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master's thesis
Sklonost aldehidne skupine sudjelovanju u halogenskoj vezi u kokristalima 2-hidroksi-1-naftaldehida i halogenperfluoriranih benzena ; Mehanokemija i nastava kemije
Zagreb: University of Zagreb, Faculty of Science, 2018. urn:nbn:hr:217:178978
Fotović, Luka
University of Zagreb
Faculty of Science
Department of Chemistry
University of Zagreb
Faculty of Science
Department of Biology

Institutional repository: Repository of the Faculty of Science

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Fotović, L. (2018). Sklonost aldehidne skupine sudjelovanju u halogenskoj vezi u kokristalima 2-hidroksi-1-naftaldehida i halogenperfluoriranih benzena ; Mehanokemija i nastava kemije (Master's thesis). Zagreb: University of Zagreb, Faculty of Science; Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:178978

Fotović, Luka. "Sklonost aldehidne skupine sudjelovanju u halogenskoj vezi u kokristalima 2-hidroksi-1-naftaldehida i halogenperfluoriranih benzena ; Mehanokemija i nastava kemije." Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:178978

Fotović, Luka. "Sklonost aldehidne skupine sudjelovanju u halogenskoj vezi u kokristalima 2-hidroksi-1-naftaldehida i halogenperfluoriranih benzena ; Mehanokemija i nastava kemije." Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:178978

Fotović, L. (2018). 'Sklonost aldehidne skupine sudjelovanju u halogenskoj vezi u kokristalima 2-hidroksi-1-naftaldehida i halogenperfluoriranih benzena ; Mehanokemija i nastava kemije', Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, accessed 23 December 2024, https://urn.nsk.hr/urn:nbn:hr:217:178978

Fotović L. Sklonost aldehidne skupine sudjelovanju u halogenskoj vezi u kokristalima 2-hidroksi-1-naftaldehida i halogenperfluoriranih benzena ; Mehanokemija i nastava kemije [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; Zagreb: University of Zagreb, Faculty of Science; 2018 [cited 2024 December 23] Available at: https://urn.nsk.hr/urn:nbn:hr:217:178978

L. Fotović, "Sklonost aldehidne skupine sudjelovanju u halogenskoj vezi u kokristalima 2-hidroksi-1-naftaldehida i halogenperfluoriranih benzena ; Mehanokemija i nastava kemije", Master's thesis, University of Zagreb, Faculty of Science, Zagreb; University of Zagreb, Faculty of Science, Zagreb, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:217:178978

Metadata
TitleSklonost aldehidne skupine sudjelovanju u halogenskoj vezi u kokristalima 2-hidroksi-1-naftaldehida i halogenperfluoriranih benzena ; Mehanokemija i nastava kemije
Title (english)The halogen bonding proclivity of the aldehyde group in cocrystals of 2-hydroxy-1-naphthaldehyde and halogenoperfluorobenzenes ; Mechanochemistry and chemical education
AuthorLuka Fotović
MentorDominik Cinčić (mentor)
MentorNenad Judaš (mentor)
Committee memberDominik Cinčić (predsjednik povjerenstva)
Committee memberNenad Judaš (član povjerenstva)
Committee memberMirela Sertić Perić (član povjerenstva)
Committee memberIvana Buj (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
GranterUniversity of Zagreb
Faculty of Science
(Department of Biology)
Zagreb
Defense date and country2018-06-19, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U sklopu znanstvenog dijela ovog diplomskog rada izučavana je sklonost aldehidne skupine sudjelovanju u halogenskoj vezi u kokristalima 2-hidroksi-1-naftaldehida i halogenperfluoriranih benzena. U tu svrhu provedena je mehanokemijska sinteza ciljanih spojeva pri čemu su uspješno pripravljeni kokristali s tetrafluor-1,4-dijodbenzenom, tetrafluor-1,3-dijodbenzenom, 1,4-dibromtetrafluorbenzenom i trifluor-1,3,5-trijodbenzenom. Sintezom iz otopine priravljeni su jedinični kristali te je difrakcijom rentgenskog zračenja u jediničnim kristalima iznađena molekulska i kristalna struktura istih. U sklopu metodičkog dijela dan je literaturni pregled mehanokemijske sinteze i sinteze ubrzanim starenjem kao reprezentativnih primjera sintetskih metoda „zelene kemije”. Analizirana je pojava istih u postojećim planovima i programima te udžbenicima za poučavanje kemije za osnovno i srednjoškolsko obrazovanje. Naposlijetku, dan je prijedlog nastavnog sata u kojem se učenici poučavaju o dvjema navedenim metodama te o difrakciji rentgenskog zračenja u polikristalinim uzorcima.
Abstract (english)
The scientific part of this graduate thesis consists of a study into the halogen bonding proclivity of the aldehyde functional group in cocrystals of 2-hydroxy-1-naphthaldehyde and haloperfluorinated benzenes. To that end, mechanochemical synthesis with a series of compounds has been performed, yielding cocrystals of tetrafluoro-1,4-diiodobenzene, tetrafluoro-1,3-diiodobenzene, 1,4-dibromotetrafluorobenzene and trifluoro-1,3,5- triiodobenzene. Single crystals were obtained by solution-based methods, and their crystal and molecular structures determined by single crystal X-ray diffraction. The methodical part contains a literature review on the topics of mechanochemical synthesis and accelerated aging synthesis, which are representative examples of the "green chemistry" approach. The existing curricula and textbooks for teaching chemistry have been analyzed. Finally, presented herein is an example of a lesson on the two methods, as well as on X-ray diffraction by polycrystalline samples.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:178978
Study programmeTitle: Integrated undergraduate and graduate university study of Biology and Chemistry Education; specializations in: Integrated undergraduate and graduate university study of Biology and Chemistry Education
Course: Integrated undergraduate and graduate university study of Biology and Chemistry Education
Study programme type: university
Study level: integrated undergraduate and graduate
Academic / professional title: magistar/magistra edukacije biologije i kemije (magistar/magistra edukacije biologije i kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2020-06-19
Terms of useLicence In copyright icon
Created on2018-07-09 12:27:01