prikaz prve stranice dokumenta Sinteza i karakterizacija metalosupramolekulskih spojeva vanadija(V) s hidrazonskim ligandima
Embargo period 2025-09-13
master's thesis
Sinteza i karakterizacija metalosupramolekulskih spojeva vanadija(V) s hidrazonskim ligandima
Zagreb: University of Zagreb, Faculty of Science, 2024. urn:nbn:hr:217:765217
Plejić, Emanuela
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Plejić, E. (2024). Sinteza i karakterizacija metalosupramolekulskih spojeva vanadija(V) s hidrazonskim ligandima (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:765217

Plejić, Emanuela. "Sinteza i karakterizacija metalosupramolekulskih spojeva vanadija(V) s hidrazonskim ligandima." Master's thesis, University of Zagreb, Faculty of Science, 2024. https://urn.nsk.hr/urn:nbn:hr:217:765217

Plejić, Emanuela. "Sinteza i karakterizacija metalosupramolekulskih spojeva vanadija(V) s hidrazonskim ligandima." Master's thesis, University of Zagreb, Faculty of Science, 2024. https://urn.nsk.hr/urn:nbn:hr:217:765217

Plejić, E. (2024). 'Sinteza i karakterizacija metalosupramolekulskih spojeva vanadija(V) s hidrazonskim ligandima', Master's thesis, University of Zagreb, Faculty of Science, accessed 25 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:765217

Plejić E. Sinteza i karakterizacija metalosupramolekulskih spojeva vanadija(V) s hidrazonskim ligandima [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2024 [cited 2024 November 25] Available at: https://urn.nsk.hr/urn:nbn:hr:217:765217

E. Plejić, "Sinteza i karakterizacija metalosupramolekulskih spojeva vanadija(V) s hidrazonskim ligandima", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2024. Available at: https://urn.nsk.hr/urn:nbn:hr:217:765217

Metadata
TitleSinteza i karakterizacija metalosupramolekulskih spojeva vanadija(V) s hidrazonskim ligandima
Title (english)Synthesis and characterization of vanadium(V) metallosupramolecular compounds with hydrazone ligands
AuthorEmanuela Plejić
MentorVišnja Vrdoljak (mentor)
Committee memberVišnja Vrdoljak (predsjednik povjerenstva)
Committee memberBranimir Bertoša (član povjerenstva)
Committee memberPredrag Novak (član povjerenstva)
Committee memberJana Pisk (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2024-09-13, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U ovom diplomskom radu istražene su reakcije oksobis(pentan-2,4-dionato)vanadija(IV) i salicilaldehid izonikotinoil hidrazona (H2SIH), odnosno salicilaldehid nikotinoil hidrazona (H2SalNH) s metanolom, etanolom i propanolom. U reakcijama s ligandom H2SIH sintetizirani su tetramer [VO(SIH)(MeO)]44CH3OH, monomer [VO2(HSIH)] i polimer [VO(SIH)(PrO)]n. Reakcijama između oksobis(pentan-2,4-dionato)vanadija(IV) i H2SalNH u metanolu, etanolu i propanolu sintetizirani su monomer [VO(SalNH)(OMe)(HOMe)] te polimeri [VO(SalNH)(OEt)]n i [VO(SalNH)(OPr)]n. Spojevi su identificirani na temelju podataka dobivenih infracrvenom spektroskopijom, termogravimetrijskom analizom, difrakcijom rentgenskog zračenja na jediničnom kristalu te u polikristalnom uzorku.
Abstract (english)
In this thesis, the reactions of oxobis(pentan-2,4-dionato)vanadium(IV) with salicylaldehyde isonicotinoyl hydrazone (H2SIH) and salicylaldehyde nicotinoyl hydrazone (H2SalNH) with methanol, ethanol, and propanol were investigated. In the reactions with the H2SIH ligand, the tetramer [VO(SIH)(MeO)]4·4CH3OH, the monomer [VO2(HSIH)], and the polymer [VO(SIH)(PrO)]n were synthesized. Reactions between oxobis(pentan-2,4- dionato)vanadium(IV) and H2SalNH in methanol, ethanol, and propanol yielded the monomer [VO(SalNH)(OMe)(HOMe)] and the polymers [VO(SalNH)(OEt)]n and [VO(SalNH)(OPr)]n. The compounds were identified based on data obtained from infrared spectroscopy, thermogravimetric analysis, single-crystal X-ray diffraction, and powder X-ray diffraction
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:765217
ProjectNumber: IP-2022-10-7368
Title: Supramolekulski i hibridni metalo-organski koordinacijski sustavi – kooperativni učinci i predviđanje aktivnosti/svojstava
Title: SUPRAMOLECULAR AND HYBRID METAL-ORGANIC COORDINATION ASSEMBLIES – COOPERATIVE EFFECTS AND ACTIVITY/PROPERTY PREDICTION
Acronym: MOCASS
Leader: Višnja Vrdoljak
Jurisdiction: Croatia
Funder: Hrvatska zaklada za znanost
Funding stream: Research Projects
Study programmeTitle: Graduate university studies in chemistry; specializations in: Graduate university studies in chemistry
Course: Graduate university studies in chemistry
Study programme type: university
Study level: graduate
Academic / professional title: sveučilišni/a magistar/magistra kemije (sveučilišni/a magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsEmbargoed access
Embargo expiration date: 2025-09-13
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Created on2024-10-07 10:47:32