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master's thesis
Supramolekulsko udruživanje kompleksa bakra(I) i bakra(II) s pirazinskim ligandima
Zagreb: University of Zagreb, Faculty of Science, 2017. urn:nbn:hr:217:428225
Kovačec, Lucija
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Kovačec, L. (2017). Supramolekulsko udruživanje kompleksa bakra(I) i bakra(II) s pirazinskim ligandima (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:428225

Kovačec, Lucija. "Supramolekulsko udruživanje kompleksa bakra(I) i bakra(II) s pirazinskim ligandima." Master's thesis, University of Zagreb, Faculty of Science, 2017. https://urn.nsk.hr/urn:nbn:hr:217:428225

Kovačec, Lucija. "Supramolekulsko udruživanje kompleksa bakra(I) i bakra(II) s pirazinskim ligandima." Master's thesis, University of Zagreb, Faculty of Science, 2017. https://urn.nsk.hr/urn:nbn:hr:217:428225

Kovačec, L. (2017). 'Supramolekulsko udruživanje kompleksa bakra(I) i bakra(II) s pirazinskim ligandima', Master's thesis, University of Zagreb, Faculty of Science, accessed 09 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:428225

Kovačec L. Supramolekulsko udruživanje kompleksa bakra(I) i bakra(II) s pirazinskim ligandima [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2017 [cited 2024 November 09] Available at: https://urn.nsk.hr/urn:nbn:hr:217:428225

L. Kovačec, "Supramolekulsko udruživanje kompleksa bakra(I) i bakra(II) s pirazinskim ligandima", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2017. Available at: https://urn.nsk.hr/urn:nbn:hr:217:428225

Metadata
TitleSupramolekulsko udruživanje kompleksa bakra(I) i bakra(II) s pirazinskim ligandima
Title (english)Supramolecular assemblies of Cu(I) and Cu(II) pyrazine based complexes
AuthorLucija Kovačec
MentorŽeljka Soldin (mentor)
Committee memberŽeljka Soldin (predsjednik povjerenstva)
Committee memberVesna Petrović Peroković (član povjerenstva)
Committee memberSanda Rončević (član povjerenstva)
Committee memberBiserka Prugovečki (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2017-02-20, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Istražene su reakcije i ispitani uvjeti priprave novih kompleksnih spojeva bakrovog(II) klorida i bakrovog(II) bromida s klorpirazinom (Cl−pz), brompirazinom (Br−pz) i jodpirazinom (I−pz). Pripravljeni su sljedeći spojevi [CuCl2(Cl‒pz)2] (1), [CuCl2(Br‒pz)2] (2), [CuCl2(I‒pz)2] (3a), [CuCl2(I‒pz)2] (3b), [CuBr2(Cl‒pz)2] (4), [CuBr2(Br‒pz)2] (5), [CuBr(Br‒pz)]n (6), [CuBr2(I‒pz)2] (7) i [CuBr(I‒pz)]n (8). Spojevi su okarakterizirani kemijskom analizom, infracrvenom spektroskopijom, termogravimetrijskom analizom i difrakcijom rentgenskog zračenja na praškastom uzorku. Spojevima 3b, 6, 7 i 8 je rentgenskom strukturnom analizom određena kristalna i molekulska struktura. Ustanovljeno je da bakar(II) s halogenpirazinima daje jednostavne monomerne molekule u kojima je atom bakra kvadratno-planarno koordiniran, dok bakar(I) polimerizira te nastaju 2D-koordinacijski polimeri. Neovisno o dimenzionalnosti gradbenih jedinica do supramolekulskog udruživanja dolazi preko istog tipa halogenskih veza, osim kod spoja 3b gdje je pronađen drugačiji supramolekulski motiv.
Abstract (english)
The reaction conditions of copper(II) chloride and copper(II) bromide with chloropyrazine, bromopyrazine and iodopyrazine were investigated. The following complexes were prepared: [CuCl2(Cl‒pz)2] (1), [CuCl2(Br‒pz)2] (2), [CuCl2(I‒pz)2] (3a), [CuCl2(I‒pz)2] (3b), [CuBr2(Cl‒pz)2] (4), [CuBr2(Br‒pz)2] (5), [CuBr(Br‒pz)]n (6), [CuBr2(I‒pz)2] (7) i [CuBr(I‒pz)]n (8). Compounds were characterized by chemical analysis, infrared spectroscopy, thermogravimetric analysis and X-ray powder diffraction. Compounds 3a, 6, 7 i 8 were structurally characterized by single crystal X-ray diffraction method. Structural investigation revealed that Cu(II) with halopyrazines form simple monomeric square-planar building units, while Cu(I) polymerizes and gives 2D-layered building blocks. Regardless of their dimensionality, the building units are assembled into supramolecular architectures via the same type of halogen-bonding. Only in the case of 3b a different supramolecular motif was found.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:428225
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2019-02-20
Terms of useLicence In copyright icon
Created on2017-03-10 09:44:58