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master's thesis
Priprava i karakterizacija spojeva nikla(II) s derivatima pirazina
Zagreb: University of Zagreb, Faculty of Science, 2017. urn:nbn:hr:217:542460
Kukavica, Zorica
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Kukavica, Z. (2017). Priprava i karakterizacija spojeva nikla(II) s derivatima pirazina (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:542460

Kukavica, Zorica. "Priprava i karakterizacija spojeva nikla(II) s derivatima pirazina." Master's thesis, University of Zagreb, Faculty of Science, 2017. https://urn.nsk.hr/urn:nbn:hr:217:542460

Kukavica, Zorica. "Priprava i karakterizacija spojeva nikla(II) s derivatima pirazina." Master's thesis, University of Zagreb, Faculty of Science, 2017. https://urn.nsk.hr/urn:nbn:hr:217:542460

Kukavica, Z. (2017). 'Priprava i karakterizacija spojeva nikla(II) s derivatima pirazina', Master's thesis, University of Zagreb, Faculty of Science, accessed 26 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:542460

Kukavica Z. Priprava i karakterizacija spojeva nikla(II) s derivatima pirazina [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2017 [cited 2024 November 26] Available at: https://urn.nsk.hr/urn:nbn:hr:217:542460

Z. Kukavica, "Priprava i karakterizacija spojeva nikla(II) s derivatima pirazina", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:217:542460

Metadata
TitlePriprava i karakterizacija spojeva nikla(II) s derivatima pirazina
Title (english)Synthesis and characterization of nickel(II) compounds with substituted pyrazines
AuthorZorica Kukavica
MentorŽeljka Soldin (mentor)
Committee memberŽeljka Soldin (predsjednik povjerenstva)
Committee memberVesna Petrović Peroković (član povjerenstva)
Committee memberSanda Rončević (član povjerenstva)
Committee memberMarijana Đaković (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2017-09-29, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Istražene su reakcije te su ispitani uvjeti priprave novih kompleksnih spojeva niklova(II) klorida, niklova(II) bromida i niklova(II) jodida s aminopirazinom (NH2-pyz) i klorpirazinom (Cl-pyz). Pripravljeni su sljedeći spojevi [NiCl2(NH2-pyz)4] (1), [NiCl2(NH2-pyz)2]n (2), [NiBr2(NH2-pyz)4] (3),[NiBr2(NH2-pyz)2]n (4), [NiI2(NH2-pyz)2]n (5), [NiCl2(Cl-pyz)2]n (6) i [NiBr2(Cl-pyz)2]n (7). Spojevi su okarakterizirani kemijskom analizom, infracrvenom spektroskopijom, termogravimetrijskom analizom i difrakcijom rentgenskog zračenja na praškastom uzorku. Spoju 1 je rentgenskom strukturnom analizom određena kristalna i molekulska struktura. Vodikove veze diktiraju način slaganja molekula u supramolekulskim strukturama spojeva s aminopirazinom, dok do udruživanja spojeva s klorpirazinom dolazi preko halogenskih veza.
Abstract (english)
The reaction conditions of nickel(II) chloride, nickel(II) bromide and nickel(II) iodide with aminopyrazine and chloropyrazine were investigated. The following complexes were prepared: [NiCl2(NH2-pyz)4] (1), [NiCl2(NH2-pyz)2]n (2), [NiBr2(NH2-pyz)4] (3),[NiBr2(NH2-pyz)2]n (4), [NiI2(NH2-pyz)2]n (5), [NiCl2(Cl-pyz)2]n (6) i [NiBr2(Cl-pyz)2]n (7). Compounds were characterized by chemical analysis, infrared spectroscopy, thermogravimetric analysis and X-ray powder diffraction. Compound 1 was structurally characterized by single crystal X-ray diffraction method. Supramolecular structure of aminopyrazine based complexes rely on hydrogen bonds, while halogen bond acts as main driving force in assembling of chloropyrazine based complexes.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:542460
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2019-09-29
Terms of useLicence In copyright icon
Created on2017-10-23 14:38:59