prikaz prve stranice dokumenta Kokristali bis(acetilacetonatnih) kompleksa prijelaznih metala s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom
  Download
PDF 5.58 MB
master's thesis
Kokristali bis(acetilacetonatnih) kompleksa prijelaznih metala s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom
Zagreb: University of Zagreb, Faculty of Science, 2018. urn:nbn:hr:217:986173
Grgurić, Toni
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Grgurić, T. (2018). Kokristali bis(acetilacetonatnih) kompleksa prijelaznih metala s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:986173

Grgurić, Toni. "Kokristali bis(acetilacetonatnih) kompleksa prijelaznih metala s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom." Master's thesis, University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:986173

Grgurić, Toni. "Kokristali bis(acetilacetonatnih) kompleksa prijelaznih metala s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom." Master's thesis, University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:986173

Grgurić, T. (2018). 'Kokristali bis(acetilacetonatnih) kompleksa prijelaznih metala s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom', Master's thesis, University of Zagreb, Faculty of Science, accessed 20 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:986173

Grgurić T. Kokristali bis(acetilacetonatnih) kompleksa prijelaznih metala s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2018 [cited 2024 November 20] Available at: https://urn.nsk.hr/urn:nbn:hr:217:986173

T. Grgurić, "Kokristali bis(acetilacetonatnih) kompleksa prijelaznih metala s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:217:986173

Metadata
TitleKokristali bis(acetilacetonatnih) kompleksa prijelaznih metala s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom
Title (english)Cocrystals of bis(acetylacetonato) complexes of transition metals with 1,4-diiodotetrafluorobenzene and 1,4-dibromotetrafluorobenzene
AuthorToni Grgurić
MentorVladimir Stilinović (mentor)
Committee memberVladimir Stilinović (predsjednik povjerenstva)
Committee memberIvan Kodrin (član povjerenstva)
Committee memberNikola Bregović (član povjerenstva)
Committee memberDominik Cinčić (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2018-05-28, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Inorganic Chemistry
Abstract
U sklopu ovog diplomskog rada je mehanokemijskom sintezom i sintezom iz otopine proučuvan potencijal bis(acetilacetonatnih) kompleksa prijelaznih metala kao akceptora halogenske veze kroz kelatirajuće atome kisika. U svrhu toga pripravljeno je šest bis(acetilacetonatnih) kompleksa s metalnim centrima Cu2+, Pd2+, VO2+, Ni2+, Co2+, Zn2+ koji su potom kokristalizirani s 1,4-dijodtetrafluorbenzenom i 1,4-dibromtetrafluorbenzenom kao donorima halogenske veze. Pripravljeni kokristali izučavani su metodom rentgenske difrakcije na praškastom uzorku, termogravimetrijom i diferencijalnom pretražnom kalorimetrijom. Za osam kokristala metodom rentgenske difrakcije na jediničnim kristalima iznađena je molekulska i kristalna struktura.
Abstract (english)
Within this diploma thesis potential of bis(acetylacetonato) complexes of transition metals as halogen bond acceptors through chelating oxygen atoms was studied. For that purpose six bis(acetylacetonato) complexes of transition metals with metal centers Cu2+, Pd2+, VO2+, Ni2+, Co2+, Zn2+ were prepared and cocrystalized with 1,4-diiodotetrafluorobenzene and 1,4- dibromotetrafluorobenzene. Cocrystals were prepared by mechanochemical synthesis and synthesis from solution. The compounds were described by powder X-ray diffraction, thermogravimetry and differential scanning calorimetry. The crystal and molecular structures of eight prepared cocrystals was determined by single crystal X-ray diffraction.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:986173
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2020-05-29
Terms of useLicence In copyright icon
Created on2018-06-05 07:53:05