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master's thesis
Utjecaj reakcijskih uvjeta na ishod kondenzacije 2-hidroksi-1-naftaldehida i 4-aminopiridina
Zagreb: University of Zagreb, Faculty of Science, 2018. urn:nbn:hr:217:669202
Ivković, Martina
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Ivković, M. (2018). Utjecaj reakcijskih uvjeta na ishod kondenzacije 2-hidroksi-1-naftaldehida i 4-aminopiridina (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:669202

Ivković, Martina. "Utjecaj reakcijskih uvjeta na ishod kondenzacije 2-hidroksi-1-naftaldehida i 4-aminopiridina." Master's thesis, University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:669202

Ivković, Martina. "Utjecaj reakcijskih uvjeta na ishod kondenzacije 2-hidroksi-1-naftaldehida i 4-aminopiridina." Master's thesis, University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:669202

Ivković, M. (2018). 'Utjecaj reakcijskih uvjeta na ishod kondenzacije 2-hidroksi-1-naftaldehida i 4-aminopiridina', Master's thesis, University of Zagreb, Faculty of Science, accessed 21 December 2024, https://urn.nsk.hr/urn:nbn:hr:217:669202

Ivković M. Utjecaj reakcijskih uvjeta na ishod kondenzacije 2-hidroksi-1-naftaldehida i 4-aminopiridina [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2018 [cited 2024 December 21] Available at: https://urn.nsk.hr/urn:nbn:hr:217:669202

M. Ivković, "Utjecaj reakcijskih uvjeta na ishod kondenzacije 2-hidroksi-1-naftaldehida i 4-aminopiridina", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:217:669202

Metadata
TitleUtjecaj reakcijskih uvjeta na ishod kondenzacije 2-hidroksi-1-naftaldehida i 4-aminopiridina
Title (english)The influence of reaction conditions on the outcome of 2-hydroxy-1-naphthaldehyde condensation with 4-aminopyridine
AuthorMartina Ivković
MentorDominik Cinčić (mentor)
Committee memberDominik Cinčić (predsjednik povjerenstva)
Committee memberInes Primožič (član povjerenstva)
Committee memberIva Juranović Cindrić (član povjerenstva)
Committee memberVladimir Stilinović (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2018-02-14, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U sklopu ovog diplomskog rada izučavana je mogućnost kondenzacije 4-aminopiridina i 2-hidroksi-1-naftaldehida metodama mehanokemijske sinteze i sinteze u otopini, kao poznatim načinima dobivanja imina, te metodom ubrzanog starenja. Promjenom množinskog omjera reaktanata, vrste otapala i vremena trajanja reakcije pokušalo se doći do spoznaja o reaktivnosti prekursora te utjecaju različitih reakcijskih uvjeta na ishod sinteze. Pripravljena su dva jedinična kristala metodama sinteze u otopini, jedan derivat 1,2-naftokinona te kokristal imina i 2-hidroksi-1-naftaldehida. Dobiveni produkti izučavani su metodom difrakcije rentgenskih zraka na praškastom uzorku, FTIR spektroskopijom, termogravimetrijom i razlikovno-pretražnom kalorimetrijom. Za oba pripravljena kristala metodom difrakcije rentgenskog zračenja na jediničnom kristalu iznađena je molekulska i kristalna struktura.
Abstract (english)
Within this diploma thesis, a possibility of 2-hydroxy-1-naphthaldehyde condensation with 4-aminopyridine was studied by mechanochemical and traditional solution synthesis methods, which are traditional methods for obtaining imines, as well as by the accelerated aging method. The goal was to attain further insights into precursor reactivity and the effect of various reaction conditions on the outcome of synthesis by changing the molar ratio of reactants, solvent types and reaction time. Two single-crystals were obtained by solution synthesis, 4-ethoxy-1,2-naphthoquinone and a cocrystal of imine and 2-hydroxy-1-naphthaldehyde. Synthesized compounds were described by powder X-ray diffraction, FTIR spectroscopy thermogravimetry and differential scanning calorimetry. The crystal and molecular structures of the two prepared compounds were determined by single-crystal X-ray diffraction.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:669202
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2020-02-14
Terms of useLicence In copyright icon
Created on2018-02-21 14:38:57