molekula otapala (voda, metanol ili piridin), sulfatni ion ili karboksilatna skupina susjednog kompleksa. Osim strukturne karakterizacije te proučavanja interakcija unutar kristalne strukture spojeva, istraživani su utjecaji korištenog otapala (vode, metanola, piridina ili njihovih binarnih smjesa) na kristalizaciju i kristalne strukture.
Abstract (english)
Eight novel ternary coordination compounds of coper(II) with L-threonine and 1,10- phenanthroline were synthesized by solution-based and/or mechanochemichal synthesis methods. All obtained compounds were analyzed by single crystal X-ray diffraction analysis, and the compounds obtained by the mechanochemical method by powder X-ray diffraction analysis. Some of the compounds were additionally analyzed by infrared spectroscopy. Crystal structures of all eight compounds were determined and analyzed. The copper(II) ion is pentacoordinated with 1,10-phenanthroline and L-threonine didentatly bound in equatorial plane whereas solvent molecule (water, methanol or pyridine), sulphate ion or carboxylate group of neighbouring complex are bound apically. In addition to structural characterization and the study of interactions within the crystal structure, the effects of the solvent (water, methanol, pyridine or their binary mixtures) on crystallization and crystal structures were investigated.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:487286
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2023-10-16 10:21:19