prikaz prve stranice dokumenta Priprava aromatskih heterocikličkih oksima
  Download
PDF 1004.61 KB
master's thesis
Priprava aromatskih heterocikličkih oksima
Zagreb: University of Zagreb, Faculty of Science, 2019. urn:nbn:hr:217:490306
Nikolić, Anđelo
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

Cite this document

Nikolić, A. (2019). Priprava aromatskih heterocikličkih oksima (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:490306

Nikolić, Anđelo. "Priprava aromatskih heterocikličkih oksima." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:490306

Nikolić, Anđelo. "Priprava aromatskih heterocikličkih oksima." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:490306

Nikolić, A. (2019). 'Priprava aromatskih heterocikličkih oksima', Master's thesis, University of Zagreb, Faculty of Science, accessed 28 July 2024, https://urn.nsk.hr/urn:nbn:hr:217:490306

Nikolić A. Priprava aromatskih heterocikličkih oksima [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2019 [cited 2024 July 28] Available at: https://urn.nsk.hr/urn:nbn:hr:217:490306

A. Nikolić, "Priprava aromatskih heterocikličkih oksima", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:217:490306

Metadata
TitlePriprava aromatskih heterocikličkih oksima
Title (english)Syntheses of aromatic heterocyclic oximes
AuthorAnđelo Nikolić
MentorInes Primožič (mentor)
Committee memberInes Primožič (predsjednik povjerenstva)
Committee memberŽeljka Soldin (član povjerenstva)
Committee memberSanda Rončević (član povjerenstva)
Committee memberVesna Petrović Peroković (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2019-07-12, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U ovom diplomskom radu sintetizirana je sol 2-(N,N-dimetilaminometil)cikloheksanona Mannichovom reakcijom. Klasičnom reakcijom kondenzacije s hiroksilamonijevim kloridom u otopini pripravljeni su oksimi 2-(N,N-dimetilaminometil)cikloheksanona, 4dimetilaminobenzaldehida te 4-dimetilaminocinamaldehida. Pored klasične sinteze, navedena tri oksima pripravljena su i mehanokemijskom sintezom bez prisutnosti otapala te uz katalitičku količinu otapala (etanol, aceton). Tijek mehanokemijskih reakcija praćen je FTIR spektroskopijom. Izvedena je i reakcija protoniranja oksima 4-dimetilaminobenzaldehida te metiliranja 4-(trimetilamonijevog)cinamaldehida. Svim pripravljenim spojevima struktura je dokazana standardnim analitičkim spektroskopskim metodama (FTIR, 1H i 13C NMR).
Abstract (english)
In this diploma thesis, the salt of 2-(N,N-dimethylaminomethyl)cyclohexanone was prepared by performing Mannich reaction. Condensation of prepared 2-(N,Ndimethylaminomethyl)cyclohexanone, 4-dimethylaminobenzaldehyde and 4dimethylaminocinnamaldehyde with the hydroxylamine hydrochloride resulted in the classical synthesis of appropriate oximes. Besides the classical syntheses in the solution, oximes were prepared by mechanochemical synthesis as well: without presence of the solvent and with the addition of the catalitical amount of the solvent (ethanol, acetone). Reaction course was monitored by FTIR spectroscopy. Furthermore, 4(dimethylammonium)benzaldehyde oxime was prepared and the reaction of methyl iodide and 4-dimethylaminocinnamaldehyde performed. All compounds were characterized by standard analytical spectroscopy methods (FTIR, 1H i 13C NMR).
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:490306
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2021-07-12
Terms of useLicence In copyright icon
Created on2019-09-27 10:31:49