prikaz prve stranice dokumenta Priprava i konformacijska analiza tert-alkilnih diamantoidnih etera
  Download
PDF 3.22 MB
master's thesis
Priprava i konformacijska analiza tert-alkilnih diamantoidnih etera
Zagreb: University of Zagreb, Faculty of Science, 2019. urn:nbn:hr:217:761348
Bakija, Marija
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Bakija, M. (2019). Priprava i konformacijska analiza tert-alkilnih diamantoidnih etera (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:761348

Bakija, Marija. "Priprava i konformacijska analiza tert-alkilnih diamantoidnih etera." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:761348

Bakija, Marija. "Priprava i konformacijska analiza tert-alkilnih diamantoidnih etera." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:761348

Bakija, M. (2019). 'Priprava i konformacijska analiza tert-alkilnih diamantoidnih etera', Master's thesis, University of Zagreb, Faculty of Science, accessed 27 December 2024, https://urn.nsk.hr/urn:nbn:hr:217:761348

Bakija M. Priprava i konformacijska analiza tert-alkilnih diamantoidnih etera [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2019 [cited 2024 December 27] Available at: https://urn.nsk.hr/urn:nbn:hr:217:761348

M. Bakija, "Priprava i konformacijska analiza tert-alkilnih diamantoidnih etera", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:217:761348

Metadata
TitlePriprava i konformacijska analiza tert-alkilnih diamantoidnih etera
Title (english)Preparation and conformational analysis of tert-alkyl diamondoid ethers
AuthorMarija Bakija
MentorMarina Šekutor (mentor)
Committee memberInes Primožič (predsjednik povjerenstva)
Committee memberIva Juranović Cindrić (član povjerenstva)
Committee memberGordan Horvat (član povjerenstva)
Committee memberIvan Kodrin (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2019-01-29, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
Diamantoidi su policikličke alkanske molekule sa strogo definiranim, kavezastim strukturama zbog čega njihovi derivati imaju svojstva koja se mogu iskoristiti u razvoju različitih materijala s potencijalnom primjenom u medicini, elektrotehnici, nanotehnologiji, itd. U tu svrhu su pripravljeni i analizirani do sada slabo istraženi diamantoidni eteri koji se sastoje od kombinacije adamantanske i diamantanske podjedinice. U sklopu ovog rada cilj je bio pripraviti di(adamant-1-il)-eter i adamant-1-il-diamant-1-il-eter kondenzacijom odgovarajućih alkohola i metansulfonata kao polaznih reaktanta. Također je provedena konformacijska analiza ciljnih etera kako bi se utvrdila mogućnost rotacije eterske veze u ovisnosti o prisutnom diamantoidnom supstituentu. Di(adamant-1-il)-eter je uspješno sintetiziran reakcijom adamantan-1-ola i adamant-1-il-metansulfonata, dok eter koji se sastoji od adamantanske i diamantanske podjedinice nije izoliran iz analogne reakcije kondenzacije diamantan-1-ola i adamant-1-il-metansulfonata, najvjerojatnije zbog steričkih razloga.
Abstract (english)
Diamondoids are polycyclic alkane molecules with strictly defined cage structures and their derivatives possess properties useful in the development of different materials applicable in medicine, electronics, nanotechnology, etc. Therefore diamondoid ethers, unexplored compounds consisting of a combination of adamantane and diamantane subunits, were prepared and analyzed. The goal of this study was to prepare di(adamant-1-yl) ether and adamant-1-yl-diamant-1-yl ether by means of condensing the corresponding alcohol and mesylate precursors. A conformational analysis of the target ethers was also performed in order to determine the possibility of rotation of the ether bond in dependence of the present diamondoid substituent. Di(adamant-1-yl) ether was successfully synthesized in a reaction between adamantan-1-ol and adamant-1-yl methanesulfonate, while the ether composed from the adamantane and diamantane subunit could not be isolated from the analogous condensation reaction between diamantan-1-ol and adamant-1-yl methanesulfonate, probably due to sterical reasons.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:761348
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2021-01-29
Terms of useLicence In copyright icon
Created on2019-02-18 14:11:01