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master's thesis
Adsorpcija poli(N-etil-4-vinilpiridinijeva) kationa na nanočestice silicijeva dioksida
Zagreb: University of Zagreb, Faculty of Science, 2024. urn:nbn:hr:217:985591
Gregurec, Filip
University of Zagreb
Faculty of Science
Department of Chemistry
University of Zagreb
Faculty of Science
Department of Physics

Institutional repository: Repository of the Faculty of Science

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Gregurec, F. (2024). Adsorpcija poli(N-etil-4-vinilpiridinijeva) kationa na nanočestice silicijeva dioksida (Master's thesis). Zagreb: University of Zagreb, Faculty of Science; Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:985591

Gregurec, Filip. "Adsorpcija poli(N-etil-4-vinilpiridinijeva) kationa na nanočestice silicijeva dioksida." Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, 2024. https://urn.nsk.hr/urn:nbn:hr:217:985591

Gregurec, Filip. "Adsorpcija poli(N-etil-4-vinilpiridinijeva) kationa na nanočestice silicijeva dioksida." Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, 2024. https://urn.nsk.hr/urn:nbn:hr:217:985591

Gregurec, F. (2024). 'Adsorpcija poli(N-etil-4-vinilpiridinijeva) kationa na nanočestice silicijeva dioksida', Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, accessed 09 May 2024, https://urn.nsk.hr/urn:nbn:hr:217:985591

Gregurec F. Adsorpcija poli(N-etil-4-vinilpiridinijeva) kationa na nanočestice silicijeva dioksida [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; Zagreb: University of Zagreb, Faculty of Science; 2024 [cited 2024 May 09] Available at: https://urn.nsk.hr/urn:nbn:hr:217:985591

F. Gregurec, "Adsorpcija poli(N-etil-4-vinilpiridinijeva) kationa na nanočestice silicijeva dioksida", Master's thesis, University of Zagreb, Faculty of Science, Zagreb; University of Zagreb, Faculty of Science, Zagreb, 2024. Available at: https://urn.nsk.hr/urn:nbn:hr:217:985591

Metadata
TitleAdsorpcija poli(N-etil-4-vinilpiridinijeva) kationa na nanočestice silicijeva dioksida
Title (english)Adsorption of poly(N-ethyl-4-vinylpyridinium) cations on silica particles
AuthorFilip Gregurec
MentorTajana Begović (mentor)
MentorDraginja Mrvoš-Sermek (mentor)
Committee memberMaja Planinić (predsjednik povjerenstva)
Committee memberDraginja Mrvoš-Sermek (član povjerenstva)
Committee memberTajana Begović (član povjerenstva)
Committee memberDavor Horvatić (član povjerenstva)
Committee memberDavor Kovačević (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
GranterUniversity of Zagreb
Faculty of Science
(Department of Physics)
Zagreb
Defense date and country2024-02-23, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Diplomski rad se sastoji od eksperimentalnog i metodičkog dijela. U eksperimentalnom dijelu istražena je adsorpcija poli(N-etil-4-vinilpiridinijeva) (P4VP) kationa i poli(natrijeva-4-stiren sulfonatnog) polianiona (PSS) na koloidne nanočestice SiO2. Koloidne čestice prije i nakon adsorpcije karakterizirane su metodom elektroforeze i dinamičkog raspršenja svjetlosti. Adsorpcija P4VP kationa na čestice SiO2 je analizirana primjenom modela Langmuirove i Freundlichove adsorpcijske izoterme. Konačan rezultat pokazuje ograničenu primjenjivost ovih modela na adsorpciju P4VP kationa na koloidne čestice SiO2. U metodičkom dijelu provedeno je preliminarno istraživanje o postojanju i rasponu učeničkih alternativnih koncepcija u okviru teme elektrokemija. Uzorak ispitanika činili su učenici dva razreda jedne zagrebačke srednje škole u čijem su školskom kurikulumu uvrštene laboratorijske vježbe iz nastave kemije. Za potrebe istraživanja kreiran je višeslojni test. Potvrđeno je da i u preliminarnoj fazi oblikovanja predloženi test može poslužiti kao koristan alat u otkrivanju učeničkih pogrešnih konceptualnih shvaćanja elektrokemije.
Abstract (english)
This Master Thesis consists of the experimental and the methodological part. In the experimental part of the Thesis, the adsorption process of poly(N-ethyl-4-vinylpyridine) cations (P4VP) and poly(sodium-4-styrene sulfonate) (PSS) anions onto silica nanoparticles was investigated. Silica nanoparticles with adsorbed polyelectrolyte were characterized using electrophoretic and dynamic light scattering methods. The adsorption process of P4VP cations was analyzed using Langmuir adsorption model and Freundlich adsorption model. Analysis show limited applicability of used models for adsorption process of P4VP cations onto colloidal silica particles. In the methodological part of the Thesis a preliminary research was conducted on the existence and range of students` alternative conceptions within the topic of electrochemistry. The test was conducted on a group of students from two classes of one highschool in Zagreb, whose school curriculum included laboratory exercises from chemistry classes. For the purpose of the research, four tier test was made. It was confirmed that even in the preliminary phase, the proposed test can serve as a useful tool in revealing students` conceptual misconceptions of electrochemistry.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:985591
ProjectNumber: IP-2020-02-9571
Title: Fizikalna kemija procesa na međupovršini mineral/otopina (poli)elektrolita
Title: Physical chemistry of processes at mineral/(poly)electrolyte solution interface
Acronym: POLYMIN2
Leader: Tajana Begović
Jurisdiction: Croatia
Funder: HRZZ
Funding stream: IP
Study programmeTitle: The University Integrated Undergraduate and Graduate Programme in Physics and Chemistry Education; specializations in: Physics and chemistry
Course: Physics and chemistry
Study programme type: university
Study level: integrated undergraduate and graduate
Academic / professional title: sveučilišni magistar edukacije fizike i kemije (sveučilišni magistar edukacije fizike i kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
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Created on2024-03-06 11:31:05