prikaz prve stranice dokumenta Strukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima
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master's thesis
Strukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima
Zagreb: University of Zagreb, Faculty of Science, 2018. urn:nbn:hr:217:005767
Mandarić, Mirna
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Mandarić, M. (2018). Strukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:005767

Mandarić, Mirna. "Strukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima." Master's thesis, University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:005767

Mandarić, Mirna. "Strukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima." Master's thesis, University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:005767

Mandarić, M. (2018). 'Strukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima', Master's thesis, University of Zagreb, Faculty of Science, accessed 04 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:005767

Mandarić M. Strukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2018 [cited 2024 November 04] Available at: https://urn.nsk.hr/urn:nbn:hr:217:005767

M. Mandarić, "Strukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:217:005767

Metadata
TitleStrukturna raznolikost kompleksnih spojeva molibdena(VI) s hidrazonskim ligandima
Title (english)Structural diversity in molybdenum(VI) complexes with hydrazone-based ligands
AuthorMirna Mandarić
MentorVišnja Vrdoljak (mentor)
Committee memberVišnja Vrdoljak (predsjednik povjerenstva)
Committee memberTajana Preočanin (član povjerenstva)
Committee memberSanda Rončević (član povjerenstva)
Committee memberMarina Cindrić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2018-04-26, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U okviru ovog diplomskog rada ispitani su uvjeti nastajanja kompleksa molibdena(VI) s derivatima nikotinhidrazida koji sadrže O i N donorne atome. Provedene su reakcije N'-(2- hidroksi-3-metoksibenziliden)nikotinhidrazona (H2VanNH) i N'-(2-hidroksi-4- metoksibenziliden)nikotinhidrazona (H24OMeSalNH) sa spojevima molibdena(VI), bis(pentan-2,4-dionato)dioksomolibdenom(VI) ([MoO2(acac)2]) i diklorodioksomolibdenom(VI) ([MoO2Cl2]). Reakcije su provedene u metanolu pri različitim temperaturama te su dobiveni kompleksi [MoO2(HVanNH)(MeOH)]Cl, [MoO2(HVanNH)Cl], [MoO2(H4OMeSalNH)Cl] i [MoO2(4OMeSalNH)(MeOH)] (α forma). Reakcijom [MoO2(HVanNH)Cl] s Et3N priređen je koordinacijski polimer [MoO2(VanNH)]n, a deprotonacijom [MoO2(H4OMeSalNH)Cl] je dobiven mononuklearni kompleks [MoO2(4OMeSalNH)(MeOH)] (β forma). Reakcija provedena u solvotermalnim uvjetima pri 110 °C rezultirala je nastajanje polinuklearnog spoja [MoO2(4OMeSalNH)]n. Dobiveni produkti okarakterizirani su na osnovi podataka IR spektroskopije, klasične kemijske analize i termičke analize. Postojanje samo jedne faze potvrđeno je usporedbom difraktograma praha.
Abstract (english)
In this Diploma thesis the synthesis conditions and formation of molybdenum(VI) complexes with nicotinic hydrazide derivatives containing O and N donor atoms were investigated. Reactions of N'-(2-hydroxy-3-methoxybenzilidene)nicotinhydrazone (H2VanNH) and N'-(2-hydroxy-4- methoxybenzilidene)nicotinhydrazone (H24OMeSalNH) with molybdenum(VI) compounds bis(pentane-2,4-dionato)dioxomolybdenum(VI) ([MoO2(acac)2]) and dichlorodioxomolybdenum(VI) ([MoO2Cl2]) were carried out. Complexes [MoO2(HVanNH)(MeOH)]Cl, [MoO2(HVanNH)Cl], [MoO2(H4OMeSalNH)Cl] and [MoO2(4OMeSalNH)(MeOH)] (α form) were obtained when reactions were carried out in methanol at various temperatures,. The coordination polymer [MoO2(VanNH)]n was prepared upon reaction [MoO2(HVanNH)Cl] with Et3N, whereas the mononuclear complex [MoO2(4OMeSalNH)(MeOH)] (β form) was prepared by deprotonation of [MoO2(H4OMeSalNH)Cl]. This reaction performed under solvothermal conditions at 110 °C yielded the polynuclear [MoO2(4OMeSalNH)]n complex. The obtained complexes were characterized by IR spectroscopy, chemical analysis and thermal analysis. The existance of only one phase was confirmed by comparison of the PXRD patterns.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:005767
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2020-04-17
Terms of useLicence In copyright icon
Created on2018-05-07 13:29:17