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master's thesis
Kristalni koordinacijski polimeri kadmijevih(II) halogenida s cijanopiridinskim ligandima - supramolekulsko povezivanje i mehanički odziv
Zagreb: University of Zagreb, Faculty of Science, 2019. urn:nbn:hr:217:767846
Posavec, Amanda
University of Zagreb
Faculty of Science
Department of Chemistry

Institutional repository: Repository of the Faculty of Science

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Posavec, A. (2019). Kristalni koordinacijski polimeri kadmijevih(II) halogenida s cijanopiridinskim ligandima - supramolekulsko povezivanje i mehanički odziv (Master's thesis). Zagreb: University of Zagreb, Faculty of Science. Retrieved from https://urn.nsk.hr/urn:nbn:hr:217:767846

Posavec, Amanda. "Kristalni koordinacijski polimeri kadmijevih(II) halogenida s cijanopiridinskim ligandima - supramolekulsko povezivanje i mehanički odziv." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:767846

Posavec, Amanda. "Kristalni koordinacijski polimeri kadmijevih(II) halogenida s cijanopiridinskim ligandima - supramolekulsko povezivanje i mehanički odziv." Master's thesis, University of Zagreb, Faculty of Science, 2019. https://urn.nsk.hr/urn:nbn:hr:217:767846

Posavec, A. (2019). 'Kristalni koordinacijski polimeri kadmijevih(II) halogenida s cijanopiridinskim ligandima - supramolekulsko povezivanje i mehanički odziv', Master's thesis, University of Zagreb, Faculty of Science, accessed 25 December 2024, https://urn.nsk.hr/urn:nbn:hr:217:767846

Posavec A. Kristalni koordinacijski polimeri kadmijevih(II) halogenida s cijanopiridinskim ligandima - supramolekulsko povezivanje i mehanički odziv [Master's thesis]. Zagreb: University of Zagreb, Faculty of Science; 2019 [cited 2024 December 25] Available at: https://urn.nsk.hr/urn:nbn:hr:217:767846

A. Posavec, "Kristalni koordinacijski polimeri kadmijevih(II) halogenida s cijanopiridinskim ligandima - supramolekulsko povezivanje i mehanički odziv", Master's thesis, University of Zagreb, Faculty of Science, Zagreb, 2019. Available at: https://urn.nsk.hr/urn:nbn:hr:217:767846

Metadata
TitleKristalni koordinacijski polimeri kadmijevih(II) halogenida s cijanopiridinskim ligandima - supramolekulsko povezivanje i mehanički odziv
Title (english)Crystal coordination polymers of cadmium(II) halogenides with cyanopyridine ligands - supramolecular conectivity and mechanical response
AuthorAmanda Posavec
MentorMarijana Đaković (mentor)
Committee memberMarijana Đaković (predsjednik povjerenstva)
Committee memberVesna Petrović Peroković (član povjerenstva)
Committee memberSanda Rončević (član povjerenstva)
Committee memberŽeljka Soldin (član povjerenstva)
GranterUniversity of Zagreb
Faculty of Science
(Department of Chemistry)
Zagreb
Defense date and country2019-09-27, Croatia
Scientific / art field,
discipline and subdiscipline		NATURAL SCIENCES
Chemistry
Abstract
U okviru ovog rada sintetizirani su koordinacijski polimeri kadmijevih(II) halogenida s nitrilnim derivatima piridina kao ligandima. Priređeno je 6 kompleksnih spojeva ([CdCl2(3-CNpy)2]n (A1), [CdBr2(3-CNpy)2]n (A2), [CdI2(3-CNpy)2]n (A3), [CdCl2(4-CNpy)2]n (B1), [CdBr2(4-CNpy)2]n (B2) i [CdI2(4-CNpy)2]n (B3)) klasičnom otopinskom sintezom. Priređeni spojevi analizirani su infracrvenom spektroskopijom, metodama termičke analize te difrakcijom rendgenskog zračenja u praškastom uzorku, te im je određena molekulska i kristalna struktura rendgenskom strukturnom analizom metodom difrakcije rendgenskog zračenja u monokristalnom uzorku. U kristalnom pakiranju ustanovljena je važnost supramolekulskih interakcija, prvenstveno vodikovih veza ali i dipol-dipol interakcija, kod povezivanja polimernih lanaca u kristalnu strukturu. Također, ispitan je odziv igličastih kristala na primjenu vanjske mehaničke sile čime je ustanovljen njihov elastičan odziv u slučaju spojeva A1, A2 i B1 te plastičan u slučaju B2, dok su se kristali spojeva A3 i B3 pokazali nefleksibilnima. Opaženi mehanički odzivi korelirani su s jakosti i usmjerenosti ostvarenih supramolekulskih interakcija u kristalnom pakiranju priređenih spojeva.
Abstract (english)
This diploma thesis presents synthesis of coordination polymers of cadmium(II) halides with 3-cyanopiridine and 4-cyanopiridine. Six compounds ([CdCl2(3-CNpy)2]n (A1), [CdBr2(3-CNpy)2]n (A2), [CdI2(3-CNpy)2]n (A3), [CdCl2(4-CNpy)2]n (B1), [CdBr2(4-CNpy)2]n (B2) and [CdI2(4-CNpy)2]n) (B3) were prepared by classical solution synthesis. The products were characterized by infrared spectroscopy, thermal methods and powder X-ray diffraction, while molecular and crystal structure were determined by single crystal X-ray diffraction analysis. The importance of supramolecular interactions (particularly hydrogen bonds and dipole-dipole interactions) in linking polymeric building units into the supramolecular architecture is established. Also, the response of needle-like crystals to the application of external mechanical force was investigated, and elastic (A1, A2, B1) and plastic (B2) flexibility was established. Furthermore, crystals of two compounds (A3 and B3) showed to be stiff and brittle. The observed mechanical responses were correlated with the strength and geometry of supramolecular interactions in the crystal packings of prepared products.
Keywords
Keywords (english)
Languagecroatian
URN:NBNurn:nbn:hr:217:767846
Study programmeTitle: Graduate university studies in chemistry; specializations in: Research programme
Course: Research programme
Study programme type: university
Study level: graduate
Academic / professional title: magistar/magistra kemije (magistar/magistra kemije)
Type of resourceText
File originBorn digital
Access conditionsOpen access
Embargo expiration date: 2021-09-27
Terms of useLicence In copyright icon
Created on2019-10-11 10:23:04