prikaz prve stranice dokumenta Priprava i karakterizacija halogenomanganata(II) izvedenih iz alifatskih triamina i tetraamina te njihovih derivata
  Download
PDF 3.89 MB
master's thesis
Priprava i karakterizacija halogenomanganata(II) izvedenih iz alifatskih triamina i tetraamina te njihovih derivata
Zagreb: University of Zagreb, Faculty of Science, 2024. urn:nbn:hr:217:703025
Rukavina, Luka
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Rukavina, L. (2024). Priprava i karakterizacija halogenomanganata(II) izvedenih iz alifatskih triamina i tetraamina te njihovih derivata (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:703025

Rukavina, Luka. "Priprava i karakterizacija halogenomanganata(II) izvedenih iz alifatskih triamina i tetraamina te njihovih derivata." Master's thesis, University of Zagreb, Faculty of Science, 2024. https://urn.nsk.hr/urn:nbn:hr:217:703025

Rukavina, Luka. "Priprava i karakterizacija halogenomanganata(II) izvedenih iz alifatskih triamina i tetraamina te njihovih derivata." Master's thesis, University of Zagreb, Faculty of Science, 2024. https://urn.nsk.hr/urn:nbn:hr:217:703025

Rukavina, L. (2024). 'Priprava i karakterizacija halogenomanganata(II) izvedenih iz alifatskih triamina i tetraamina te njihovih derivata', Master's thesis, University of Zagreb, Faculty of Science, accessed 26 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:703025

Rukavina L. Priprava i karakterizacija halogenomanganata(II) izvedenih iz alifatskih triamina i tetraamina te njihovih derivata [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2024 [cited 2024 November 26] Available at: https://urn.nsk.hr/urn:nbn:hr:217:703025

L. Rukavina, "Priprava i karakterizacija halogenomanganata(II) izvedenih iz alifatskih triamina i tetraamina te njihovih derivata", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2024. Available at: https://urn.nsk.hr/urn:nbn:hr:217:703025

Metadata
TitlePriprava i karakterizacija halogenomanganata(II) izvedenih iz alifatskih triamina i tetraamina te njihovih derivata
Title (english)Synthesis and characterization of halomanganates(II) derived from aliphatic triamines and tetraamines and their derivates
AuthorLuka Rukavina
MentorMirta Rubčić (mentor)
Committee memberMirta Rubčić (predsjednik povjerenstva)
Committee memberIvan Nemet (član povjerenstva)
Committee memberĐani Škalamera (član povjerenstva)
Committee memberMarina Cindrić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2024-09-27, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Hibridni organsko-anorganski halogenometalati (HOAH) privlače pažnju šire znanstvene zajednice s obzirom na izuzetna svojstva koje ti materijali potencijalno mogu imati, poput fotonaponskih, optičkih, električnih i magnetskih. U okviru ovog diplomskog rada ispitana je sinteza HOAH spojeva s manganom(II) kao metalnim centrom, kloridnim i bromidnim anionima kao ligandima te organskim kationima izvedenima iz odabranih triamina i tetraamina (dietilentriamin, DETA; N-(2-aminoetil)propan-1,3-diamin, N-P-1,3-DA i trietilentetraamin, TETA). Klasičnom otopinskom sintezom priređeni su hibridni organsko-anorganski halogenomanganati(II): (H3DETA)[MnCl5], (H3[N- P-1,3-DA])[MnCl5] i (H4TETA)[MnCl6]. Uz to, provedena je i sinteza halogenidnih soli (klorida i bromida) istih triamina i tetraamina: (H3DETA)Cl3, (H3[N-P-1,3-DA])Cl3, (H3[N-P-1,3-DA])Br3, (H4TETA)Cl4, (H4TETA)Br4 te (H4TETA)Br4·H2O. Priređeni spojevi okarakterizirani su FT-IR spektroskopijom, metodama termičke analize te difrakcijom rendgenskog zračenja na polikristalu i monokristalu. Pripravljeni kloromanganati(II) pripadaju skupini slojevitih 2D HOAH, gdje se između anorganskih slojeva kloromanganatnih(II) jedinki ugrađuju organski kationi.
Abstract (english)
Hybrid organic-inorganic halometalates (HOIHs) are currently in the spotlight of the wider scientific community due to the exceptional photovoltaic, optical, electrical and magnetic properties that these materials might display. Within the framework of this diploma thesis, synthesis of HOIH compounds with manganese(II) metal center, chloride and bromide anions as ligands and organic cations derived from triamines and tetraamines (diethylenetriamine, DETA; N-(2-aminoethyl)propane-1,3-diamine, N-P-1,3-DA and triethylenetetramine, TETA) was examined. By solution synthesis hybrid organic- inorganic halomanganates(II): (H3DETA)[MnCl5], (H3[N-P-1,3-DA])[MnCl5] and (H4TETA)[MnCl6] were prepared. In addition, the halide salts (chlorides and bromides) of the same triamines and tetraamines: (H3DETA)Cl3, (H3[N-P-1,3-DA])Cl3, (H3[N-P-1,3-DA])Br3, (H4TETA)Cl4, (H4TETA)Br4 and (H4TETA)Br4·H2O were synthesized. Compounds were characterized by FT-IR spectroscopy, thermal analysis and X-ray diffraction. Prepared hybrid chloromanganates(II) belong to the class of layered HOIHs.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:703025
Study programmeTitle: Graduate university studies in chemistry; specializations in: Graduate university studies in chemistry
Course: Graduate university studies in chemistry
Study programme type: university
Study level: graduate
Academic / professional title: sveučilišni/a magistar/magistra kemije (sveučilišni/a magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Terms of useLicence In copyright icon
Created on2024-10-18 09:53:12