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master's thesis
Halogenska interakcija u supramolekulskim arhitekturama halogenidnih kadmijevih(II) kompleksa s derivatima pirazina ; Kemijska svojstva alkohola-primjer dobre nastavne prakse
Zagreb: University of Zagreb, Faculty of Science, 2016. urn:nbn:hr:217:946175
Nakani, Tea
University of Zagreb
Faculty of Science
Department of Chemistry
University of Zagreb
Faculty of Science
Department of Biology

Institutional repository: Repository of the Faculty of Science

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Nakani, T. (2016). Halogenska interakcija u supramolekulskim arhitekturama halogenidnih kadmijevih(II) kompleksa s derivatima pirazina ; Kemijska svojstva alkohola-primjer dobre nastavne prakse (Master's thesis). Zagreb: University of Zagreb, Faculty of Science; Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:946175

Nakani, Tea. "Halogenska interakcija u supramolekulskim arhitekturama halogenidnih kadmijevih(II) kompleksa s derivatima pirazina ; Kemijska svojstva alkohola-primjer dobre nastavne prakse." Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, 2016. https://urn.nsk.hr/urn:nbn:hr:217:946175

Nakani, Tea. "Halogenska interakcija u supramolekulskim arhitekturama halogenidnih kadmijevih(II) kompleksa s derivatima pirazina ; Kemijska svojstva alkohola-primjer dobre nastavne prakse." Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, 2016. https://urn.nsk.hr/urn:nbn:hr:217:946175

Nakani, T. (2016). 'Halogenska interakcija u supramolekulskim arhitekturama halogenidnih kadmijevih(II) kompleksa s derivatima pirazina ; Kemijska svojstva alkohola-primjer dobre nastavne prakse', Master's thesis, University of Zagreb, Faculty of Science; University of Zagreb, Faculty of Science, accessed 29 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:946175

Nakani T. Halogenska interakcija u supramolekulskim arhitekturama halogenidnih kadmijevih(II) kompleksa s derivatima pirazina ; Kemijska svojstva alkohola-primjer dobre nastavne prakse [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; Zagreb: University of Zagreb, Faculty of Science; 2016 [cited 2024 November 29] Available at: https://urn.nsk.hr/urn:nbn:hr:217:946175

T. Nakani, "Halogenska interakcija u supramolekulskim arhitekturama halogenidnih kadmijevih(II) kompleksa s derivatima pirazina ; Kemijska svojstva alkohola-primjer dobre nastavne prakse", Master's thesis, University of Zagreb, Faculty of Science, Zagreb; University of Zagreb, Faculty of Science, Zagreb, 2016. Available at: https://urn.nsk.hr/urn:nbn:hr:217:946175

Metadata
TitleHalogenska interakcija u supramolekulskim arhitekturama halogenidnih kadmijevih(II) kompleksa s derivatima pirazina ; Kemijska svojstva alkohola-primjer dobre nastavne prakse
Title (english)Halogen interaction in supramolecular architectures of halide complexes of cadmium(II) with pyrazine derivatives ; Chemical properties of alcohols-an example of good teaching practice
AuthorTea Nakani
MentorMarijana Đaković (mentor)
MentorDraginja Mrvoš-Sermek (mentor)
Committee memberMarijana Đaković (predsjednik povjerenstva)
Committee memberDraginja Mrvoš-Sermek (član povjerenstva)
Committee memberInes Radanović (član povjerenstva)
Committee memberRenata Matoničkin Kepčija (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
GranterUniversity of Zagreb
Faculty of Science
(Department of Biology)
Zagreb
Defense date and country2016-12-20, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Ovaj diplomski rad sastoji se od dvije cjeline: istraživačkog i metodičkog dijela. U istraživačkom dijelu sintetiziran je niz kadmijevih(II) koordinacijskih polimera s 2- kloropirazinom (2-Clpz), 2-bromopirazinom (2-Brpz) i 2-jodopirazinom(2-Ipz) s raznim halogenidnim anionima kao protuionima. Kristalne strukture kompleksa [CdBr2(2-Clpz)2]n, [CdBr2(2-Brpz)2]n, [CdI2(2-Brpz)2]n, [CdI2(2-Ipz)2]n određene su rentgenskom strukturnom analizom. Kompleksi su okarakterizirani IR spektroskopijom, metodom rentgenske difrakcije u polikristalnom uzorku, termogravimetrijskom analizom i diferencijalnom skenirajućom kalorimetrijom. Ustanovljeno je da se najbliži polimerni lanci međusobno povezuju halogenskim interakcijama između halogenog atoma halopirazinskog liganda i halogenidnog iona vezanog na kadmijev(II) kation neoivsno o halogenom atomu te halogenidnom ionu. U metodičkom dijelu rada pod naslovom „Kemijska svojstva alkohola – primjer dobre nastavne prakse“, metodički je preoblikovan pokus pomoću kojeg se principi „zelene kemije“ integriraju u nastavni proces. Predložen je nastavni dvosat učenja otkrivanjem u kojem su ciljana obrazovna postignuća za uzrast učenika četvrtog razreda gimnazije povezana s opažanjima iz pokusa.
Abstract (english)
This Diploma thesis consists of two parts: the research part and the methodological part. In the research part a series of cadmium(II) coordination polymers was prepared with 2- chloropyrazine (2-Clpz), 2-bromopyrazine (2-Brpz) and 2-iodopyrazine (2-Ipz) and halide anions as counter ions. The crystal structures of the complexes [CdBr2(2-Clpz)2]n, [CdBr2(2-Brpz)2]n, [CdI2(2- Brpz)2]n, [CdI2(2-Ipz)2]n were determined by single crystal Xray structural analysis. The complexes were studied by infrared spectroscopy, PXRD methods, thermal analysis and differential scanning calorimetry. Crystal structure analysis revealed that the closest polymeric chains are interconnected via halogen interactions between halogen atoms and halide ions coordinated on metal centers regardless of the halogen atom and halide ions. In the methodological part of the Thesis entitled „Chemical properties of alcohols – an example of good teaching practice" one experiment was methodically transformed with integrated principles of „green chemistry“. Two hour discovery lesson was suggested, in which the targeted educational achievement for students of the fourth year of high school are associated with the observations from the experiment.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:946175
Study programmeTitle: Integrated undergraduate and graduate university study of Biology and Chemistry Education; specializations in: Integrated undergraduate and graduate university study of Biology and Chemistry Education
Course: Integrated undergraduate and graduate university study of Biology and Chemistry Education
Study programme type: university
Study level: integrated undergraduate and graduate
Academic / professional title: magistar/magistra edukacije biologije i kemije (magistar/magistra edukacije biologije i kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2018-12-20
Terms of useLicence In copyright icon
Created on2017-03-22 13:32:34