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master's thesis
Sinteza i strukturna karakterizacija klorometalatnih(II) soli propan-1,2-diamina
Zagreb: University of Zagreb, Faculty of Science, 2024. urn:nbn:hr:217:076049
Baričević, Dorja
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

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Baričević, D. (2024). Sinteza i strukturna karakterizacija klorometalatnih(II) soli propan-1,2-diamina (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:076049

Baričević, Dorja. "Sinteza i strukturna karakterizacija klorometalatnih(II) soli propan-1,2-diamina." Master's thesis, University of Zagreb, Faculty of Science, 2024. https://urn.nsk.hr/urn:nbn:hr:217:076049

Baričević, Dorja. "Sinteza i strukturna karakterizacija klorometalatnih(II) soli propan-1,2-diamina." Master's thesis, University of Zagreb, Faculty of Science, 2024. https://urn.nsk.hr/urn:nbn:hr:217:076049

Baričević, D. (2024). 'Sinteza i strukturna karakterizacija klorometalatnih(II) soli propan-1,2-diamina', Master's thesis, University of Zagreb, Faculty of Science, accessed 26 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:076049

Baričević D. Sinteza i strukturna karakterizacija klorometalatnih(II) soli propan-1,2-diamina [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2024 [cited 2024 November 26] Available at: https://urn.nsk.hr/urn:nbn:hr:217:076049

D. Baričević, "Sinteza i strukturna karakterizacija klorometalatnih(II) soli propan-1,2-diamina", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2024. Available at: https://urn.nsk.hr/urn:nbn:hr:217:076049

Metadata
TitleSinteza i strukturna karakterizacija klorometalatnih(II) soli propan-1,2-diamina
Title (english)Synthesis and structural characterization of propan-1,2-diamine chlorometalate(II) salts
AuthorDorja Baričević
MentorMirta Rubčić (mentor)
MentorEdi Topić (komentor)
Committee memberMirta Rubčić (predsjednik povjerenstva)
Committee memberIvan Nemet (član povjerenstva)
Committee memberĐani Škalamera (član povjerenstva)
Committee memberMarina Cindrić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2024-09-27, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U okviru ovoga diplomskog rada priređena je serija odabranih hibridnih organsko-anorganskih klorometalata(II) izvedenih iz propan-1,2-diamina. Spojevi su priređeni reakcijom odgovarajuće halogenidne soli MCl2 (M= Cu, Mn, Zn) te rac-propan-1,2-diamina, odnosno R-propan-1,2-diamina, uz dodatak klorovodične kiseline, klasičnom otopinskom sintezom, te u odabranim slučajevima mehanokemijskom sintezom. Pri različitim reakcijskim uvjetima priređene su ukupno tri različite klorokupratne(II) soli, dok je u slučaju kloromanganata(II) i klorocinkata(II) nastao samo jedan tip soli. Struktura spojeva u čvrstom stanju određena je na temelju podataka difrakcije rendgenskog zračenja na jediničnom kristalu. Spojevi su dodatno okarakterizirani u čvrstom stanju difrakcijom rendgenskog zračenja na praškastom uzorku, FT-IR spektroskopijom, te termičkom analizom.
Abstract (english)
As part of this thesis, a series of selected hybrid organic-inorganic chlorometalates(II) derived from propane-1,2-diamine were prepared. The compounds were prepared by the reaction of the appropriate halide salt MCl2 (M= Cu, Mn, Zn) and rac-propane-1,2-diamine, or R-propane-1,2-diamine, with the addition of hydrochloric acid and by classic solution synthesis, and in selected cases by mechanochemical synthesis. A total of three different chlorocuprate(II) salts were prepared under different reaction conditions, while only one type of salt was formed in the cases of chloromanganate(II) and chlorozincate(II). The structure of the compounds in the solid state was derived on the basis of X-ray diffraction data on the single crystal. The compounds were additionally characterized in the solid state by X-ray diffraction on a powder sample, FT-IR spectroscopy, and thermal analysis.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:076049
ProjectNumber: IP-2022-10-6321
Title: Evolucija složenih magnetskih i polarnih uređenja iz jednostavnih 2D podstruktura u slojevitim hibridnim organsko-anorganskim halogenometalatima
Title: Evolution of the complex magnetic and polar orders from simple 2D scaffolds in the layered hybrid organic-inorganic halometallates
Acronym: HOI2DEM
Leader: Damir Pajić
Jurisdiction: Croatia
Funder: Hrvatska zaklada za znanost
Funding stream: Research Projects
Study programmeTitle: Graduate university studies in chemistry; specializations in: Graduate university studies in chemistry
Course: Graduate university studies in chemistry
Study programme type: university
Study level: graduate
Academic / professional title: sveučilišni/a magistar/magistra kemije (sveučilišni/a magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2024-10-17 14:26:14