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master's thesis
Kinetika polimerizacije 1,3-dinitrozobenzena u čvrstom stanju
Zagreb: University of Zagreb, Faculty of Science, 2018. urn:nbn:hr:217:873901
Pavković, Margareta
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Pavković, M. (2018). Kinetika polimerizacije 1,3-dinitrozobenzena u čvrstom stanju (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:873901

Pavković, Margareta. "Kinetika polimerizacije 1,3-dinitrozobenzena u čvrstom stanju." Master's thesis, University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:873901

Pavković, Margareta. "Kinetika polimerizacije 1,3-dinitrozobenzena u čvrstom stanju." Master's thesis, University of Zagreb, Faculty of Science, 2018. https://urn.nsk.hr/urn:nbn:hr:217:873901

Pavković, M. (2018). 'Kinetika polimerizacije 1,3-dinitrozobenzena u čvrstom stanju', Master's thesis, University of Zagreb, Faculty of Science, accessed 22 November 2024, https://urn.nsk.hr/urn:nbn:hr:217:873901

Pavković M. Kinetika polimerizacije 1,3-dinitrozobenzena u čvrstom stanju [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2018 [cited 2024 November 22] Available at: https://urn.nsk.hr/urn:nbn:hr:217:873901

M. Pavković, "Kinetika polimerizacije 1,3-dinitrozobenzena u čvrstom stanju", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2018. Available at: https://urn.nsk.hr/urn:nbn:hr:217:873901

Metadata
TitleKinetika polimerizacije 1,3-dinitrozobenzena u čvrstom stanju
Title (english)Kinetics of polymerization of 1,3-dinitrosobenzene in solid state
AuthorMargareta Pavković
MentorIvana Biljan (mentor)
Committee memberIvana Biljan (predsjednik povjerenstva)
Committee memberSanda Rončević (član povjerenstva)
Committee memberŽeljka Soldin (član povjerenstva)
Committee memberIvan Kodrin (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2018-11-22, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U sklopu ovog rada istražena je kinetika polimerizacije 1,3–dinitrozobenzena u čvrstom stanju u različitim topokemijskim okolinama. 1,3–Dinitrozobenzen sintetiziran je redukcijom 1,3– dinitrobenzena do odgovarajućeg hidroksilamina, koji je potom oksidiran do 1,3– dinitrozobenzena. Kinetika polimerizacije 1,3–dinitrozobenzena istražena je nakon kriogene fotolize polimera u KBr pastili pri kriogenim uvjetima te nakon kriogene depozicije para monomera na pločicu cezijeva jodida. Kinetike reakcija polimerizacije praćene su pri različitim temperaturama vremenski razlučenom IR spektroskopijom. Iz temperaturne ovisnosti koeficijenta brzina reakcija određeni su aktivacijski parametri za reakciju polimerizacije 1,3– dinitrozobenzena.
Abstract (english)
Within this work, kinetics of solid–state polymerization of 1,3–dinitrosobenzene in different topochemical environments was studied. 1,3–Dinitrosobenzene was synthetised by reduction of 1,3–dinitrobenzene to corresponding hydroxylamine, which was subsequently oxidized to 1,3–dinitrosobenzene. Kinetics of polymerization of 1,3–dinitrosobenzene was studied after cryogenic photolysis of polymers in KBr pellet and after cryogenic deposition of monomers on cesium iodide surface. Kinetics of polymerization was followed by time–resolved IR spectroscopy at different temperatures. Activation parameters for the polymerization reaction of 1,3–dinitrosobenzene were calculated from the temperature dependence of the reaction rate constants.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:873901
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2020-11-22
Terms of useLicence In copyright icon
Created on2018-11-29 15:21:43