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master's thesis
Sinteza i strukturna karakterizacija kompleksnih soli [Co(NH3)6][Fe(C2O4)3] i [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2]
Zagreb: University of Zagreb, Faculty of Science, 2017. urn:nbn:hr:217:831842
Nakić, Kristian
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

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Nakić, K. (2017). Sinteza i strukturna karakterizacija kompleksnih soli [Co(NH3)6][Fe(C2O4)3] i [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2] (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:831842

Nakić, Kristian. "Sinteza i strukturna karakterizacija kompleksnih soli [Co(NH3)6][Fe(C2O4)3] i [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2]." Master's thesis, University of Zagreb, Faculty of Science, 2017. https://urn.nsk.hr/urn:nbn:hr:217:831842

Nakić, Kristian. "Sinteza i strukturna karakterizacija kompleksnih soli [Co(NH3)6][Fe(C2O4)3] i [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2]." Master's thesis, University of Zagreb, Faculty of Science, 2017. https://urn.nsk.hr/urn:nbn:hr:217:831842

Nakić, K. (2017). 'Sinteza i strukturna karakterizacija kompleksnih soli [Co(NH3)6][Fe(C2O4)3] i [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2]', Master's thesis, University of Zagreb, Faculty of Science, accessed 29 December 2024, https://urn.nsk.hr/urn:nbn:hr:217:831842

Nakić K. Sinteza i strukturna karakterizacija kompleksnih soli [Co(NH3)6][Fe(C2O4)3] i [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2] [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2017 [cited 2024 December 29] Available at: https://urn.nsk.hr/urn:nbn:hr:217:831842

K. Nakić, "Sinteza i strukturna karakterizacija kompleksnih soli [Co(NH3)6][Fe(C2O4)3] i [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2]", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:217:831842

Metadata
TitleSinteza i strukturna karakterizacija kompleksnih soli [Co(NH3)6][Fe(C2O4)3] i [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2]
Title (english)Synthesis and structural characterization of complex salts [Co(NH3)6][Fe(C2O4)3] and [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2]
AuthorKristian Nakić
MentorMarina Cindrić (mentor)
Committee memberMarina Cindrić (predsjednik povjerenstva)
Committee memberDavor Kovačević (član povjerenstva)
Committee memberSanda Rončević (član povjerenstva)
Committee memberVišnja Vrdoljak (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2017-09-25, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U okviru ovog diplomskog rada priređene su kompleksne soli [Co(NH3)6][Fe(C2O4)3], [CoC2O4(NH3)4]- -[Fe(C2O4)2(OH2)2] ∙ H2O i [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2] ∙ 2H2O. Spojevi su priređeni reakcijama izmjene kationa i aniona pri čemu su kao ishodne supstancije korišteni kompleksni spojevi [CoC2O4(NH3)4]NO3·H2O, K3[Fe(C2O4)3]·3H2O i FeC2O4. Prilikom priprave navedenih kompleksnih soli željeza(III) i kobalta(III) primijenjeni su različiti reakcijski uvjeti, kao što su npr. različite reakcijske temperature, mijenjan je množinski omjer reaktanata kao i volumen otapala. Ovisno o reakcijskim uvjetima bilo je moguće izolirati dvije hidratne forme kompleksne soli [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2], mono- i dihidrat. Rentgenskom strukturnom analizom je ustanovljeno da produkt formule [Co(NH3)6][Fe(C2O4)3] u vodenoj otopini podliježe transformaciji u dihidratnu formu [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2]. Pri transformaciji kod [Co(NH3)6][Fe(C2O4)3] dolazi do preraspodjele liganada u koordinacijskim sferama i željezovog(III) i kobaltovog(III) metalnog centra. Svi su spojevi identificirani i okarakterizirani temeljem podataka difrakcije rentgenskog zračenja na polikristalnom uzorku, infracrvene spektroskopije i termičke analize. Molekulska i kristalna struktura kompleksnih soli određena je difrakcijom rentgenskog zračenja na jediničnom kristalu.
Abstract (english)
In this diploma thesis three new complex salts were described, [Co(NH3)6][Fe(C2O4)3], [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2] ∙ H2O and [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2] ∙ 2H2O. Those complexes were prepared by reactions of ion exchange with [CoC2O4(NH3)4]NO3·H2O, K3[Fe(C2O4)3]·3H2O and FeC2O4 as reactants and at various reaction conditions, such as different reaction temperatures, molar ratio of reactants and solvent volumes. Depending on rection conditions it was possible to isolate two hydrate forms of [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2]: monohydrate and dihydrate. It was established that complex salt [Co(NH3)6][Fe(C2O4)3] undergoes transformation into dihydrate form of [CoC2O4(NH3)4][Fe(C2O4)2(OH2)2], in aqueous solution and at room temperature. Upon mentioned transformation, the rearangement of ligands within both iron(III) and cobalt(III) coordination spheres takes place. All compounds were identified and characterized by means of powder X-ray diffraction, IR spectroscopy and by thermal analysis. Molecular and crystal structure of complex salts was defined by means of single crystal X-ray diffraction.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:831842
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2019-09-25
Terms of useLicence In copyright icon
Created on2017-10-24 11:49:15